functional group name and reactivity Flashcards

1
Q

alkane

A

c-c ethane

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2
Q

alkene

A

c=c ethene

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3
Q

are alkene nucleophiles?

A

yes . double bond attacks

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4
Q

alkyne

A

c triple bond ethyne

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5
Q

are alkyne nucleophiles are electrophiles?

A

nucleophiles

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6
Q

are alkynes better nucleophiles?

A

When a proton adds to an alkene, an alkyl cation is formed.

When a proton adds to an alkyne, a vinylic cation is formed.

A vinylic cation has a positive charge on a vinylic carbon.

It is less stable than a similarly substituted alkyl cation because the positive charge is on an sp carbon, which is more electronegative than an sp 2 carbon of an alkyl cation. This makes it less able to bear a positive charge.”

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7
Q

arene

A

ethyl benzene

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8
Q

are benzene nucleophile or electrophile?

A

nucleophile

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9
Q

haloalkane

A

chloroethane

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10
Q

aldehyde

A

final carbon
ethanal

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11
Q

ketone

A

any centre carbon
ethanone

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12
Q

carboxylic acid

A

ethanoic acid

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13
Q

carbonyl group

A

electrophile
electron sink

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14
Q

are carboxylic acids electrophiles or nucleophiles?

A

electrophile,

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15
Q

acid anhydride

A

ethanoic anhydride

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16
Q

are acid anhydride nucleophiles or electrophiles?

A

electrophilic

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17
Q

acyl halide

A

ethanoyl chloride

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18
Q

ester

A

ethyl ethanoate first part is alcohol the second is carboxylic acid

ro-c=o

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19
Q

is ester an electrophile or nucleophile?

A

electrophile

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20
Q

ether

A

methoxymethane

oxy -ane

c-o-c

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21
Q

are ethers nucleophiles or electrophiles

22
Q

epoxides

A

triangle with oxygen
ethene oxide

23
Q

amine

A

ethanamine
NR3

24
Q

Amide

25
are amides nucleophiles
weak electrophiles ethanamide
26
nitrate
o-n=o I o-
27
what are nitrates
weak nucleophiles,
28
nitrite
o-n=o
29
are nitrite nucleophiles?
ambident nucleophiles
30
nitrille
c triple bond n nucleophile
31
nitro
r-n=o - o
32
nitroso
r-n=o
33
imine
c=n-r
34
imide
o=c-n-c=o
35
azide
methyl azide n=n=n-r
36
cyanate
r-o-c= triple n
37
isocyanate
n=c=o
38
azo
r-n=n-r
39
thiol
r-sh
40
thiols are
bronsted acids nucleophile when loses h
41
sulfide
r-s-r dimethyl sulfide
42
sulfoxide
s=o two r groups dimethly sulfoxide
43
sulfone
o=s=o two r group dimethyl sulfone
44
sulfinic acid
oh-s=o r group
45
sulfonic acid
o=s=o -oh - r
46
sulfonate acid
ly methylmethanesulfonate acid
47
thiocyanate
r-s-c triple n ethyl thiocyanate
48
isothiocyanate
r - n= c= s
49
thial
r-c = s I h
50
thioketone
r-c-r = s methanethione
51
phosphine
p R 3