HALOALKANES Flashcards

(48 cards)

1
Q

What are alkyl halides or haloalkanes?

A

Organic compounds in which a halogen atom is bonded to an alkyl group.

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2
Q

What is the general formula for haloalkanes?

A

R-X

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3
Q

What is the IUPAC name for CH2-CH-Br?

A

Bromoethane

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4
Q

What is the common name for CH2-CH-Br?

A

Ethyl bromide

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5
Q

True or False: Alkyl halides are classified under haloalkanes.

A

True

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6
Q

Fill in the blank: The IUPAC name for an alkyl halide is also known as a _______.

A

Haloalkane

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7
Q

What are haloalkanes classified based on?

A

The number of carbon atoms to which the halogen linked carbon is bonded.

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8
Q

Define primary haloalkane.

A

A haloalkane in which halogen linked carbon is bonded to none or one other carbon atom.

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9
Q

Provide an example of a primary haloalkane.

A

CH3-CH2-Br (Bromoethane)

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10
Q

Define secondary haloalkane.

A

A haloalkane in which halogen linked carbon is further bonded to two other carbon atoms.

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11
Q

Fill in the blank: A primary haloalkane is also known as a ______ haloalkane.

A

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12
Q

Fill in the blank: A secondary haloalkane is also known as a ______ haloalkane.

A

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13
Q

What is a tertiary haloalkane?

A

A haloalkane in which the halogen-linked carbon is further bonded to three other carbon atoms.

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14
Q

Provide an example of a tertiary haloalkane.

A

2-chloro-2-methylpropane.

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15
Q

What is the structural formula for 2-bromobutane?

A

CH3-CH2-CHBr-CH3.

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16
Q

What is the structural formula for 2-bromo-2-methylbutane?

A

CH3-CH2-C(Br)-CH3.

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17
Q

Define haloalkanes.

A

Compounds containing carbon, hydrogen, and halogen atoms.

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18
Q

What is the common system used in the nomenclature of haloalkanes?

A

AaBbCcD.

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19
Q

True or False: A secondary haloalkane is bonded to two other carbon atoms.

A

True.

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20
Q

Fill in the blank: A haloalkane in which the halogen is attached to a carbon that is bonded to one other carbon atom is known as a _______.

A

primary haloalkane.

21
Q

What is a tertiary haloalkane?

A

A haloalkane in which the halogen-linked carbon is further bonded to three other carbon atoms.

22
Q

Provide an example of a tertiary haloalkane.

A

2-chloro-2-methylpropane.

23
Q

What is the structural formula for 2-bromobutane?

A

CH3-CH2-CHBr-CH3.

24
Q

What is the structural formula for 2-bromo-2-methylbutane?

A

CH3-CH2-C(Br)-CH3.

25
Define haloalkanes.
Compounds containing carbon, hydrogen, and halogen atoms.
26
What is the common system used in the nomenclature of haloalkanes?
AaBbCcD.
27
True or False: A secondary haloalkane is bonded to two other carbon atoms.
True.
28
Fill in the blank: A haloalkane in which the halogen is attached to a carbon that is bonded to one other carbon atom is known as a _______.
primary haloalkane.
29
How are haloalkanes named in the common system?
Haloalkanes are named by adding the word 'halide' after the name of the alkyl group. ## Footnote Common names are always written as two separate words.
30
What prefixes are commonly used in naming haloalkanes?
The words n-, sec-, tert-, iso-, and neo- are usually used in writing the common names.
31
How are haloalkanes named in the IUPAC system?
Haloalkanes are named by adding the prefix 'halo-' before the name of the parent alkane. ## Footnote The IUPAC name of any monohalo alkane is always written as one word.
32
What is the common name for CH3-CH2-Br?
The common name is Ethyl bromide.
33
What is the IUPAC name for CH3-CH2-Br?
The IUPAC name is bromoethane.
34
What is the common name for CH3-CH2-CH2-I?
The common name is n-propyl iodide.
35
What is the IUPAC name for CH3-CH2-CH2-I?
The IUPAC name is 1-iodopropane.
36
What is the common name for CH3-CH-CH3?
The common name is Isopropyl chloride.
37
What is the IUPAC name for CH3-CH-CH3?
The IUPAC name is 2-chloropropane.
38
What is the common name for CH3-CH2-CH2-CH2-Br?
The common name is n-butyl bromide.
39
What is the IUPAC name for CH3-CH2-CH2-CH2-Br?
The IUPAC name is 1-bromobutane.
40
What is the IUPAC name for CH3-CH-CH2-Br?
The IUPAC name is 2-bromobutane.
41
What are polyhalogen compounds?
Organic compounds containing more than one halogen atom in their molecules. ## Footnote Example: 2-bromo-2-methylpropane, 1-bromo-2-methylpropane.
42
What is the IUPAC name for tert-butyl bromide?
tert-butyl bromide.
43
What is the IUPAC name for isobutyl bromide?
Isobutyl bromide.
44
What is the IUPAC name for neopentyl bromide?
Neopentyl bromide.
45
What is the structural formula of sec-pentyl chloride?
To be determined based on the molecular structure.
46
What is the structural formula of tert-pentyl chloride?
To be determined based on the molecular structure.
47
What does 'iso' indicate in organic chemistry?
1° (if the second last carbon contains one methyl group and no other branches).
48
What does 'neo' indicate in organic chemistry?
1° (if the second last carbon contains two methyl groups and no other branches).