Halogens Flashcards

(30 cards)

1
Q

What are the group 7 elements?

A

Chlorine, Florine Iodine and Bromine

~they exist as diatomic

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2
Q

What are the different types of halite ions?

A

Bromide
Chloride
Iodide

  • they exist as single ions with a charge -1
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3
Q

Reactivity series of halogens?

A
  1. 2.
    3.

*More reactive halogen displaces weaker halogens

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4
Q

What colour is produced when chlorine and KBR reacts? Why does it change this color? Give equation ionic/symbol:

A

Orange solution - Because bromine is the product in the reaction

{ Cl2 + 2KBR -> Br2 + 2KCL }

ionic: { Cl2 + Br-
- -> Br2 + 2Cl-}

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5
Q

What happens when chlorine and potassium iodine?

A

Brown solution

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6
Q

What happens when bromine reacts with potassium iodide?

A

Brown Solution

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7
Q

What is the formation of bleach?

A

2NaOH + Cl2 –> NaClO + NaCl +

H20

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8
Q

What is bleach used for?

A

Cleaning

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9
Q

What is a disproportionation reaction?

A

Is a reaction were same thing is oxidized and reduced

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10
Q

What is the word equation for chlorine and water?

A

Cl2 + H20 ⇌ HClO (chloric 1 acid) + HCl

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11
Q

Why is chlorine used to treat water?

A

They benefit outweighs the risk

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12
Q

Why is chlorine used to treat water?

A

It kills bacteria making it clean preventing spread of disease

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13
Q

What are the disadvantages of using chlorine to treat water?

A

It is toxic

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14
Q

What is a reducing agent?

A

a substance that tends to bring about reduction by being oxidized and losing electrons.

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15
Q

Are halides reducing agents?

True/False

A

True

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16
Q

What happens when halide and sulfuric acid reacts?

A

metal halide + sulfuric acid —> metal sulfate + hydrogen halide

e.g.

NaCl + H2SO4 –> NaHSO4 + HCl

17
Q

Why is a reaction between metal halides and sulfuric acid non redox?

A

This is because there no change in oxidation states

18
Q

What is released between a reaction with sulfuric acid and metal halide?

A

Misty White Fumes

19
Q

What happens during reaction of hydrogen bromine and sulfuric acid?

A

2HBr + H2SO4 —-> Br2 + SO2 + 2H20

20
Q

Is hydrogen bromide and sulphric acid a redox reaction?

TRUE/ FALSE

21
Q

What happens when you react hydrogen halide and sulfuric acid?

A

hydrogen halide + sulfuric acid —> halogen + sulfuric oxide + water

e.g.

2HI + H2SO4 —> I2 + SO2 + 2H20

22
Q

What happens when you react hydrogen halide and sulfur oxide?

A

hydrogen halide + sulfur oxide –> hydrogen halide + halogen + water

e.g.

6HI + SO2 –> H2S + 3I2 + 2H20

23
Q

How do you test for halides?

A

Add Nitric Acid (HNO3) and Silver Nitrate (AgNO3)

If present:
Chlorine - White precipitate

Iodide - Yellow Precipitate

You can conduct an ammonia (NH3) test:

Chlorine - dissolves in dilute ammonia

Bromine - dissolves in concentrated ionic ammonia

Iodine - does not dissolve in ammonia

24
Q

What is the the generic symbol equation for halide test?

A

Ag+ (+) X- —-> AgX

X = Halide

25
Halogen order according to reducing power
1. Iodine (Largest) 2. Bromine 3. Chlorine (Weakest)
26
What is the trend in boiling point as you go down group 7? Why?
The boiling point increases - this is because van der walls forces increase due to the increasing size and relative mass of atoms
27
How does states change as you go down group 7?
gas at the top and solid at the bottom
28
How does electronegativity change as you go down the group? Why?
As you go down elecronegativity decreases - This is because the larger the atom the distance between positive nucleus and bonding electrons increase know as shielding
29
What is electronegativty?
Is the ability for an atom to attract electrons towards its' covalent bond
30
What happens with reactivity as you go down group 7?
Reactivity decreases