IMF of Liquids (chapter 2) Flashcards

(74 cards)

1
Q

gas/ liquid; a substance that can flow

A

Fluid

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2
Q

The measure of the elastic force in the surface of a liquid.

A

Surface tension

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3
Q

The amount of energy required to stretch or increase in the surface of liquid by a unit area.

A

Surface tension

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4
Q

Tendency of a liquid to rise in narrow tubes or to be drawn to small openings.

A

Capillary action

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5
Q

The measure of a fluid’s resistance to flow.

A

Viscosity

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6
Q

A gaseous substance that exist naturally as a liquid/ solid at normal temperature.

A

Vapor

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7
Q

Change of phase from liquid to vapor (gaseous phase).

A

Vaporization

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8
Q

The equilibrium pressure of a vapor above its liquid; that is, the pressure exerted by the vapor above the surface of the liquid in a closed container.

A

Vapor pressure

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9
Q

The temperature at which a liquid boils

A

Boiling point

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10
Q

Normal boiling point in atm?

A

1 atm

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11
Q

The energy (kilojoules) required to vaporize 1 mole of a liquid at a given temperature.

A

Molar heat of vaporization (Hvap)

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12
Q

It is manifested as some sort of skin on the surface of a liquid or in a drop of liquid.

A

Surface tension

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13
Q

Molecules in liquid are pulled in?

A

All directions; downwards or sideways

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14
Q

IMF causes liquid surface to

A

tighten like an elastic film/ skin

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15
Q

in ST liquid; high IMF equals?

A

high surface tension

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16
Q

Capillary action is also known as?

A

“Capillarity”

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17
Q

Result of IM attraction between solid and liquid materials.

A

Capillary action

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18
Q

Capillary action is shown in?

A

Water rising in capillary tubes

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19
Q

CA 2 Types of Forces

A

Cohesion and Adhesion

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20
Q

IM attraction between like molecules

A

Cohesion

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21
Q

IM attraction between unlike molecules

A

Adhesion

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22
Q

Cohesive forces > Adhesive forces

A

Surface is convex; ex. mercury

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23
Q

Cohesive forces < Adhesive fores

A

Surface is concave; ex. water in glass

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24
Q

Cohesive forces = Adhesive forces

A

Surface is horizontal; ex. distilled water

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25
High viscosity equals?
High time of liquid to flow
26
Viscosity unit
Units of centipose
27
Water's viscosity
1 centipose/ 0.001 Pa/s at 20°C
28
Examples of lower viscosity
Carbon tetrachloride and benzene
29
Resistance to flow is 1000x stronger than water
Glycerol
30
is a metric system unit
Poise/ stoke
31
SI unit of Viscosity
Pascal-second (Pa/s) or Newton-second/meter
32
What makes glycerol's IMF stronger than water?
its larger number of -OH groups allows it to form more H bonds w/ other glycerol
33
V in liquids; high IMF
high viscosity
34
V in liquids; high temperature
low viscosity
35
closed container
Vapor pressure
36
greater # of gaseous particles equals
greater pressure
37
equilibrium; closed container
Vapor pressure
38
Pressure of gas is ___ proportional to # of gas present.
directly
39
High temperature = ___ molecules escaping
high
40
High VP = ___ temperature
high
41
Examples (of lower vapor pressure)
ethyl alcohol and water
42
Why does ethyl alcohol and water have lower VP?
bc both is in hydrogen bonding
43
Polar but doesn't have H bonding
Acetone
44
Nonpolar and has higher VP compared to ethyl alcohol and water
Pentane
45
VP in liquids; high IMF
low vapor pressure
46
move in random directions
gas molecules
47
collide with other molecules
gas molecules
48
rate of condensation is equal to?
rate of evaporation
49
when condensation is equal to evaporation
equilibrium with liquid
50
Relationship of vapor pressure and boiling point is ___ with other
consistent
51
2 Properties of Liquids
1. Enthalpy/ molar heat of vaporization | 2. Boiling point of the liquid
52
energy required to vaporize 1 mole of a liquid at a given temperature
enthalpy/ molar hear of vaporizarization
53
symbol for enthalpy
"H"
54
heat content at a given standard condition
enthalpy
55
may be considered as a measure of the strength of IMF in a liquid
heat of vaporization
56
easier to vaporize than H2O
acetone
57
Why is acetone easier to vaporize than H2O?
bc acetone has no H bonding and heat in KE is enough to vaporize then
58
Temperature at which the liquid converts into gas
boiling point
59
liquid boils when
VP = pressure acting on the surface of the liquid.
60
VP is equal to
external pressure
61
normal boiling point
1 atm/ 100°C
62
High enthalpy/ molar heat of vaporization
high boiling point
63
good solvent (1)
water
64
Has the ability to dissolve a large amount of chemical substance.
water
65
Water is also known as?
"universal solvent"
66
bc of water, H2O plans absorb?
nutrient ions
67
water issues? (2)
farming and industrial plants
68
Water has high?
Specific heat
69
Amount of heat/ energy needed to raise the temperature of 1g of a substance by 10°C
Specific heat
70
Specific heat of water?
1 calorie/g-°C (4.18J/g-°C)
71
has one of the highest specific heat
water
72
to raise the temperature of water...
IM hydrogen bonds should break
73
Water's boilng point is? (3)
Unusually high
74
Solid water is? (4)
less dense causing it to float.