IMPORTANT Flashcards

(29 cards)

1
Q

zero order reaction equation

A

at - a0 = -kt

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2
Q

zero order reaction graph

A

decreasing linear(concentration only)

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3
Q

first order reaction(equation)

A

lnat - lna0 = -kt

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4
Q

first order reaction(graph)

A

decreasing linear

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5
Q

second order reaction(equation)

A

1/at - 1/a0 = kt

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6
Q

second order reaction graph

A

if concentration: increasing exponential
if 1/concentration: positive linear

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7
Q

half life order equation

A

t 1/2 = 0.693/k

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8
Q

MUST KNOW STRON ACIDS

A

HCLO4(perchloric acid)
HCL03(choric acid)
HCL(hydrochloric acid)
HBr(hydrobromic acid)
HI(hydroiodic acid)
HNO3(nitric acid)
H2SO4(sulfuric acid)`

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9
Q

COMMON WEAK ACIDS

A

HSO4- (HYDROGEN SULFATE ION)
H3PO4(phosphoric acid)
HF(hydrogen fluoride)
HNO2(nitrous acid)
CH3CO2H(acetic acid)

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10
Q

for acid base reactions, if ka is less than 1.0*10^-3

A

you can ignore the x in [ha]0 - x

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11
Q

a strong acid DOES NOT

A

make a buffer

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12
Q

optimal buffering occurs when

A

[ha] = [a-]

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13
Q

[ha] = [a-]

A

ph=pka

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14
Q

[ha] > [h]

A

ph < pka

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15
Q

the solubility is affected by common ion effects

A
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16
Q

as temperature increase..

A

positional randomness is FAVORED. (energy randomness is ignored)

17
Q

as temp decreases..

A

energy randomness is FAVORED

18
Q

decide whether this process is spon or nonspon

exothermic and becomes more positionaly random

19
Q

decide whether this process is spon or nonspon

exothermic and becomes less positionaly random

A

depends on temp

20
Q

decide whether this process is spon or nonspon

endothermic and becomes more positionaly random

A

depends on temp

21
Q

decide whether this process is spon or nonspon

endothermic and becomes less positionaly random

A

nonspontaneous

22
Q

at the boilin point, delta g is 0

23
Q

delta s +, delta h -

A

spontaneous at all temp

24
Q

delta s +, delta h +

A

spon at hih temp

25
delta s -, delta h -
spon at low temp
26
delta s - delta h +
not spon at ANY TEMP
27
N2 + 3h2 -----> 2Nh3 is called
the haber process
28
acid rain is caused by
SULFIRIC ACID
29