From structures to properties Flashcards

(29 cards)

1
Q

why atoms bond

A

To become stable by filling their outer electron shell (octet rule)

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2
Q

Types of chem bonds :

A

Ionic covalent,polar covalent, and metallic bonds.

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2
Q

metallic

A

electrons move freely

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2
Q

Ionic bonding

A

Attratcs eachother

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3
Q

Covalent bonding

A

Electrons are shared between two non-metals.

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4
Q

Polar

A

Unequal share.Electronegative atoms pulls electrons more.

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5
Q

Non-Polar

A

Equally sharing electrons

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6
Q

Lewis Structures

A

Shows valence electrons as dots and bonds as line.

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7
Q

Trigonal Planar (120)

A

Flat triangle, 3 B.P, 0 L.P

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8
Q

VSEPR Theory

A

Electron pairs repel eachother , so molecules adjust shape tp minimize repulsion.

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9
Q

Linear (180)

A

Straight line, 2 B.P, 0 L.P

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10
Q

Tetrahedral (109.5)

A

3D pyramid , 4 B.P, 0 L.P

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11
Q

Pyramidal

A

3D Pyramid , 3 B.P, 1 L.P

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12
Q

Bent (104.5)

A

Bent Shape, 2 B.P, 2 L.P

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13
Q

Intermolecular forces

A

Weak forces of attraction between molecules.

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14
Q

What is IMF’s responsible for?

A

States,boiling points,surface tension,viscosity, and solubility.

15
Q

Intramolecular forces :

A

Forces that hold atoms together. (stronger than intermolecular forces)

16
Q

Types on Intra Forces :

A

Covalent, Ionic and mettallic

17
Q

London dispersion forces (LDF):
present in?
Strength?
Caused by?
Increases with?

A
  • Present in : all molecules, especially non-polar.
  • Strength : WEAKEST IMF
  • Caused by temporary dipoles due to electrons.
  • Increases with larger molecules and more surface area (SA)
18
Q

Hydrogen Bonding :
Present in?
Strength?
caused by?
why the strongest IMF?

A
  • Present in : Molecules where H bonds w/ F,O, or N.
  • Strength : STRONGEST IMF
  • Caused by strong attractions between H lone pairs.
  • Why the strongest : F,O,N are very elctronegative (Highly polar bonds).
18
Q

Dipole - Dipole Forces :
Present in?
Strength?
Caused by?

A
  • Present in : Polar molecules ONLY.
  • Strength : Moderate
  • Caused by attraction between partial (+) and (-) ends.
19
Q

Isoelectronic substances :

A

same number of electrons

20
Q

Boiling point : Non-polar

A

ONLY LDF (USE VESPR)

21
Q

Boiling point : Polar

A

LDF + D-D FORCES (USE VESPR )

22
Properties of molecular substances :
- Affected by intermolecular forces. - Includes : Solubility,density, surface tension and viscosity.
23
Solubility explanation :
- Polar solutes dissolve in polar solvents. - Hydrogen bonding increases solubility of polar substances.
24
Density explanation :
-stronger IMF = Highr density - Temperature affect : Solids are denser than liquid,but ice is an exception.
25
Viscosity explanation :
- A liquid's resistance to flow Higher viscosity = Thick
26
Surface Tension explanation :
- The skin on the surface of a liquid. - Caused by moelcules pulling on eachother. - Higher intermolecular = Higher surface tension.