GE-CHEM 1103 Module 4.2 Flashcards

(54 cards)

1
Q

composed of the
two nucleons, protons and neutrons

A

nucleus

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2
Q

number of protons

A

atomic number (Z)

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3
Q

number of protons and neutrons together

A

mass number (A)

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4
Q

Not all atoms of the same element have the
same mass, due to different numbers of
neutrons in those atoms

A

Isotopes

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5
Q

nuclei change spontaneously,
emitting radiation

A

radioactive and refer to these nuclei’s as radionuclides

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6
Q

show how
these nuclear reactions occur

A

nuclear equations

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7
Q

atoms and
charges need to balance

A

chemical equations

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8
Q

atomic number
and mass number need to balance

A

nuclear equations

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9
Q

Has a charge of 2+, a mass of 6.64x10^-24 g, a relative penetrating power of 1 and its nature of radiation is 4(A) 2(Z) He nuclei

A

α

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10
Q

Has a charge of 1-, a mass of 9.11x10^-28 g, a relative penetrating power of 100 and its nature of radiation is electrons

A

β

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11
Q

Has a charge of 0 , a mass of 0 g, a relative penetrating power of 10000 and its nature of radiation is high-energy photons

A

γ

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12
Q

How far do the alpha, beta, neutron and gamma radiation pass through materials

A

paper(alpha) > hand (skin) > metal(beta) > water (neutron)> concrete > lead(gamma)

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13
Q

Nuclear Equation:
(A)(Z) X > (A-4)(Z-2) Y + 4(A) 2(Z) He
Change in atomic no.: -2
Change in mass no.: -4

A

Alpha decay

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14
Q

Nuclear Equation:
(A)(Z) X > (A)(Z+1) Y + 0(A) -1(Z) e
Change in atomic no.: +1
Change in mass no.: no change

A

Beta decay

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15
Q

Nuclear Equation:
(A)(Z) X > (A)(Z-1) Y + 0(A) +1(Z) e
Change in atomic no.: -1
Change in mass no.: no change

A

Positron emission

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16
Q

Nuclear Equation:
(A)(Z) X + 0(A) -1(Z) e > (A)(Z-1) Y
Change in atomic no.: -1
Change in mass no.: no change

A

Electron capture

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17
Q

loss of an α-particle
(He-4 nucleus, two protons and two neutrons):

A

Alpha decay

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18
Q

is the loss of a β-particle (a
high-speed electron emitted by the nucleus)

A

Beta decay

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19
Q

is the loss of a γ-ray,
which is high-energy radiation that
almost always accompanies the loss of
a nuclear particle

A

Gamma emission

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20
Q

a particle that has the same
mass as, but an opposite charge to, that
of an electron

A

positron

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21
Q

Some nuclei decay by emitting a
positron

A

Positron Emission

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22
Q

An electron from the surrounding electron
cloud is absorbed into the nucleus

A

electron capture

23
Q

Writing Nuclear Equations for
Nuclear Transmutations

A

Example
(A)(Z) X(α, p) (A)(Z) Y

24
Q

first-order process

A

Radioactive decay

25
The kinetics of such a process obey this equation
ln(Nt/No) = -kt
26
time required for half of a radionuclide sample to decay.
Half-life
27
Formula of k constant
k = ln 2 (or 0.693)/t 1/2
28
radioisotopes used to study a chemical reaction
Radiotracers
29
An element can be followed through a reaction
to determine its path and better understand the mechanism of a chemical reaction
30
react chemically exactly the same as nonradioactive nuclei of the same element
Radionuclides
31
Medical Application of Radiotracers
1. wide diagnostic use in medicine 2. administered to a patient (usually intravenously) and followed. Certain elements collect more in certain tissues, so an organ or tissue type can be studied based on where the radioactivity collects.
32
* A compound labeled with a positron emitter is injected into a patient. * Blood flow, oxygen and glucose metabolism, and other biological functions can be studied. * Labeled glucose is used to study the brain, as seen in the figure to the right.
Positron Emission Tomography (PET Scan)
33
There is a tremendous amount of energy stored in nuclei. * Einstein’s famous equation, E = mc2 relates directly to the calculation of this energy.
Energy in Nuclear Reactions
34
associated with making and breaking chemical bonds
Chemical energy
35
due to changes in the nucleus of atoms changing them into different atoms
Nuclear energy
36
13% of worldwide energy
nuclear energy
37
Commercial nuclear power plants
fission
38
Bombardment of the radioactive nuclide with a neutron starts the process
Nuclear Fission
39
Neutrons released in the transmutation strike other nuclei, causing their decay and the production of more neutrons. (note: This process continues on and on)
chain reaction
40
rate of neutron loss > rate of neutron creation by fission
Subcritical mass
41
rate of neutron loss = rate of neutron creation by fission
Critical mass
42
rate of neutron loss < rate of neutron creation by fission
Supercritical mass
43
The minimum mass that must be present for a chain reaction to be sustained
critical mass
44
the heat generated by the reaction is used to produce steam that turns a turbine connected to a generator.
nuclear reactors
45
What does The reactor core consists?
fuel rods, control rods, moderators, and coolant
46
block the paths of some neutrons, keeping the system from reaching a dangerous supercritical mass
control rods
47
* Reactors must be stopped periodically to replace or reprocess the nuclear fuel. * They are stored in pools at the reactor site. * The original intent was that this waste would then be transported to reprocessing or storage sites. * Political opposition to storage site location and safety challenges for reprocessing have led this to be a major social problem.
Nuclear Waste
48
When small atoms are combined, much energy is released. This occurs on the Sun. The reactions are often called thermonuclear reactions.
Nuclear Fusion
49
more harmful to living systems
Ionizing radiation
50
any type of electromagnetic radiation that does not carry enough energy per quantum to ionize atoms or molecules that is, to completely remove an electron from an atom or molecule.
nonionizing radiation
51
depends on the type of radioactivity, the length of exposure, and whether the source is inside or outside the body.
damage to cells
52
Outside the body it is the most dangerous
gamma rays
53
Inside the body it can cause most harm
alpha radiation
54
* Low-level, long-term exposure can cause health issues. * Damage to the growth-regulation mechanism of cells results in cancer.
Exposure in radiation