Gases Flashcards

(70 cards)

1
Q

is a measure of the change in volume of a sample of matter resulting from a pressure change.

A

compressibIlity

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2
Q

is a measure of the change in volume of a sample of matter resulting from a temperature change.

A

thermal expansion

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3
Q

set of five statements used to explain the physical behavior
of the three states of matter (solids, liquids, and gases).

A

kinetic molecular theory of matter

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4
Q

is energy that matter possesses because of particle motion.

A

kinetic energy

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5
Q

is stored energy that matter possesses as a result of its position, condition, and/or composition

A

potential energy

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6
Q

Five Statements of KMT

A
  1. Matter is ultimately composed of tiny particles (atoms, molecules, or
    ions) that have definite and characteristic sizes that do not change.
  2. The particles are in constant random motion and therefore possess kinetic energy.
  3. The particles interact with one another through attractions and repulsions and therefore possess potential energy.
  4. The kinetic energy (velocity) of the particles increases as the
    temperature is increased.
  5. The particles in a system transfer energy to each other through elastic collisions.
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7
Q

is the physical state characterized by a complete dominance of kinetic energy (disruptive forces) over potential energy (cohesive forces).

A

gas

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8
Q

is the physical state characterized by potential energy (cohesive forces)
and kinetic energy (disruptive forces) of about the same magnitude.

A

liquid

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9
Q

is the physical state characterized by a dominance of potential energy (cohesive
forces) over kinetic energy (disruptive forces).

A

solid

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10
Q

Identify the physical state described below:
1. definite volume and shape
2. high density
3. small compressibility
4. very small thermal expansion

A

solid

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11
Q

Identify the physical state described below:
1. definite volume and indefinite shape
2. high density
3. small compressibility
4. small thermal expansion

A

liquid

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12
Q

Identify the physical state described below:
1. indefinite volume and shape
2. low density
3. large compressibility
4. moderate thermal expansion

A

gas

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13
Q

is a generalization that describes in mathematical
terms the relationships among the amount, pressure, temperature, and volume of a gas.

A

gas law

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14
Q

Occurrence of Gases: Composition of air by volume

A

78% N2
21% O2
1% of other gases

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15
Q

Abundance of elements: composition of the universe

A

91% Hydrogen
9% Helium
<0.1% Others

HY HELIUM

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16
Q

Abundance of elements:
earth’s crust

A

Oxygen 47%
Silicon 28%
Aluminum 8%
Iron 5%
Others 12%

OXSILAFE

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17
Q

Abundance of elements:
Human Body

A

65% Oxygen
18% Carbon
9.5% Hydrogen
3.2% Nitrogen
4.3% Others

OX KA? HYDNI

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18
Q

a substance that is gaseous state at ordinary temperatures and pressures

A

gas

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19
Q

is the gaseous form of a substance that is usually a liquid or solid under those conditions

A

vapor

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20
Q

the force applied per unit area

A

pressure

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21
Q

what is 1 newton (N) equal to?

A

1N = 1 kgm/s^2

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22
Q

what is 1 Pa equal to?

