Injection Moulding Flashcards

(79 cards)

1
Q

What are some advantages of injection moulding?

A

 Complete design freedom; ability to mould complex shapes with ribs, bosses etc. in a single process.
 High levels of versatility, in terms of size / shape of products and the types of materials that can be moulded successfully.
 Close tolerances can be achieved, with high levels of repetitive accuracy across relatively short machine cycle times.
 Suitable for high levels of process automation in a mass production, high volume manufacturing sector.
 Large-area, thin-section parts can be shaped easily and quickly, but often require high pressure to fill the mould cavity.
 Multi-impression and family moulds can be utilised to optimise the number of units produced per cycle. PET preforms for stretch blow moulding are made in large, multi-impression moulding tools.
 Computer-aided design (CAD) and process simulation is well advanced and well-used in the injection moulding sector. Examples include Moldflow ® MPA software

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2
Q

What are some disadvantages of injection moulding?

A

 Injection moulding is a capital-intensive process, with large financial outlay required for machines, moulding tools and ancillary equipment.
 Long production runs are usually required to ensure financial viability.
 Changes in process conditions can have a profound influence on
microstructural features (crystallinity, orientation, fibre alignment in composites) and formation of defects (weld lines, air traps). These will then compromise the quality of the finished parts**.  Injection moulding grades of polymers are often limited to relatively low molecular weight grades.
 Waste material is produced unless hot runner feed systems are used

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3
Q

KEy way to answer questions

A

structure (microstructure)
processing
properties

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4
Q

Give a light processing overview of injection moulding

A

PROCESS DESCRIPTION
 Machine & Process Sequence
 Machine Size & Specification
MANUFACTURING CYCLE
 Time & pressure cycles
 Process variables and machine control
MOULD CLAMP FORCE
 Mould filling
 Mould packing/dwelling/holding

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5
Q

What are the 3 units of an injection moulding machine?

A

 a clamping unit
 a mould (unit) and
 an injection unit.

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6
Q

What is the function of the clamping unit? and what are the 2 types of clamping methods?

A

 The functions of the clamping unit are opening and closing a die (mould),and the ejection of products.
 There are 2 types of clamping
methods, namely:
 the toggle type and
 the straight-hydraulic type in
which a mould is directly opened
and closed with a hydraulic
cylinder.

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7
Q

What is the mould ?

A

 A mould is a hollow metal block into which molten plastic is
injected to from a certain fixed shape.  There are many holes drilled in the block for temperature control by means of hot water, oil or heaters.
 Molten plastic flows into a mould through a sprue and fills cavities
by way of runners and gates.
 Then, the mould is opened after cooling process and the ejector
rod of the injection moulding machine pushes the ejector plate of
the mould to further eject mouldings.

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8
Q

How is the moulding area of an injection moulder be designed for efficiency?

A

ref diagram pg 13
 Since obtaining only one product by one shot is very inefficient, a
mould is usually designed to have multiple cavities connected with a runner so that many products can be made by one shot.  If the length of the runner to each cavity is different in this case, the
cavities may not be filled simultaneously, so that dimensions,
appearances or properties of the mouldings are often different cavity by cavity.
 Therefore the runner is usually designed so as to have the same
length from the sprue to each cavity.

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9
Q

What is the mould function?

A

 Shaping by injection; shear flow at high pressure.
 Displacement of air from the closed cavity.
 Heating/cooling environment.
 Ejection mechanism
 minimise cycle time

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10
Q

What is the function of the injection moulding machine?

A

The functions of the injection unit
are to melt plastic by heat and then
to inject molten plastic into a mould.

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11
Q

What are the 3 main components of the injection unit?

A

 Screw / barrel assembly - rotation and axial, backwards motion - similar to extrusion, injection/screw forward - screw acts as a piston assembly to inject into the mould no rotation.
 Nozzle (to feed the mould)
 Hydraulic motor & cylinder

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12
Q

What should the injection unit do?

