Fuels and Earth Science Flashcards
(37 cards)
What is crude oil?
Our main source of hydrocarbons
What is crude oil used for?
Used as a feedstock (raw material) to create lots of useful substances used in the petrochemical industry (basically to make different types of petrol)
How is crude oil formed?
Formed underground over millions of years from the buried remains of plants and animals
What is a hydrocarbon?
a compound that contains carbon and hydrogen - in crude oil they are arranged in chains or rings and are usually alkanes (have a general formula of Cn H2n+2)
What are alkanes?
Hydrocarbons with the formula CnH2n+2
What are fractions? (in relation to crude oil)
fractions are simpler, more useful mixtures containing groups of hydrocarbons of similar lengths (similar no. of hydrogen and carbon atoms) - fractions from crude oil include petrol, kerosene and diesel
How are fractions in crude oil separated?
using fractional distillation - oil is heated until most of it has turned into a gas - gases enter a fractionating column (and the liquid bit - bitumen - is drained off at the bottom) - in the column there is a temperature gradient (cooler at top) so the longer hydrocarbons with higher boiling points turn back to liquids and drain out of the column early on and shorter hydrocarbons drain out later on - near to the top of the column (there are different heights where different length hydrocarbons (fractions) drain)
Which different heights on a fractionating column do different crude oil fractions drain out?
- bitumen - 70+ carbon atoms in each hydrocarbon in this fraction (stays liquid when heated and drained out bottom)
- fuel oil ~40 carbon atoms in each hydrocarbon
- diesel oil ~20 carbons
- kerosene ~15 carbons
- petrol ~8 carbons
- gases ~3 carbons (go out the top of the fractionating column)
What are the different fractions in crude oil used for?
- bitumen - surfacing roads and roofs
- fuel oil - fuel for large ships and power stations
- diesel oil - fuel in some cars and larger vehicles e.g. trains
- petrol - fuel in cars
- gases - domestic heating and cooking
do you understand fractional distillation of crude oil (pg 137)
page 137
What is a homologous series?
a homologous series is a family of molecules with the same general formula and similar chemical properties e.g. alkanes and alkenes are differing homologous series of hydrocarbons - neighbouring compounds in a homologous series differ by a CH2 unit (e.g. Methane: CH4 and Ethane: C2H6)
What does the size of a hydrocarbon determine?
- intermolecular forces of attraction are stronger in bigger hydrocarbons = higher boiling point (so determines which fraction of crude oil it will separate into)
- shorter hydrocarbons = easy to ignite bc lower boiling points mean they’re gases at room temp so they mix with oxygen easily which make them flammable (where as longer hydrocarbons are liquid at room temp)
- longer hydrocarbons = higher viscosity bc stronger force between hydrocarbon molecules so harder it is for the liquid to flow - thicker so higher viscosity (how well it flows)
What does viscosity mean?
How hard it is for a substance to flow - longer hydrocarbons are thicker so have a higher viscosity
Why do hydrocarbons make good fuels?
very exothermic - combustion reactions that happen when you burn them in oxygen give out lots of energy
What is a complete combustion?
When hydrocarbons are burned in enough oxygen so that the only products are carbon dioxide and water
What is incomplete combustion?
When hydrocarbons burn in a limited supply of oxygen
What does incomplete combustion produce?
carbon monoxide and soot - e.g. in boilers which use carbon compounds as fuel (and when there isn’t enough oxygen for a complete combustion - which would produce water and CO2)
What are the dangers of incomplete combustion reactions?
- produce carbon monoxide (CO) that combines with red blood cells and stops blood from carrying oxygen around the body - lack of oxygen to brain causes fainting, comas and death
- tiny carbon particles are released into the atmosphere, falling back to the ground as soot which makes buildings look dirty, reduces air quality and worsens respiratory problems
What harmful gases do fossil fuels release when burned?
- CO2 (causing global warming)
- Sulfur Dioxide (from sulfur impurities in fuels - forms sulfuric acid in clouds - acid rain which makes lakes acidic and trees die, killing wildlife, damages limestone buildings/statues and corrodes metal)
- Nitrogen Oxides (when nitrogen reacts with oxygen in air - caused by energy released in combustion reactions - cause acid rain and photochemical smog, causing breathing difficulties, tiredness and headaches)
What can be used as a clean, renewable fuel to power vehicles?
hydrogen gas
What are the advantages of using hydrogen gas to power vehicles?
- very clean (combines with oxygen in a fuel cell to produce energy, water is the only waste product, no greenhouse gases)
- obtained from water which is a renewable resource (waste product is water so this can in theory be used again)
What are the disadvantages of using hydrogen gas to power vehicles?
- special, expensive engine required
- hydrogen gas must be manufactured which is expensive and uses energy from another source which probably uses fossil fuels
- hydrogen is hard to store and not widely available
What is cracking?
turning alkAne (long) hydrocarbons into smaller, more useful alkAne molecules +alkEne molecules which are used to make polymers (e.g. plastics)
How is cracking a form of thermal decomposition?
one substance breaks down into at least two when being heated - covalent bonds need to be broken so a lot of heat energy is needed (catalysts are often added to speed the process)