Group 7 Flashcards

1
Q

What type of molecule are halogens?

A

diatomic molecules

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2
Q

What is the appearance of fluorine at room temperature?

A

pale yellow gas

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3
Q

What is the appearance of chlorine at room temperature?

A

greenish gas

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4
Q

What is the appearance of bromine at room temperature?

A

red-brown liquid

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5
Q

What is the appearance of iodine at room temperature?

A

black solid

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6
Q

How does atomic radius change down the halogens?

A

atoms bigger
each element has extra filled main level to previous

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7
Q

What is the trend in electronegativity down the halogens?

A

decreases

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8
Q

Why does electronegativity decrease down the group?

A

shared electrons become further from halogen nucleus
increased shielding from inner shells

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9
Q

How does melting and boiling points change down Group 7?

A

Increase

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10
Q

Why does the melting and boiling point increase down Group 7?

A

atoms are larger
more electrons
stronger van der Waals forces

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11
Q

How does oxidising ability change down Group 7?

A

decreases from F>Cl>Br>I

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12
Q

Are halogens reduced or oxidised?

A

reduced

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13
Q

What happens in a halide halogen displacement reaction?

A

Halide in compound displaced by more reactive halogen

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14
Q

How does fluorine react with a fluoride ion?

A

no reaction

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15
Q

How does fluorine react with a chloride ion?

A

oxidises

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16
Q

How does fluorine react with a bromide ion?

A

oxidises

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17
Q

How does fluorine react with an iodide ion?

A

oxidises

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18
Q

How does chlorine react with a fluoride ion?

A

isn’t oxidised

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19
Q

How does chlorine react with a chloride ion?

A

no reaction

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20
Q

How does chlorine react with a bromide ion?

A

oxidises

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21
Q

How does chlorine react with an iodide ion?

22
Q

How does bromine react with a fluoride ion?

A

isn’t oxidised

23
Q

How does bromine react with a chloride ion?

A

isn’t oxidised

24
Q

How does bromine react with an iodide ion?

25
How does iodine react with a fluoride ion?
Isn’t oxidised
26
How does iodine react with a chloride ion?
Isn’t oxidised
27
How does iodine react with a bromide ion?
isn’t oxidised
28
How does iodine react with an iodide ion?
no reaction
29
How does bromine react with a bromide ion?
no reaction
30
What do halide ions act as?
Reducing agents
31
How does reducing power change down Group 7?
increases from F>Cl>Br>I
32
How does sodium chloride react with sulfuric acid?
NaCl (s) + H2SO4 (l) > NaHSO4 (s) + HCl (g)
33
What are the products for the reaction between sodium chloride and sulfuric acid?
steamy fumes of hydrogen chloride and solid sodium hydrogensulfate
34
How does sodium bromide react with sulfuric acid?
1: NaBr (s) + H2SO4 (l) > NaHSO4 (s) + HBr (g) 2: 2H+ + 2Br- + H2SO4 (l) > SO2 (g) + 2H2O (l) + Br2 (l)
35
What are the products of the reaction between sodium bromide and sulfuric acid?
solid sodium hydrogensulfate, steamy fumes of hydrogen bromide and colourless sulfur dioxide
36
How does sodium iodide react with concentrated sulfuric acid?
1: Na(s) + H2SO4(l) > NaHSO4(s) + HI (g) 2: 8H+ + 8I- + H2SO4(l) > H2S(g) + 4H2O(l) + 4I2(s) 3: H2SO4(l) + 2I- + 2H+ > SO2(g) + I2(s) + 2H2O(l) 4: H2SO4(l) + 6I- + 6H+ > S(s) + 3I2(s) + 4H2O(l)
37
What are the products in the reaction between sodium iodide and concentrated sulfuric acid?
solid hydrogensulfate, hydrogen iodide, hydrogen sulfide, sulfur, iodine, sulfur dioxide
38
How are metal halides identifies through the use of silver ions?
1. Dilute nitric acid to halide solute to remove carbonate and hydroxide impurities 2. Few drops of silver nitrate 3. Precipitate will form
39
What precipitate does chlorine form?
White
40
What precipitate does fluorine form?
No precipitate
41
What precipitate does bromine form?
Cream
42
What precipitate does iodine form?
Pale yellow
43
How can we test further with a chlorine precipitate?
dissolved in dilute ammonia
44
How can we test further for a bromine precipitate?
dissolves in concentrated ammonia
45
How can we test further with iodine precipitate?
Insoluble
46
How does chlorine react with water?
Cl2(g) + H2O(l) <> HClO(aq) + HCl(aq)
47
What is produced in the reaction between water and chlorine?
chloric (I) acid and hydrochloric acid
48
What is chlorine used for?
Prevent life threatening diseases Treats water by killing bacteria/microorganisms
49
What does chloric acid do?
Acts as oxidising agent which kills bacteria
50
What alternative reaction shows how water exposed to sunlight is chlorinated?
NaClO(s) + H2O(l) <> Na+(aq) + OH-(aq) + HClO(aq)