A

 The screw is rotated to melt plastic introduced from the hopper and to accumulate molten plastic in front of the screw (metering zone) . After the required amount of molten plastic is accumulated, injection process is started.
 While molten plastic is flowing in a mould, the machine controls the
moving speed of the screw, or injection speed. On the other hand, it controls dwell (holding) pressure after molten plastic fills out cavities. The position of change from speed control to pressure control (The ‘V-P Switchover’) is set at the point where either screw position or injection pressure reaches a certain fixed value.

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13
Q

What are the sizes and specifications of the injection unit?

A
  1. Injection capacity (max. shot weight or volume) (g or cm3)
  2. Screw details (diameter, L / D, stroke, max. speed or drive power)
  3. Hopper capacity (filling mechanism and drying power / temperature)
  4. Heating capacity (kg / hr)
  5. Pressures: maximum injection pressure capability
  6. Injection phase: screw forward speed, injection time
  7. Additional: Special alloy steels?
    Special features (e.g. swivel carriage, machine control etc.)
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14
Q

What are the machine size and specifications of the clamp unit?

A
  1. Clamp type, maximum clamp force (next session)
  2. Mould opening stroke, speeds, maximum ‘daylight’ between platens3. Platen size (area, m2)
  3. Tie-bar (clearance, diameter, constructional features)
  4. Mould (thickness range, opening force, height adjustment)
  5. Ejection system
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15
Q

What is the machine size and specification for the injection unit/clamping frame ?

A

1 Maximum Shot Weight / Volume
 Maximum volume (weight of PS)
 Range: ‘grams’ – x 10 (kg’s)
2 Maximum Clamp Force
 Oppose melt pressure in the mould cavity – prevents the mould from opening Range few tonnes – (several x 1000) tonnes

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16
Q

What is the clamp force required for the moulding machine specification?

A

ref pg 21
F = ΔP x A (projected area of parts)
ΔP = pressure developed during mould filling /packing
Machine size / specification:
 Injection capacity - maximum shot-weight (g) or shot volume (cm3).
 Clamp force (in kN, or tonnes-force).
 Screw / barrel diameter (mm) – determines output.

 Power – motor main drive, total power requirements
 Overall dimensions and weight
 Hydraulics – oil tank capacity, pressure capabilities
 Machine control system / data storage and processing facilities
 Interface with mainframe computer system, production planning
Additional features:
I. Mould temperature / pressure monitoring
II. Hours and / or cycle counter
III. Core-pulling systems
IV. Product withdrawal, robotics, material conveying systemsV. Software capability; statistical process control (SPC) and data
processing facilities.

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17
Q

What is the main 5 steps of the injection moulding process?

A

Injection Moulding is the process of pushing or injecting molten plastic into a mould cavity.
 Clamping
 Injection
 Dwelling / Packing / Holding
 Cooling Mould
 Opening / Ejection

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18
Q

What is melting in injection moulding?

A

Material granules from the hopper feed into the heated barrel
& rotating screw.
 Material melted by heat, friction & shear force is forced
through a check valve to the front by the rotating screw

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19
Q

What is step 1 - clamping for injection moulding?

A

 The high strength clamp operates by holding the two halves of
the injection mould together during the injection and cooling.
 The clamping is accomplished through hydraulic or electric
pressure

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20
Q

What is step 2 - injection for injection moulding?

A

 During the injection phase plastic pellet material flows into a
hopper on top of the injection unit.
 The pellets feed into a cylinder where they are heated until they
turn molten.
 A motorised screw, or ram, within the heating cylinder then mixes the molten resin and force the polymer to the end of the cylinder.
 Once enough material has accumulated in front of the screw, the injection process begins.
 The molten plastic is inserted into the mould through a sprue, while the pressure and speed are controlled by the screw.

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21
Q

What is step 3 - dwelling/packing/holding for injection moulding?

