heat and mass Flashcards

(35 cards)

1
Q

What is evaporation?

A

The phenomenon of change of a liquid into its vapors at any temperature below its boiling point.

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2
Q

What is the main operation in evaporation processes?

A

The removal of large amounts of water from solution.

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3
Q

What is a typical industrial application of evaporation?

A

Concentration of aqueous solutions of fruit juices, sodium hydroxide, sodium chloride, sugar, glycerol, glue, and milk.

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4
Q

What are the main benefits of evaporation?

A
  • Reduction in mass and volume
  • Preservation by reduced water activity
  • Required operation for other treatments like crystallization
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5
Q

What is the difference between evaporation and drying?

A
  • Evaporation removes large amounts of water from liquids
  • Drying removes small amounts of water from solids
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6
Q

What factors affect evaporation?

A
  • Solubility
  • Temperature sensitivity of material
  • Foaming or frothing
  • Pressure and temperature
  • Scale deposition
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7
Q

How does solubility affect evaporation?

A

The maximum concentration of solution obtained depends on the solubility of the solute in the solution.

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8
Q

What is boiling-point-rise (BPR)?

A

The phenomenon where the boiling point of the solution may rise as evaporation proceeds.

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9
Q

What is the role of pressure in evaporation?

A

The higher the operating pressure, the higher the boiling temperature of the solution.

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10
Q

What are the general types of evaporators?

A
  • Open Kettle or Pan Evaporator
  • Horizontal Tube Evaporator
  • Short Tube Vertical Evaporator
  • Falling Film Evaporator
  • Forced Circulation Evaporators
  • Agitated Thin Film Evaporator
  • Open-pan Solar Evaporator
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11
Q

What characterizes an Open Kettle or Pan Evaporator?

A

It consists of an open pan where liquid is boiled, often operated at atmospheric pressure or under vacuum.

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12
Q

How does a Horizontal Tube Evaporator work?

A

The feed solution is inside the tubes, and steam condenses outside, causing liquid to rise naturally.

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13
Q

What is a Short Tube Vertical Evaporator known for?

A

It uses the formation of vapor bubbles to give rise to high liquid velocities and is suitable for foamy liquids.

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14
Q

What is the purpose of a Falling Film Evaporator?

A

The liquid flows down the inner wall of vertical tubes as a film, allowing for rapid vaporization and concentration.

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15
Q

What is a Forced Circulation Evaporator used for?

A

To concentrate highly viscous solutions by pumping liquid to enhance heat transfer.

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16
Q

What is the significance of mechanical agitation in an Agitated Thin Film Evaporator?

A

It improves the heat transfer coefficient by spreading the feed as a thin film on the heating surface.

17
Q

What is a Single-effect evaporator?

A

An evaporator used when the required capacity is small or steam is cheap, with all operations occurring in one effect.

18
Q

What is Multiple effect evaporation?

A

A process where vapors produced in one effect are reused to heat the feed in the next effect, improving steam economy.

19
Q

What is the steam economy formula?

A

Steam economy = kg of vapor produced / kg of steam used.

20
Q

What defines Forward-feed Multiple-effect Evaporators?

A

Both feed and steam are introduced in the first effect, with the boiling temperatures decreasing from effect to effect.

21
Q

What is a key characteristic of Backward-feed Multiple-effect Evaporators?

A

The feed enters the last effect first, allowing for a more concentrated solution to be produced as it moves backward.

22
Q

What is the last effect under when using steam at a pressure of 1 atm?

A

Under vacuum pressure

Vacuum pressure is used to prevent damage to the final concentrated product at high temperatures.

23
Q

In backward feed multiple-effect evaporators, where does the feed enter?

A

The last effect (coldest effect)

This arrangement allows effective concentration due to high heat availability in the first effect.

24
Q

What happens to viscosity in backward feed multiple-effect evaporators?

A

Viscosity reduces from effect to effect

High temperature in the first effect significantly reduces viscosity.

25
In mixed feed multiple-effect evaporators, where does the dilute feed liquid enter?
An intermediate effect ## Footnote This allows for further concentration of the liquor before being pumped back.
26
What is the main advantage of the mixed feed arrangement in multiple-effect evaporators?
It eliminates some pumps needed in backward configuration ## Footnote Flow occurs due to pressure difference whenever applicable.
27
In parallel feed multiple-effect evaporators, what is introduced in each effect?
Fresh feed ## Footnote Products are withdrawn from the same effect, and there is no liquid transfer between effects.
28
What is the typical condition of vapors from the last effect in multiple-effect evaporators?
Usually under vacuum ## Footnote These vapors must be condensed and discharged as liquid at atmospheric pressure.
29
What is a surface condenser?
A type of condenser where vapor and cooling water are separated by a metal wall ## Footnote This prevents mixing and is often a shell and tube design.
30
What types of noncondensable gases may be present in the vapor stream?
* Air * CO2 * N2 * Other gases ## Footnote These gases can enter as dissolved gases or from decomposition.
31
What is the energy balance equation for direct contact condensers?
Heat IN = Heat OUT ## Footnote This relationship involves vapor and cooling water flow rates.
32
How does feed temperature affect evaporator design?
Lower feed temperature requires more heat to reach boiling ## Footnote This may necessitate a larger heat transfer area.
33
What is boiling point elevation (BPR)?
The difference between the boiling temperature of a solution and that of pure water at the same pressure ## Footnote BPR increases as the solution becomes more concentrated.
34
What does Duhring’s chart represent?
The relationship between the boiling point of a pure liquid and that of a mixture ## Footnote It is used for estimating boiling point rise (BPR).
35
Fill in the blank: The pressure in an evaporator for a solution of 30% NaOH is given as ______.
25.6 kPa (0.256 bar) ## Footnote This pressure is crucial for determining the boiling point and BPR of the solution.