GenChem2 (PeriodicTable) Flashcards

(62 cards)

1
Q

Periodic Law states that the chemical properties of the elements are dependent, in a systematic way, upon their

A

Atomic numbers

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2
Q

How many periods (rows) are there?

A

7

They represent n=1 to n=7

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3
Q

Groups represent elements that have the same electronic configuration in their _____, and the have similar chemical properties because of it

A

Valence Shell

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4
Q

The Roman numeral above each group represents the number of

A

Valence Electrons

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5
Q

A groups have ____ sublevels as their outermost orbitals

B groups have _____ sublevels as their outermost orbitals

A

s and p

d and f

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6
Q

The B elements include these groups

A

transition elements
lanthanide series
actinide series

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7
Q

This B element group has partially filled d levels

A

Transition elements

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8
Q

This B element has partially filled f sublevels

A

Lanthanide and Actinide Series

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9
Q

As one goes from left to right across a period, the electrons of the outermost shell experience INCREASING/DECREASING amount of nuclear attraction

A

As one goes from left to right across a period, the electrons of the outermost shell experience INCREASING amount of nuclear attraction
(they become closer and more tightly bound to the nucleus)

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10
Q

As one goes down a column, the outermost electrons become MORE/LESS tightly bound to the nucleus

A

As one goes down a column, the outermost electrons become LESS tightly bound to the nucleus

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11
Q

The _____ is equal to one-half the distance between the centers of two atoms of that element that are just touching each other

A

Atomic radius

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12
Q

Atomic radius ______ from right to left and ________ down a given group

A

Atomic radius decreases from right to left and increases down a given group

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13
Q

The atoms with the largest atomic radius will be located where on the periodic table?

A

Bottom of group 1

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14
Q

The energy required to completely remove an electron from a gaseous atom or ion.

A

Ionization Energy (IE) or Ionization Potential

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15
Q

Is removing an electron exothermic or endothermic?

A

Endothermic, as it requires energy.

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16
Q

The energy required to remove one valence electron from the parent atom

The energy required to remove a second valence electron from the univalent ion to form the divalent ion

A

Second Ionization energy

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17
Q

Which has a greater ionization energy, second or first ionization energy?

A

second ionization energy

IEs grow increasingly large

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18
Q

From left to right across the periodic table, ionization energy INCREASES/DECREASES

Why?

A

From left to right across the periodic table, ionization energy INCREASES

The atomic radius DECREASES

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19
Q

Moving down a group, ionization energy INCREASES/DECREASES

Why?

A

Moving down a group, ionization energy DECREASES

The atomic radius increases

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20
Q

Defined as the energy change that occurs when an electron is added to a gaseous atom, and represents the ease to with which the atom can accept an electron.

A

Electron Affinity

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21
Q

Positive electron affinity (in this text) represents energy absorption when an electron is added or energy release?

