Gas laws PPT Flashcards
(18 cards)
2 main factors determine state:
• The forces (inter/intramolecular) holding particles together
• the kinetic energy present(the
energy an object possesses due to its motion of the particles)
This tends to pull particles apart
Kinetic energy
These have a higher kinetic energy because their particles move a lot more than in a solid or a liquid
Gases
As the temperature increases, the gas particles move faster, and thus kinetic energy ____
increases
Characteristics of Gases (5)
- Gases expand to fill any container
-random motion, no attraction - Gases are fluids (like liquids)
- no attraction - Gases have very low densities
-no volume = lots of empty space - Gases can be compressed
-no volume = lots of empty space - Gases undergo diffusion and effusion (across a barrier with small holes).
-random motion
Particles in an ideal gas….
• have no volume.
• have elastic collisions (ie. billiard ball-> particles exchange energy with eachother, but total KE is conserved
• are in constant, random, straight-line motion.
• don’t attract or repel each other.
• have an avg. KE directly related to temperature
Particles in a REAL gas…
• have their own volume
• attract each other (intermolecular forces)
Gas behavior is most ideal at
• at low pressures
• at high temperatures
At STP, molecules of gas are moving ___ and are very ____, making their intermolecular forces and volumes _____, so assumptions of an ideal gas are valid under normal temp/pressure conditions. BUT…..
fast
far apart
insignificant
• at high pressures: gas molecules are pushed closer together, and their interactions with each other become more significant due to volume
• at low temperatures: gas molecules move slower due to KE and intermolecular forces are no longer negligible
Pressure
Pressure = force/area
The gas molecules in the atmosphere are ____ toward Earth due to gravity, exerting ____
pulled
pressure
measures atmospheric pressure
Barometer
At Standard Atmospheric Pressure
(SAP)
101.325 kPa (kilopascal)
1 atm (atmosphere)
760 mm Hg (millimeter Hg)
760 torr
14.7 psi (pounds per square inch)
kPa equation
kPa = N/m2
Standard Temperature and Pressure
0 C or 273 K
1 atm or 101.325 kPa
Scottish physicist ____ suggested that -273°C (OK) was the temperature at which the motion particles within a gas approaches zero.. And thus, so does volume)
Lord Kelvin
Does everything freeze at 0°C?
No, not everything freezes at 0C but for ALL substances, motion stops at 0 K
Why use Kelvin Scale?
It eliminates the use of negative values for temperature! Makes mathematic calculations possible (to calculate the temp. twice warmer than -5°C we can’t use 2x(-
5°C) because we would get -10°C!)