group15_flashcards

(15 cards)

1
Q

Which elements belong to Group 15 of the periodic table?

A

N, P, As, Sb, Bi

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2
Q

What is the general electronic configuration of Group 15 elements?

A

ns² np³

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3
Q

Why does nitrogen not form pentahalides?

A

Because nitrogen lacks d-orbitals.

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4
Q

Which Group 15 element has the highest ionization enthalpy?

A

Nitrogen

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5
Q

Order the thermal stability of MH₃ (Group 15 hydrides) from highest to lowest.

A

NH₃ > PH₃ > AsH₃ > SbH₃ > BiH₃

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6
Q

Which nitrogen oxides are neutral?

A

N₂O and NO

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7
Q

What hybridization and geometry does PCl₅ have?

A

sp³d; trigonal bipyramidal

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8
Q

Name the process used to prepare nitric acid industrially.

A

Ostwald Process

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9
Q

Which nitrogen oxide is paramagnetic and dimerizes?

A

NO₂ → N₂O₄

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10
Q

What is the basicity of orthophosphoric acid?

A

3 (three ionizable OH groups)

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11
Q

Which compound evolves PH₃ when reacted with water?

A

Ca₃P₂ + H₂O → PH₃ + Ca(OH)₂

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12
Q

List the acid strength order of E₂O₅ oxides in Group 15.

A

N₂O₅ > P₂O₅ > As₂O₅ > Sb₂O₅ > Bi₂O₅

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13
Q

What complex ions can ammonia form?

A

[Ag(NH₃)₂]⁺, [Cu(NH₃)₄]²⁺

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14
Q

What are the oxidation states shown by Group 15 elements?

A

-3, +3, +5

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15
Q

Which Group 15 hydride has the highest basicity?

A

NH₃

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