group15_flashcards
(15 cards)
Which elements belong to Group 15 of the periodic table?
N, P, As, Sb, Bi
What is the general electronic configuration of Group 15 elements?
ns² np³
Why does nitrogen not form pentahalides?
Because nitrogen lacks d-orbitals.
Which Group 15 element has the highest ionization enthalpy?
Nitrogen
Order the thermal stability of MH₃ (Group 15 hydrides) from highest to lowest.
NH₃ > PH₃ > AsH₃ > SbH₃ > BiH₃
Which nitrogen oxides are neutral?
N₂O and NO
What hybridization and geometry does PCl₅ have?
sp³d; trigonal bipyramidal
Name the process used to prepare nitric acid industrially.
Ostwald Process
Which nitrogen oxide is paramagnetic and dimerizes?
NO₂ → N₂O₄
What is the basicity of orthophosphoric acid?
3 (three ionizable OH groups)
Which compound evolves PH₃ when reacted with water?
Ca₃P₂ + H₂O → PH₃ + Ca(OH)₂
List the acid strength order of E₂O₅ oxides in Group 15.
N₂O₅ > P₂O₅ > As₂O₅ > Sb₂O₅ > Bi₂O₅
What complex ions can ammonia form?
[Ag(NH₃)₂]⁺, [Cu(NH₃)₄]²⁺
What are the oxidation states shown by Group 15 elements?
-3, +3, +5
Which Group 15 hydride has the highest basicity?
NH₃