From structures to properties Flashcards
(29 cards)
why atoms bond
To become stable by filling their outer electron shell (octet rule)
Types of chem bonds :
Ionic covalent,polar covalent, and metallic bonds.
metallic
electrons move freely
Ionic bonding
Attratcs eachother
Covalent bonding
Electrons are shared between two non-metals.
Polar
Unequal share.Electronegative atoms pulls electrons more.
Non-Polar
Equally sharing electrons
Lewis Structures
Shows valence electrons as dots and bonds as line.
Trigonal Planar (120)
Flat triangle, 3 B.P, 0 L.P
VSEPR Theory
Electron pairs repel eachother , so molecules adjust shape tp minimize repulsion.
Linear (180)
Straight line, 2 B.P, 0 L.P
Tetrahedral (109.5)
3D pyramid , 4 B.P, 0 L.P
Pyramidal
3D Pyramid , 3 B.P, 1 L.P
Bent (104.5)
Bent Shape, 2 B.P, 2 L.P
Intermolecular forces
Weak forces of attraction between molecules.
What is IMF’s responsible for?
States,boiling points,surface tension,viscosity, and solubility.
Intramolecular forces :
Forces that hold atoms together. (stronger than intermolecular forces)
Types on Intra Forces :
Covalent, Ionic and mettallic
London dispersion forces (LDF):
present in?
Strength?
Caused by?
Increases with?
- Present in : all molecules, especially non-polar.
- Strength : WEAKEST IMF
- Caused by temporary dipoles due to electrons.
- Increases with larger molecules and more surface area (SA)
Hydrogen Bonding :
Present in?
Strength?
caused by?
why the strongest IMF?
- Present in : Molecules where H bonds w/ F,O, or N.
- Strength : STRONGEST IMF
- Caused by strong attractions between H lone pairs.
- Why the strongest : F,O,N are very elctronegative (Highly polar bonds).
Dipole - Dipole Forces :
Present in?
Strength?
Caused by?
- Present in : Polar molecules ONLY.
- Strength : Moderate
- Caused by attraction between partial (+) and (-) ends.
Isoelectronic substances :
same number of electrons
Boiling point : Non-polar
ONLY LDF (USE VESPR)
Boiling point : Polar
LDF + D-D FORCES (USE VESPR )