A

1Pa = 1N/m^2

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23
Q

is the pressure exerted by the Earth’s atmosphere

A

atmospheric pressure

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24
Q

the force exerted by the weight of the air above us

A

atmospheric pressure

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25
instrument for measuring pressure
barometer
26
is equal to the pressure that supports a column of mercury exactly 760nm high at 0oC at sea level
standard atmospheric pressure
27
The pressure outside a jet plane fl ying at high altitude falls considerably below standard atmospheric pressure. Therefore, the air inside the cabin must be pressurized to protect the passengers. What is the pressure in atmospheres in the cabin if the barometer reading is 688 mmHg?
0.905 atm
28
The atmospheric pressure in San Francisco on a certain day was 732 mmHg. What was the pressure in kPa?
97.6 kPa
29
CONVERSION FACTOR: 1 atm is equal to ______ bar
1.01325 bar
30
CONVERSION FACTOR: 1 atm is equal to ______ Pa
101,325 Pa
31
CONVERSION FACTOR: 1 atm is equal to ______ kPa
101.325
32
CONVERSION FACTOR: 1 atm is equal to ______ mmHg
760
33
CONVERSION FACTOR: 1 atm is equal to ______ torr
760
34
is a device used to measure the pressure of gases other than the atmosphere.
manometer
35
CONVERSION FACTOR: 1 L is equal to ______ mL
1000
36
CONVERSION FACTOR: 1 mL is equal to ______ cm^3
1 cm^3
37
the volume of a fixed amount of a gas is inversely proportional to the pressure applied to the gas if the temperature is kept constant.
Boyle's law
38
CONVERSION FACTOR: 1 m3 is equal to ______ dm^3
1000 dm^3
39
CONVERSION FACTOR: 1 bar is equal to ______ Pa
10^5 Pa
40
property that describes the flow of energy when 2 objects are in contact or between a thermally conducting rigid wall
temperature
41
property that is defined as the amount of matter
number of moles
42
property that is defined as the space occupied by a system
volume
43
a model gas system that approximates gas behavior at LOW PRESSURES AND HIGH TEMPERATURES
Ideal gas
44
IUPAC Standard Temperature and Pressure (STP)
273.15K and 1 bar
45
What gas law describes the mathematical expression law below? P ∝ 1/V
Boyle's Law
46
What gas law describes the mathematical expression law below? V ∝ T
Charles' Law
47
What gas law describes the mathematical expression law below? V ∝ n
Avogadro's Law
48
What gas law describes the mathematical expression law below? P ∝ T
Gay-Lussac's Law
49
states that the volume of a fixed amount of gas maintained at constant pressure is directly proportional to the absolute temperature of the gas.
Charles' Law
50
states that at constant pressure and temperature, the volume of a gas is directly proportional to the number of moles of the gas present.
Avogadro's Law
51
Combined Gas Law Formula
(P1V1)/T1 = (P2V2)/T2
52
describes the relationship among the four variables P, V, T, and n
Ideal gas equation
53
Ideal gas law
PV=nRT
54
Formulae for getting the density from the gas law
rho = PM/RT
55
Formulae for getting the molar mass from the gas law
M= mRT/PV
56
Universal Gas Constant
0.0821 L-atm/mol-k 8.314 J/mol-k
57
The total pressure of a mixture of gases is equal to the sum of the partial pressures of the individual gases
Dalton's Law of Partial Pressures
58
is a dimensionless quantity that expresses the ratio of the number of moles of one component to the number of moles of all components present.
mole fraction
59
Mole fraction formula:
Xf = ni/nt
60
If a system contains more than two gases, then the partial pressure of the i th compo- nent is related to the total pressure by
Pi = XiPt
61
Sulfur hexafluoride (SF ) is a colorless, odorless, very unreactive gas. Calculate the pressure (in atm) exerted by 1.82 moles of the gas in a steel vessel of volume 5.43 L at 69.5°C.
9.42 atm
62
Calculate the volume (in liters) occupied by 7.40 g of NH 3 at STP.
9.74L
63
An infl ated helium balloon with a volume of 0.55 L at sea level (1.0 atm) is allowed to rise to a height of 6.5 km, where the pressure is about 0.40 atm. Assuming that the temperature remains constant, what is the final volume of the balloon?
1.4L
64
Calculate the density of carbon dioxide (CO2) in grams per liter (g/L) at 0.990 atm and 55 C.
1.62g/L
65
A chemist has synthesized a greenish-yellow gaseous compound of chlorine and oxygen and finds that its density is 7.71 g/L at 36°C and 2.88 atm. Calculate the molar mass of the compound and determine its molecular formula.
67.9 g/mol
66
Chemical analysis of a gaseous compound showed that it contained 33.0 percent silicon (Si) and 67.0 percent fl uorine (F) by mass. At 35°C, 0.210 L of the compound exerted a pressure of 1.70 atm. If the mass of 0.210 L of the compound was 2.38 g, calculate the molecular formula of the compound.
Si2F6
67
Determine the molar mass of an unknown gas if a sample weighing 0.389g is collected in a flask with a volume of 102 cm^3 at 97°C. The pressure of the gas is 728 mmHg.
a) 187g/mol b) 121g/mol c) 112g/mol d) 31.6 g/mol
68
There are 135 L of gas in a container at a temperature of 2600°C. If the gas was cooled until the volume decreased to 75 L, what would the temperature of the gas be?
296K or 23°C
69
The initial volume of a gas at a pressure of 3.2 atm is 2.9 L. What will the volume be if the pressure is increased to 4.0 atm?
2.3L
70
Two flasks are connected with a stopcock. Flask #1 has a volume of 2.5 L and contains oxygen gas at a pressure of 0.70 atm. Flask #2 has a volume of 3.8 L and contains hydrogen gas at a pressure of 1.25 atm. When the stopcock between the two flasks is opened and the gases are allowed to mix, what will the resulting pressure of the gas mixture be?
0.28 atm + 0.5 atm = 1.0 atm