A

 The dwelling phase provides increased pressure building within the injection process.
 Once the molten plastic has been injected into the mould, pressure is applied to make sure all the mould cavities are filled.
 This portion of the injection moulding process helps to build the
moulded parts overall wall thickness.

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22
Q

What is Stage 4 - Cooling for injection moulding?

A

 The cooling stage of the injection moulding process allows the
moulded part to properly cool.
 Cooling times vary depending on thickness of the part wall. This
is often the longest part of the injection moulding process.

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23
Q

What is Stage 5 – Opening / Ejection for injection moulding?

A

 The mould separates as the clamping pressure releases. Once this occurs the mould is separated into two halves.
 The ejection of the mould is accomplished by using an ejection rod and plate to eject the newly generated finished part.
 The tool is closed and the injection moulding process starts again at stage 1.
 The unused sprues and runners can be recycled for use again in
future production runs.
ref equations for shot volume and clamp force..

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24
Q

What is the difference between extrusions and injection moulding?

A

 EXTRUSION – continuous rotation / steady state
 INJECTION MOULDING – intermittent rotation / cyclic process

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25
What is the cycle time in injection moulding?
 The cycle time in injection moulding refers to the total time required to complete one full cycle of the injection moulding process.  It encompasses various stages, including  injection time,  cooling time,  dwelling (packing/holding) time,  ejection time, and  mould opening/closing time.  Each stage plays a crucial role in determining the overall cycle time and the efficiency of the production process.
26
How does the cycle time vary for each of the 5 stages of injection moulding?
 Injection Time  The injection time is the duration required to fill the mould cavity with molten plastic.  It depends on factors such as the material’s flow characteristics, injection speed, and part geometry.  Optimising the injection time can significantly contribute to reducing the overall cycle time.  Dwelling (Packing/Holding) Time  This is the phase after the Injection time during which the material remains in the mould but is held under pressure to finally fill the cavity and prevent sink and distortion while it solidifies fully.  Reducing the Holding time without compromising the quality of the part can help optimise the cycle time.  Cooling Time  Once the mould cavity is filled with molten plastic, the material needs time to cool and solidify.  The cooling time is a critical part of the cycle as it affects the part’s dimensional stability and quality.  Factors such as the type of material used, the thickness of the part, and the efficiency of the mould cooling system influence the cooling time.  Ejection Time  Once the cooling and dwelling stages are complete, the finished part is ejected from the mould using ejector pins or other mechanisms.  The ejection time is the duration required to remove the part from the mould.  Efficient ejection mechanisms and proper ejection force can minimise the ejection time.  Mould Opening/Closing Time  The time taken to open and close the mould between cycles is also part of the overall cycle time.  The complexity and size of the mould, as well as the capabilities of the moulding machine, influence the mould opening/closing time.  Streamlining this stage can contribute to reducing the cycle time.  Calculating Cycle Time  Calculating the cycle time in injection moulding involves considering the duration of each stage in the moulding process.  By summing up the time spent in each stage, manufacturers can optimise the cycle time and improve production efficiency. REF eq pg 42/43
27
what is the 1st and 2nd stage of mould filling in injection moulding?
 The first stage - Injection for getting most of the plastic into the part, normally 90% to 99.9% full by volume;  The second stage –packing/holding, to pack the part to replicate the steel cavity texture and shape;  The second stage normally moves relatively little plastics in the cavities, but critically important for the finishes, cosmetics and part dimensions.
28
How is packing pressure created and why?
 Packing pressure is created by the compressibility of the melt and the continued forward motion of the screw after all the cavities are completely filled.  This could be considered as overfilling in which a certain % of cavity volume is overfilled with melt, creating a rapid rise in pressure.  Packing is the last stage during injection, which is the only pressure controlled stage so its pressure has to be set carefully to avoid flashing.  After the packing stage, the process switches to holding pressure. The position of the screw at the transition is called the transition point.