A

Energy release

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22
Q

Group IIA elements have HIGH/LOW electron affinityies

Group VIIA elements have HIGH/LOW electron affinities

A

Group IIA elements have LOW electron affinityies

Group VIIA elements have HIGH electron affinities

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23
Q

A measure of the attraction an atom has for electrons in a chemical bond

A

Electronegativity

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24
Q

Electronegativities are related to…

A

Ionization energies

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25
Electrons with low ionization energies have HIGH/LOW electronegativities Why?
Electrons with low ionization energies have LOW electronegativities Their nuclei do not strongly attract electrons.
26
Electrons with high ionization energies have HIGH/LOW electronegativities Why?
Electrons with high ionization energies have HIGH electronegativities The nucleus has a strong pull on the electrons
27
As you move from left to right across the periodic table, electronegativity ______ As you increases the atomic number in a group, electronegativity ______
Increases Decreases because of increased distance between valence shell and nucleus
28
The three categories of elements in the periodic table
Nonmetals, Metals, Metalloids
29
Category of elements that have high densities and high melting points, and are solid at room temperature
Metals
30
Metalshave the ability to be deformed without breaking, like hammering it into different shapes. This characteristic ability of metals is called
Malleability
31
The ability of metal to be drawn into a wire
Ductility
32
Metals have a SMALL/LARGE atomic radius Metals have a HIGH/LOW IE Metals have a HIGH/LOW electronegativity These properties are explained by
Metals have a LARGE atomic radius Metals have a LOW IE Metals have a LOW electronegativity These properties are explained by the few electrons in the valence shell which can be easily removed.
33
Metals are BAD/GOOD conductors of electricity and heat? Why?
Metals are GOOD conductors of electricity and heat The valence electrons can move freely
34
Which metals are the most reactive metals?
Groups IA and IIA
35
This category of elements is brittle in the solid state and show little or no metallic luster.
Nonmetals
36
Nonmetals have HIGH/LOW IE Nonmetals have HIGH/LOW electronegativit Nonmetals are GOOD/POOR conductors of heat and electricity
Nonmetals have HIGH ionization energies Nonmetals have HIGH electronegativity Nonmetals are POOR conductors of heat and electricity (usually)
37
Name the one characteristic of nonmetals that they share, otherwise they have a wide range of chemical behaviors and reactivities
Nonmetals share the ability to gain electrons easily
38
The category of elements located along the line between the metals and nonmetals on the periodic table
Metalloids
39
Are metalloid properties universal or diverse?
Their properties vary considerably | Densities, BPs, and MPs
40
Metalloids have HIGH/LOW/INTERMEDIATE electronegativites and IEs
Intermediate between metals and nonmetals, they possess characteristics of both classes
41
What does the reactivity of metalloids depend pon?
The element with which they are reacting
42
B behaves as a nonmetal when reacting with... | B behaves as a metal when reacting with...
Na | F
43
Name the elements classified as metalloids
Boron, Silicon, Germanium, Arsenic, Antimony, Tellurium
44
The elements of group IA are referred to as
Alkali Metals
45
How do alkali differ from other metals? Why?
They have lower densities. They have one loosely bound electron in the valence shell, meaning they have the largest atomic radii in a period.
46
Alkali metals have ____ IEs Alkali metals have ____ electronegativity Alkali metals have _____ reactivity Why?
Low IEs Low electronegativity High reactivity They easily lose their valence electron
47
What group do alkali metals react easily with? Especially...
Nonmetals, especially halogens
48
The elements of group IIA are the...
Alkaline earth metals
49
Alkaine earths have a LARGER/SMALLER atomic radius than alkali metals
Smaller.
50
Can the two valence electrons of alkaline earths be removed to form divalent cations?
Yes.
51
Alkaline earths have _____ IEs | Alkaline earths have _____ electron affinities
Alkaline earths have LOW IEs | Alkaline earths have LOW electron affinities
52
Elements in group VIIA are the...
Halogens
53
Halogens have ____ reactivity Why?
Halogens have HIGH reactivity Seven electrons in the valence shell
54
In terms of physical properties, are the halogens uniform or diverse?
Halogens are highly variable. F2 and CL2 are gaseous, Br2 is liquid, I2 is solid at room temperature
55
Are the chemical properties of halogens uniform or diverse? What group of elements are halogens most reactive with?
Uniform. High electronegativities, high ionization energies Alkali Metals and Alkaline Earth metals (group IA and IIA)
56
The group of elements found in group VIIIA are the...
Noble Gases
57
The noble gases are REACTIVE/NONREACTIVE The noble gases have HIGH/LOW IEs The noble gases have HIGH/LOW electronegativities Why?
NONREACTIVE HIGH IEs NO ELECTRONEGATIVITIES Noble gases have a full valence shull
58
Groups IB to VIIIB are the
Transition metals.
59
The transition metals are very SOFT/HARD The transition metals have HIGH/LOW melting points Transition elements have HIGH/LOW IEs
The transition metals are very HARD The transition metals have HIGH BPs The transition metals have LOW IEs
60
Transition metals may exist in a variety of positively charged forms, aka Why?
Oxidation states Transition metals are capable of losing various numbers of electrons from the s and d orbitals of the valence shell
61
Dissolves ions of transition metals can form ____ with other molecules of water or with nonmetals Does the formation of complex ions increase or decrease the solubility of a compound?
Complex Ions It enhances the solubility
62
What gives the complex ions their characteristic colors?
The d orbitals split into two energy sublevels, enabling complexes to absorb certain frequencies of light. Those not absorbed are observed.