halogenalkanes Flashcards
(6 cards)
what is nucleophillic substitution
when the halogen is substituted to snother group (OH/CN/NH2)
what are the reagents and conditions for nucleophilic substitution forming an alcohol
reagent: NaOH
conditions: warm, aqueous
what are the reagents and conditions for nucleophilic substitution forming a nitrile
reagent:KCN
conditions: aqueous ethanol
what are the reagents and conditions for nucleophilic substitution forming an amine
reagent: NH3
conditions: excess NH3
what are the reagents and conditions for elimination
reagent: NaOH
conditions: hot, in ethanol
what factors affect substitution/elimation
the structure of the halogenalkanes
-primary halogensalkanes (RCH2X) favour substitution
-secondary halogenalkanes (R2CHX) favour both
-tertiary halogenalkanes (R3CX)
the base strength of the nucleophile
-aqueous = substitution
-ethsnolic = elimination
the reaction conditions
-hot = elimination
-warm = substitution