29
What is the purpose of holding pressure?
to maintain a pressure at the screw tip to continue filling material into the cavities as the melt in the mould cools and contracts.  The space created by the contraction is taken up by more melt to reduce or avoid sink marks in the solidified parts.  The holding pressure setting should not exceed the packing stage pressure setting, otherwise, flashing could be created at the holding pressure stage. The purpose of holding pressure is to compensate for the defects caused by the cooling mould shrinkage rate of the melt and the drop in melt temperature, while also ensuring the longitudinal and transverse consistency of the product.  The process of holding pressure is to maintain the pressure of the injection moulding machine for a period of time immediately after injection moulding.  This allows the plastic material to be partially melted through the interaction of pressure and temperature to ensure the quality and performance of injection moulding.
30
What are the main roles of pressure holding?
1.Solve the problem of shrinkage holes and burrs - when the pressure is released after injection moulding, the melt will shrink leaving shrinkage holes/burrs at the corners so by maintaining pressure the machine can be maintained in a good pressure state and prevent product defects. 2.Improve the firmness of the product - pressure holding ensures that the plastic material is well filled into every corner and blind hole of the injection mould. When the melt is compacted the molecules of the plastic are arranged more closely which makes the product stronger and more durable and increases the density of the product. 3.Improve the moulding accuracy of the product - During the pressure maintaining process of the injection moulding machine, the plasticity of the melt is increased. This allows the plastic material to fill the injection mould more completely, thus effectively improving the moulding accuracy of the product.
31
What is the screwback and why do it come about in injection moulding?
 Since the sprue (the entry channel for melt flow into the mould) is already occupied by rapidly-cooling melt, the material being pumped forward by rotary shear action of the screw generates a positive pressure (back pressure) in front of the screw tip.  Once it exceeds the back pressure pre-set, the pressure forces the screw back down to the barrel (whilst still rotating) to the desired set-point (pre-set limit) which determines the swept-volume available for the next shot, the stroke.  The screw rotation phase is usually termed screwback.  When this position is reached, the screw will stop rotating.
32
What are the several factors that create back pressure?
 Viscosity of the Material: Thicker or more viscous materials require higher pressure to flow through the injection system.  Mould Design: Complex geometries, narrow gates, or long flow paths can increase resistance and thus back pressure.  Injection Speed: Rapid injection can lead to increased back pressure if the material cannot flow quickly enough.  Temperature: Higher temperatures generally reduce viscosity, which can lower back pressure, while lower temperatures can increase it.
33
What is the importance of backpressure?
 Material Homogeneity: Proper back pressure helps ensure that the material is well-mixed, which is crucial for achieving consistent properties in the final product.  Control of Injection: Managing back pressure allows for better control over the injection process, leading to improved part quality and reduced defects.  Cycle Time Optimisation: Balancing back pressure can help optimise cycle times by ensuring that the material fills the mould efficiently without causing defects.
34
How can backpressure be managed and adjusted in injection moulding?
 Managing Back Pressure, Back pressure can be adjusted by:  Modifying the injection speed.  Adjusting the temperature of the barrel and nozzle.  Changing the design of the injection system or mould.  Understanding and controlling back pressure is essential for achieving high-quality injection-moulded parts and efficient manufacturing processes.  As backpressure is increased, the time for the screw to recover to set-point is increased. Screw recovery speeds should be increased as well to maintain cycle time.
35
What is decompression in injection moulding?
Decompression in injection moulding refers to the process of reducing pressure within the injection unit or mould after the injection of molten plastic into the mould cavity.
36
Why is decompression important?
