Halogenoalkanes Flashcards
what does halogenoalkanes contain ?
saturated hydrocarbon chains with a carbon atom bonded to a halogen atom ( F, CI, Br or I )
what bonds do halogenoalkanes contain ? why ?
polar bonds since the halogens are more electronegative than a carbon atom
- electron density is drawn towards the halogen, forming delta positive and negative regions
how do we make halogenoalkanes ?
ethane + chlorine - >
chloroethane + HCI
condition: UV
how do we make halogenoalkanes ?
ethene + hydrogen bromide - >
bromoethane
physical properties of halogenoalkanes
they have a higher boiling point than their analogous alkane because the polarity of the carbon - halogen bond leads to stronger intermolecular forces
- there are more electrons so London forces are stronger
why are halogen carbon bonds polar ?
due to the greater electronegativity of the halogen atom this leads to a much stronger pd- pd interaction
as alkyl chain length increases what happens to the solubility ?
it decreases
is halogenoalkanes more/ less soluble compared to analogous alkanes ?
more because more similar intermolecular forces with the solvent means greater solubility
what forces makes halogenoalkanes more soluble in water than alkanes
PD - PD forces - must form hydrogen bonds
what is an elimination ?
a reaction which produces an unsaturated product by loss of atoms or groups
what is a base ?
a chemical species with a pair of electrons to remove a hydrogen ion
how are halogenoalkanes usually attacked by ?
nucleophiles
what is hydrolysis ?
a reaction in which a compound is split apart in a reaction with water
what solution is a good test for the presence of halogenoalkanes ?
aqueous silver nitrate
what does AgCI make ?
white
