Halogenoalkanes Flashcards
(11 cards)
-:OH
Name
Conditions
Product
Sodium hydroxide
Most be dissolved in water 60°
Alcohol
Halogenoalkanes must be dissolved in
Ethanol
-:CN/ -:C≡N
Name
Conditions
Product
Cyanide
Ethanol solvent 60°
Nitrile
Ah important thing to notice about a cyanide reaction
Carbon chain length increases by one carbon
:NH3
Name
Conditions
Product
Ammonia
Ethanol solvent 60°
Ammonia must be in excess for one to acts a nucleophile and some other to act as a base
Amine
Why is ethanol added in hydrolysis of halogenoalkanes
To dissolve the halogenoalkanes
As they are insoluble in water
Explain the reactivity of halogenoalkanes
Going down the group bond length increases
Bond strength decreases due to the share pair of electrons in the C-hal bond gets further away from nuclei ( c and hal)
The electrostatic attraction between the bonding pair and the nucleus is decreases
Chloro
White 3
Bromo
Cream 2
Iodo
Yellow 1
Conditions for elimination mechanisms
High temperature -hot
Ethanol -ethanolic (dissolved in Ethanol only no water present)
No water