Halogenoalkanes Flashcards
(8 cards)
Halogenoalkanes from alkanes
Radical substitution
Halogenoalkanes from alkenes
Electrophyllic addition
Reactions of halogenoalkanes
Elimination
Substitution
Reflux reaction uses a..
Reflux condenser
NaOH(aq) + HNO3(aq) + AgNO3(aq) with chloroalkane, bromoalkane and iodoalkane
Chloroalkane = white ppt dissolves in dilute ammonia solution Bromoalkane = cream ppt dissolves in concentrated ammonia solution Iodoalkane = primrose yellow ppt doesn't dissolve in ammonia solution
Rate of hydrolysis
Iodo>bromo>chloro
As C-Cl is most polar (stronger bonds to break)
CFCs were used as propellants, effect on ozone layer
C-Cl bonds broken by UV light: Cl•+O3-->ClO•+O2 UV light in upper atmosphere breaks down O2: O2-->2O React with radicals: ClO•+O-->O2+Cl•
CFCs replaces with…
HCFCs