Group 2 elements Flashcards

(31 cards)

1
Q

atomic radius _ down group 2

because:

A

increases

energy level added and hence weaker force of attraction felt

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2
Q

metallic radius is measure of

A

size

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3
Q

melting point _ down group 2

and why

A
decreases 
delocalised electrons (in their own energy level) are further away from nucleus and strength of metallic bond decreases
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4
Q

density _ down group 2

why?

A

increases Generally

as atomic radius increases so do mass and volume but mass at greater rate which is proportional to density

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5
Q

how do group 2 elements react

A

lose 2 electrons from S-orbital

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6
Q

group 2 reactivity _ down the group

why?

A

increases
there is greater shielding effect and distance because of increased energy levels hence easier to remove outer shell electron

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7
Q

ionisation energy _ down the group

A

decreases

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8
Q

group 2 metals burn in oxygen to form _ which is _ in nature

A

white solid oxide

basic (dissolve to form hydroxide)

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9
Q

reactivity of metals with water down the group _ and forms _

A

increases

metal hydroxide

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10
Q

metals react with steam to form

A

metal oxide and H2 gas

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11
Q

use of calcium oxide

A

used to neutralise acid in soil

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12
Q

why beryllium is not an alkali earth metal

A

amphoteric rather than alkaline behvaior of compounds

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13
Q

reactivity with oxygen _ down group

A

increases

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14
Q

barium stored in oil because

A

rapidly vigourously reacts with O2 in air

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15
Q

flame test of Ca, Sr, Ba, Mg compounds

A
Burn in O2:
Ca- brick red color
Sr- red
Ba- light green 
Mg- white
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16
Q

How metals burn at atomic level

A

metal loses 2e- and donates to O

17
Q

alkalinity _ down group because ..

A

increases

cos solubility increases down group: more soluble=more dissociation/able to donate more OH-

18
Q

alkalinity _ down group because …

A

increases
cos solubility of hydroxides increases down group: more soluble=more dissociation/able to donate more OH-

white ppt (as not transition) or sol

19
Q

solubility of hydroxides and sulfates(why for this) _ down

A

hydroxide- inc
sulfates- dec bcos lattice energy and enthalpy change of hydration decrease hence applying hess law the value of enthalpy chnage of solution becomes more endothermic

20
Q

carbonates of grp 2 are _ in water

21
Q

carbnotes react with dil acid to give

22
Q

which grp 2 sulfates (formed from reacting with dil h2so4) are sol and insol

A

mgso4-sol

rest-insol

23
Q

grp 2 nitrate salts are _ in water

24
Q

thermal decomposition of grp 2 carbonates

A

give off metal oxide + co2

25
thermal decomposition of grp 2 nitrates
metal oxide + no2 + o2
26
temperature of thermal decomposition _ down grp
increases
27
stability of nitrates _ down group hence _ temp required
increases | higher
28
uses of CaCO3, Ca(OH)2
CaCO3- rocks for building, marble for tiles, cement making | Ca(OH)2- neutralize soil aka slaked lime
29
cement making:
high temp of kiln CaCO3 decomposes to CaO+CO2 and the quick lime is roasted with clay to make cement -cement can be mixed with sand to increase strength
30
why does solubility of sulfates decrease down group
1) larger the cation, weaker lattice so lattice energy decreases as becomes less endo 2) weaker cations bond with water less exo so E change of hydration decreases hence E of sol becomes more endothermic hence more difficult to dissolve so 1 has mor value than 2 relatively because 1 decreases less compared to 2
31
process of hydroxides dissolving
ionic lattice breaks as ions dislodge as water attracts ions. this process is endo to break ionic bonds then new bonds between ions and polar water are formed