General Knowledge Flashcards

(66 cards)

1
Q

Area

A

L^2
cm^2

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2
Q

Volume

A

L^3
cm^3

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3
Q

Speed or velocity

A

L/T
cm/s

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4
Q

Acceleration

A

L/T^2
cm/s^2

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5
Q

Force

A

ma
g cm/s^2 or dynes

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6
Q

Pressure

A

F/A
dynes/cm^2 or g/cm s^2

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7
Q

Density

A

m/L^3
g/cm^3

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8
Q

Surface tension

A

F/L
dynes/cm or g/s^2

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9
Q

Work or energy

A

FL
dynes cm or erg

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10
Q

1 atm is equivalent to

A

760 torr or mmHg
76 cmHg
1.01325 x 10^6 dynes/cm^2
1.01325 x 10^5 N/m^2 or Pa
1.01325 bar

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11
Q

The gas constant (R) is equivalent to

A

0.08205 L-atm/n-K
8.314 m^3-Pa/n-K

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12
Q

Vapor pressure lowering

Vapor pressure

A

Vapor pressure of pure substance x mole fraction of solute

Vapor pressure of pure substance - change in vapor pressure

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13
Q

Boiling point elevation

Boiling point

A

Kbm

Boiling point of pure substance - change in boiling point

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14
Q

Freezing point depression

Freezing point

A

Kfm

Freezing point of pure substance - change in freezing point

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15
Q

Osmotic pressure

A

pi = mRT

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16
Q

Freezing point depression using Liso for electrolytes (Van’t Hoff)

Modified Van’t Hoff

A

ikfm

Liso m

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17
Q

Factors that affect solubility of gas in liquid (Henry’s Law)

A

Pressure
Temperature
Presence of dissolved substances

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18
Q

Factors affecting Le Chatelier’s Principle

A

Pressure
Temperature
Concentration chanage

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19
Q

Methods for determining specific gravity in solids

A

Hydrostatic balance method
Pynometer method
Graduated cylinder method
Immersion of solid in transparent liquid

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20
Q

Methods for determining specific gravity in liquids

A

Pycnometer using Leach pycnometer
Floatation method (hydrometers)
Constant weight with variable depth of immersion (Baume, Twaddell, Cartier, Gay-Lussac, Alcoholometer or Tralle’s hydrometer)
Constant depth of immersion with variable weight (Nicholson, Fahrenheit, Lovi’s beads, Mohr-Westphal balance)

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21
Q

Methods for determining specific gravity in manometric method

A

Fischer-Davidson gravitometer

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22
Q

Dipole-dipole is also known as

A

Keesom forces

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23
Q

Dipole-induced dipole is also known as

A

Debye forces

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24
Q

Induced dipole- induced dipole is also known as

A

Dispersion or London forces

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25
Factors affecting solubility
Temperature Polarity and Hydrogen Bonding Particle size
26
Factors affecting drug dissolution
Physicochemical Physiological Formulation
27
Unit of kinematic viscosity
Stokes or centistokes
28
Unit of absolute viscosity
Poise or centipoise dynes s/cm^2
29
Unit of relative viscosity
No unit
30
Examples of plastic flow
Ointments Pastes Creams Cataplasms Cerates Butter Margarine
31
Examples of pseudoplastic flow
Natural and synthetic gums Liquid dispersion of tragacanth, sodium alginate, methylcellulose
32
Examples of dilatant flow
Paint Suspension (>50% conc)
33
Examples of thixotropy
Aqueous dispersion of sodium bentonite, colloidal SiO2, magnesium bentonite
34
Instruments for determining viscosity (Single point) Instruments for determining viscosity (Multi point)
Capillary viscometer (Ostwald, Saybolt, Falling sphere, Hoppler) Cup and bob viscometer (Searle and Couette) Cone and plate viscometer (Ferranti-Shirley)
35
Searle type cup and bob viscometers
Stormer Haake-Rotovisko Brookefield synchro-lectric
36
Couette type cup and bob viscometer
MacMichael, Coaxial cylinder
37
Instrument used to measure viscosity for ointments
Penetrometer
38
Span 20
Sorbitan monolaurate
39
Span 40
Sorbitan monopalmitate
40
Span 60
Sorbitan monostearate
41
Span 65
Sorbitan tristearate
42
Span 80
Sorbitan monooleate
43
Span 85
Sorbitan trioelate
44
Tween 20
Polyoxyethylene sorbitan
45
Tween 40
Polyoxyethylene sorbitan monopalmitate
46
Tween 60
Polyoxyethylene sorbitan monostearate
47
Tween 65
Polyoxyethylene sorbitan tristearate
48
Tween 80
Polyoxyethylene sorbitan monooleate
49
Tween 85
Polyoxyethylene sorbitan trioleate
50
Brij 30
Polyoxyethylene lauryl ether
51
Brij 72
Polyoxyethylene stearyl ether
52
Brij 92
Polyoxyethylene oleyl ether
53
Ariacel 83
Sorbitan sesquioleate
54
Myri 45
Polyoxyethylene monostearate
55
Poiseuille's Method
r^5 (density x time x pi)/ 8 (volume x length)
56
Methods of determining surface tension
Capillary rise Du Nuoy tensiometer (ring method) Drop weight Bubble pressure Sessile drop Wilhemy plate
57
Capillary rise method
1/2 hdgr g is gravity constant r is radius of capillary refill
58
Instrument used for sedimentation
Andreasen apparatus
59
Instrument used for particle volume measurement
Coulter counter
60
Stoke's Law
dx/dt= V = h/t= d^2 (density in dispersed phase - density of dispersion medium) g/ 18 (absolute viscosity)
61
Porosity of voids formula
void vol/ bulk vol bulk - true/ bulk vol x 100
62
Derived properties of powder
Porosity or voids Packing arrangement Density Flow properties
63
Factors affecting sedimentation
Particle size and density Viscosity of the medium
64
NaCl equivalent method
(mol wt of NaCl/ i of NaCl) x (i of subs/ mol of subs)
65
First order sample reactions
Decay of radioactive atoms Decomposition Hydrolysis (pseudo-first)
66
Second order sample reactions
Combination of hydrogen and oxygen Decomposition of HI Hydrolysis of ester in alkaline solution