halogenalkanes Flashcards

(6 cards)

1
Q

what is nucleophillic substitution

A

when the halogen is substituted to snother group (OH/CN/NH2)

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2
Q

what are the reagents and conditions for nucleophilic substitution forming an alcohol

A

reagent: NaOH
conditions: warm, aqueous

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3
Q

what are the reagents and conditions for nucleophilic substitution forming a nitrile

A

reagent:KCN
conditions: aqueous ethanol

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4
Q

what are the reagents and conditions for nucleophilic substitution forming an amine

A

reagent: NH3
conditions: excess NH3

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5
Q

what are the reagents and conditions for elimination

A

reagent: NaOH
conditions: hot, in ethanol

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6
Q

what factors affect substitution/elimation

A

the structure of the halogenalkanes
-primary halogensalkanes (RCH2X) favour substitution
-secondary halogenalkanes (R2CHX) favour both
-tertiary halogenalkanes (R3CX)

the base strength of the nucleophile
-aqueous = substitution
-ethsnolic = elimination

the reaction conditions
-hot = elimination
-warm = substitution

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