1. Preventing Flash: Decompression helps to relieve pressure that could cause excess material to escape from the mould cavity, which is known as flash. 2. Improving Surface Finish: By reducing pressure, decompression can help improve the surface finish of the moulded part, as it minimizes the risk of surface defects caused by excess material flow. 3. Enhancing Material Flow: It allows the molten material to flow more easily, ensuring that it fills the mould completely and uniformly lower the pressure 4. Controlling Shrinkage: Decompression can help manage the cooling and solidification process, reducing the likelihood of warping or uneven shrinkage in the final product. 5. Preventing Sticking: It reduces the adhesion of the moulded part to the mould, making it easier to eject the part without damage.
37
How is the decompression process typically achieved?
 This is often achieved by retracting the screw slightly or using a vacuum system to lower the pressure in the cavity.  Properly managing decompression is essential for producing high-quality moulded parts with consistent characteristics.  Too much decompression can result in excessive air being pulled into the melt stream, resulting in bubbles or splay in the moulded part.
38
IF the moulded part did not have the desired output, what machine variables in the process would you change to fix this? and what can you not control?
Primary Settings: Temperature – melt Temperature – mould tool Injection speed (cm/s) Packing pressure Packing time  Secondary Variables : Stroke, Speed, Time  Response Variables: ΔP (injection pressure) ie machine parameters (pressure, temp, speed, stroke, time) Mould design (feed system layout and size, gate number and position) CAN'T CONTROL:  Controllable / off-line: mould tool / mould system design  Uncontrollable: variability in material quality (MFR), additives, humidity, water temperature, hydraulic oil …….
39
Why have heat moulding for thermoplastics?
- Mould filling (reduce ΔP) - Effect on properties (nucleation etc)- Surface finish / tool replication oil/water would be circulated through internal channels
40
How does mould temperature affect the plastic in injection moulding?
 Orientation  Residual Stress  Shrinkage & Distortion  Microstructure  Weld-line Formation Large interaction between processing and properties for injection moulding: Flow and cooling  Predictions using theory and simulation
41
What are the 4 main factors affecting injection moulding cycle time?
1.Mould Design Parameters:  Factors such as cooling system design, runner and gate design, and the number of cavities in the mould can impact the cycle time.  Efficient cooling channels, well-designed runners and gates, and optimal cavity arrangements can contribute to reducing the overall cycle time. 2. Product Design Parameters:  Factors such as wall thickness and part geometry influence the cooling time and overall cycle time.  Designing parts with uniform wall thickness and minimising complex geometries can help optimise the cycle time. 3.Injection Moulding Process Parameters  Injection speed and pressure, melt temperature, mould temperature, and holding time and pressure all play a role in determining the cycle time.  Optimising these parameters can result in shorter cycle times and increased production efficiency 4.Material Selection  Different materials have varying melt temperatures and cooling rates, which affect the overall cycle time.  Selecting materials with optimal flow characteristics and cooling properties can contribute to reducing the cycle time.
42
How can the injection time be optimised?
 Utilise high-speed injection to fill the mould quickly.  Set the injection pressure at the minimum required for proper part filling.  Optimise the gate design to ensure smooth material flow and minimise pressure drop.
43
How can the cooling time be improved?
Affects the quality of the moulded part = reduced cycle times and improved production efficiency.  Design efficient cooling channels in the mould to ensure uniform cooling. Or use metal 3d printed conformal cooling channels to help get the cooled water to the exact areas that the tool requires.  Use advanced cooling systems, such as chilled water, to enhance cooling efficiency.  Optimise the mould temperature control to achieve optimal cooling rates for the specific material.
44
How can the hold time be reduced and why?
hold time allows the material to fully solidify in the mould and reduces the risk of warping or distortion. Reducing hold time without compromising part quality can contribute to cycle time reduction.  Optimise the holding time and pressure to the minimum required for proper part packing.  Utilise advanced process control systems to ensure accurate and efficient packing.  Employ mould flow simulation software to analyse and optimise the hold time.
45
How can streamlining mould opening/closing time help cycle time reduction?
