IB CHEM: KINETICS VOCAB Flashcards

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1
Q

Collision Theory

A
  • Two particles must collide
  • The collecting particles must have the correct orientations
  • The particles must have sufficient knetic energy to initiate the reaction
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2
Q

Activation Energy

A

The minimum energy that colliding particles need for a reaction to occur

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3
Q

Factors affecting collision Rate

A
  • Concentration/pressure
  • Surface area
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4
Q

Factors affecting the required activation energy

A
  • Temperature
  • Catalysts
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5
Q

Pressure increases

A
  • Volume decreases
  • Then look for side with less mols
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6
Q

Volume increases

A
  • Pressure decreases
  • Then look for side with less mols

NO AATT

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7
Q

Concentration/ Pressure

A
  • Increasing the concentration increases the amount of particles, therefore increasing reaction rate
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8
Q

Surface Area

A
  • Increasing the surface area, increases the area for particles to make contact. Therefore increasing the reaction rate
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9
Q

Temperature

A
  • Increasing temp. increases the speed at whoch the particles move, therefore increasing the frquency of effective collisions
  • Increases the # of particles with sufficient activation energy
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10
Q

Method for Pressure

A

Increasing: Shift to side with less mols
Decreasing: Shift to side with More

(Inverse of volume) As P+, V- and vice verse

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11
Q

Method for Volume

A

Increasing: Shift to side with more mols
Decreasing: Shift to side with less mols

(Inverse of Pressure) As V+, P- and vice verse

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12
Q

Endothermic

A
  • Low to High graph
  • Positive temp
  • Goes on Left
  • Then AATT
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13
Q

Exothermic

A
  • High to low graph
  • Negative temp
  • Goes on Right
  • Then AATT
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14
Q

If Q=Kc

A

Reaction is at equilibrium

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15
Q

If Q<Kc

A
  • Q -> K is increase
  • Reaction will proceed to the right
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16
Q

If Q> Kc

A
  • Q -> K is decrease
  • Reaction will proceed to the left
17
Q

Equation for Kc

A

Products/Reactants

18
Q

If Reaction is flipped

A

1/Kc (Inversed) or Kc^-1

19
Q

If reaction is multiplied by 2 or 3

A

Kc^2 or Kc^3

20
Q

If reaction is halved

A

Kc^1/2 or sq. rt. ofKc

21
Q

On Kinetic graph…

A

Higher temp: lower # of particles. farther right
Lower temp: Higher # of particles. farther Left

22
Q

Catalysts

A
  • Decreases Activaton Energy required
  • Provides an alternate pathway
  • Increases the frequency of collisions
  • ## Increases the rate of the forward and rev. rxn equally
23
Q

When asked to sketch a curve of reaction

A
  • If rxn speeds up, slope shuld be steeper and level off quicker
24
Q

To calculate slope of tangent to the curve

A

Y-Axis/X-axis at selected time