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JEE Chemistry > Hydrocarbons > Flashcards

Hydrocarbons Flashcards

becz, zindagi jhandwa. (118 cards)

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1
Q

2(Vicinal Di Halide)+ Zn Dust

A

Alkane–>Alkyne

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2
Q

Geminal Di Halide

A

Alkane–>Alkyne

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3
Q

Geminal Di Halide + NaNH2(base)

A

Remove Halide–> Bond–> all halide removed–> negative on suitable C atom

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4
Q

Calcium Carbide(CaC2)+H20

A

Ethyne

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5
Q

2(same C atom with 3 halides) + 6Ag

A

Alkyne

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6
Q

Mg2C3+H20

A

Propyne Major, di Ethyne minor

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7
Q

Alkyne+HX

A

On same C atom, 2 X add

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8
Q

Propyne+ (H2O H2SO4 Hg+2)

A

propanone

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9
Q

Propyne+(Cl2+H2O)

A

3,3 dichloropropan-2one

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10
Q

Propyne+(Cl2+CCl4)

A

bond wle carbon pr 2 Cl each

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11
Q

C–C(triple bond)C+ Ch3COOH

A

C—-C(double b)C—O—–C(double b)O—C

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12
Q

C–C(triple bond)C + AsCl3 (ASCl2+ + Cl-)

A

C—C(Cl)===C—-AsCL2

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13
Q

Cold Alk KMnO4 in alkyne

A

Double bond O on bonded C’s

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14
Q

3C(triple bond)C + Red Hot Fe Tube

A

Benzene

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15
Q

3Propyne + Red Hot Fe Tube

A

Benzene Alt CH3 ya for Benzene nearby 2 CH3 aur ek chodhke CH3

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16
Q

4Ethyne + Ni(CN)2

A

Cyclo Octene Alternate bond wli, 16 Annulene

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17
Q

nC(triple B)C + H2

A

Polymerisation with double bond

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18
Q

2(CtripleC) + CH2Cl2

A

c===c—c triple c

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19
Q

Alkyl Halide+ Alc. KOH–>

A

Double Bond

B elimination)( Bulky base, SIde se H lega)

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20
Q

viccinal Di halide + Zn Dust

A

Alkene

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21
Q

Alcohol–> H2SO4/[H+]

A

Double bond

[Carbocation formation and rearrangement exists]

