IMPORTANT Flashcards
(29 cards)
zero order reaction equation
at - a0 = -kt
zero order reaction graph
decreasing linear(concentration only)
first order reaction(equation)
lnat - lna0 = -kt
first order reaction(graph)
decreasing linear
second order reaction(equation)
1/at - 1/a0 = kt
second order reaction graph
if concentration: increasing exponential
if 1/concentration: positive linear
half life order equation
t 1/2 = 0.693/k
MUST KNOW STRON ACIDS
HCLO4(perchloric acid)
HCL03(choric acid)
HCL(hydrochloric acid)
HBr(hydrobromic acid)
HI(hydroiodic acid)
HNO3(nitric acid)
H2SO4(sulfuric acid)`
COMMON WEAK ACIDS
HSO4- (HYDROGEN SULFATE ION)
H3PO4(phosphoric acid)
HF(hydrogen fluoride)
HNO2(nitrous acid)
CH3CO2H(acetic acid)
for acid base reactions, if ka is less than 1.0*10^-3
you can ignore the x in [ha]0 - x
a strong acid DOES NOT
make a buffer
optimal buffering occurs when
[ha] = [a-]
[ha] = [a-]
ph=pka
[ha] > [h]
ph < pka
the solubility is affected by common ion effects
as temperature increase..
positional randomness is FAVORED. (energy randomness is ignored)
as temp decreases..
energy randomness is FAVORED
decide whether this process is spon or nonspon
exothermic and becomes more positionaly random
spontaneous
decide whether this process is spon or nonspon
exothermic and becomes less positionaly random
depends on temp
decide whether this process is spon or nonspon
endothermic and becomes more positionaly random
depends on temp
decide whether this process is spon or nonspon
endothermic and becomes less positionaly random
nonspontaneous
at the boilin point, delta g is 0
idk y
delta s +, delta h -
spontaneous at all temp
delta s +, delta h +
spon at hih temp