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22
Q

Alkyl viccinal Di Carboxylic Acid + Electrolysis

A

Double bond

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23
Q

Alkyne+ H2/Ni 1 eq

A

Double bond

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24
Q

Alkyne+ H2 Pd BaSO4 quinoline

A

Cis Alkene

, Lindlar’s Catalyst

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25
Alkyne+ NH3 Na Li
Trans Alkene
26
Ni2B w H2 (P2 Catalyst) + Alkyne
Cis Alkene
27
Alkene + HX
Markonikov Alkyl halide, rearrangement of C cation possible.
28
Alkene + HBr + Peroxide
Karaash effect Anti Markonikov alkyl Haldie.
29
Alkene + H+ in H2O
markonikov Alcohol(poor yield and reversible) c cation rearrangement possible
30
Alkene + Ch3COOH
Markonikov addition of OAc C cation rearrangement possible
31
Alkene + H2SO4 boil
Markonikov Alcohol, not reversible rearrangement possible
32
Alkene + [Hg(OAc)/THF/H2O/NaBH4/OH-]
Mkov addn of OH and anti addition of H and OH ## Footnote NaBH4 is source of H and H2O of OH-
32
X2 in CCL4 in Alkene
Different C different side Br ( no C+)
32
Alkene +[Hg(OAc)/THF/R(OH)/NaBH4/OH-]
Mkov Ether | Because of ROH
32
Alkene + [BH3/THF/H2O2/OH]
syn and anti-Mkov Alcohol
33
Alkene+[OsO4/Pyridine/NaHSO4/H2O]
syn Addn of OH OH
34
1 degree Alkyl halide + 1/2 degree R-O-
Ether major
35
2/3 degree Alkyl halide + any degree R-O-
Alkene Major
36
1 degree Alkyl halide + 3 degree R-O-
Alkene Major
37
Alkyne+ H2/Ni/Pd
Alkene
38
Alkyne+H2Pd+BaSO4
Cis Alkene
39
Alkyne+ Liq NH3+Na
Trans Alkene
40
Kolbe's Electrolysis of viccinal di Carboxalic Acid
Alkene
41
Alcohol+H+/H2SO4/Heat
Alkene
42
Alkyl Halide+ Base
Alkene(stable C+ and Stable Alkene)
43
Viccinal Di Halide+Zn Dust
Alkene
44
Akane+HNO3+heat
R-NO2
45
alkane+/Cr/V oxide ## Footnote Pyrolysis
Alkene
46
Methane+CuTube Heat
Methanol
47
Methane+Mo2O3
Methanal
48
R-CH3+Ag2O
R-C(OH)==O
49
Hexane+Cr2O3+Al2O3
Benzene
50
Alkane+X2+H(nyu)
AlkylHalide(most suitable)
51
Al4C3+H2O
Methane+Al(OH)3
52
Be2C3+4H2O
Methane+Be(OH)2
53
R-COO-+Q
R-R + CO2+H2
54
R-COO-+NaOH+CaO
RH
55
R(OH)+HI
RCH3
56
Ketone +HI
RCH2R'
57
Aldehyde
RCH3
58
Acid+HI redP
RCH3
59
Ketone+N2H4(wolf Kishner)
R-CH2-R'
60
Aldehyde+N2H4(wolf Kishner)
RCH3
61
Ketone+ Zn+Hg(Clemensons Reduction)
R-CH2-R'
62
Aldehyde+ Zn+Hg(Clemensons Reduction)
RCH3
63
R-X --->Mg+Ether----> HCl(Grignard's Reagent)
RH
64
R-X --->Mg+Ether----> Ch3COOH(Grignard's Reagent)
RH
65
R-X --->Mg+Ether----> H2O(Grignard's Reagent)
RH
66
R-X --->Mg+Ether---->ROH(Grignard's Reagent)
RH
67
R-X --->Mg+Ether----> NH3(Grignard's Reagent)
RH
68
R-X --->Mg+Ether----> RNH2(Grignard's Reagent)
RH
69
R-X[CuLi CuX]+R'X (Corey House Synthesis)
R-R'
70
Frankland Reaction) R-X+Zn Ether
R-R
71
(Wurtz Reacn) R-X---> Na Ether--->
R-R
72
R-X+Zn[H+]{OH-}
RH
73
R-X+HI Red P
RH
74
ALkene+H2 Pd+C Black
Alkane
75
RX+ Zn Cu Couple
RH
76
Alkyne/Alkene+ H2 Ni
Alkane
77
Hexane+ Cr2O3+V2O5
Benzene
78
Ethyne+Cu/FeTube
Benzene
79
Chloro Benzene + Ni Al NaOh
benzene
80
Halo Benzene Benzene+ Mg+water/acid whtever)
benzene
81
Phenol+ Zn Dust
Benzene
82
Benzene sulphonic Acid +Steam
Benzene
83
Benzene Diazonium Chloride+ H2PO2
Benzene+ N2
84
Benzene Diazonium Chloride + Ethanol
Benzene+ Ethanal+ N2+HCl
85
Benzene Phenol+ HI Red P
Toulene
86
Benzene Aldekhyde+ HI Red P
Toulene
87
Benzene Carboxalic Acid
Toulene
88
Benzene Carboxalic Acid+ NaOH + CaO
Benzene
89
Benzene Carboxalic Acid+ Q
di benzene
90
Benzene + Cl2+ FeCL3
Chloro Benzene
91
Benzene + Conc HNO3
NitroBenzene
92
Benzene+ H2SO4/SO3
Benzene Sulphonic acid
93
Benzene+RCl==O+AlCl3
Benzene Aldehyde
94
Benzene+Rcl+Alcl3
R-Benzene
95
Benzene+HCl+CO+AlCl3
Benzene-C==o
96
Benzene Ozonolysis
done
97
Toulouene+KMnO4
Benzene Carboxalic Acid
98
Toulouene(Etard Rxn) + CrO2+Cl2 in CS2
BenzeneAldehyde
99
Toulouene+ Cl2
CH2Cl--Ph
100
Bnezene+ H2 Ni
CycloHexane
101
Cl-C-C-C-Cl+ Na Ether
Cyclo propane+Cyclo Hexane
102
COO--C-C-C-C-C-C-COO+Q
Cyclo Hexane
103
Di Carboxalic salt of Ba/Ca-->A---->wolf kishner/clemmensons-->B
A:cyclo ketone B: Cyclo Alkane
104
c==c--c===c+ c==c
Cyclo Hexane + double bond(1)
105
c===c + C2H2N2
c--c---c(arranged in a triangle)
106
c===c + C2H2I2+ Zn Cu Couple / Simon Rxn
c--c---c(arranged in a triangle)
107
Isolated di halide+ NH2-
Cunjugated DIene
108
Benzene+Na NH3
cyclo hexane + 2 opp double bond
109
Alkadiene+ Na NH3/H2 Li
Beech mei double bond
110
C====c---c====C+ HBr
C==c---c(Br)---C+ c----c===c---c(Br)
111
C====c---c====C+ Br2 CCl4
BrC----C====c----c(Br)+ c====c-----c(Br)-----C(Br)
112
c---c===c---c + O3+Zn/Pd
2(C---C===O)
113
c---c===c---c + O3
C----C(OH)===O
114
c---c===c---c + O
CH3COOH
115
C(triplebond)C+O3+Zn
(C==O)----(C===O) | For O3 or (O) , same as alkenes...complete oxidation

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