=time taken to open and close the mould between cycles  Invest in injection moulding machines with fast clamping systems.  Optimise the mould design to minimise the complexity and size of the mould.  Regularly inspect and maintain the mould to ensure smooth and efficient mould movement.
46
How does efficient ejection time help minimise ejection time from mould and overall cycle time reduction?
 Use fast ejection systems to reduce the time taken for part ejection.  Ensure sufficient ejection force to avoid part sticking or damage during ejection.  Regularly maintain and lubricate mould components to ensure smooth and efficient mould movement
47
What is the relevance of the mould clamp force?
the force must exceed the pressure(consider filling and packing phases) X projected area(normal to mould face, total area is relevant so mould design is important), but if it is less this causes mould flashing [ref equation pg 75-80]
48
What is the V-P switchover?
(A) Injection phase:  Screw moves forward at a set speed (velocity, v), hence controlled displacement of material  Therefore: this is a ‘velocity-imposed’ flow: “V” Volume flow rate (Q) – is set / fixed; Pressure (ΔP) – is a dependent variable(B) Packing phase:  Screw moves forward according to the set pressure in the hydraulic cylinder  Therefore: this is a ‘pressure-imposed’ flow: “P” V/P switchover: when the injection phase ends, packing phase begins
49
How does packing and cooling allow shrinkage of thermoplastics?
When plotting Pressure (MPa) Specific volume (cm3 g-1) Temperature (oC), it Allows estimation of shrinkage following processing, taking account of both process temperature (T) and pressure (P). Typical pressures for injection moulding can be as high as 100 MPa.
50
How are injection moulds filled?
From the injection unit it heats and therefore softens the viscous fluid into the mould for shape stabilisation. Thermoplastics cool Thermosets and elastomers- cross link/cure in the mould
51
What is the feed system in injection moulding?
The tool is machined with a series of channels (the feed system) through which the polymer flows on injection: from the machine to the ends of the cavities.
52
What are the 4 main feed systems to make up the entire feed system?
Sprue – this is a tapered channel machined through the sprue brush, fed by and in-line with the machine nozzle. Allows easy separation from the mould. Runner – these are the basis of the feed system design that takes the polymer melt to the mould cavities. Runners are positioned on or perpendicular to the parting surface of the mould and are designed to deliver the melt to the cavities with minimal pressure drop. Runners should always be balanced and be symmetrical (wherever possible) for multi cavity tools. Gate(s) – these are the entrances to the mould cavities, fed by runners. Many variations in gate design exist. Once filled, their function is to allow the polymer to freeze rapidly (preventing back flow) and to provide easy de-gating at ejection. Cavities – the cavity (or cavities) are machined to high-precision. Depending on the product complexity, inserts and/or cores may be necessary to simplify mould manufacture.
53
how is flow balancing achieved for multi cavity moulds? What are the main requirements for a balanced feed system?
 Unbalanced Feed Systems (multi-cavity moulds): - cavities which fill first are being ‘packed’ whilst others are still filling- this leads to non-uniform dimensions, weight, quality, part distortion etc. Unbalanced Feed System (complex, single cavity mould): contains a flow obstruction, therefore weld lines form BALANCED FEED SYSTEM:  more complex layout  greater amount of material in the runners weld lines positioned appropriately more uniform filling  Equalising the pressure requirement (ΔP) to fill each cavity;  Attempt to achieve symmetrical flow wherever possible.
54
What are the three modes of a balanced flow?
1) Unbalanced – varying part quality (2) Naturally Balanced – limited applications (3) Artificially Balanced – requires analysis – secondary runners have smaller diameter (middle components) MUST CHOSE WHICH IS BETTER FOR USAGE
55
How does artificial runner balancing differ from naturally balanced and unbalanced feed systems?
Lateral dimensions of the runners (e.g. diameter, for a circular section) are different Objectives:  to deliver plastic melt to all cavities at the same pressure  all the cavities fill at the same time – switch to packing phase
56
How does gate positioning on the feed system effect the mould type to be used?
1. An edge gate at the end of the component would require a very high pressure = more orientation. The gate is in a better position in regard to avoiding mechanical weaknesses in the middle. Better for MULTI CAVITY mould/ SMALL components. 2. A gate at the centre of the panel centre gate gives the possibility of a direct feed from the machine, simplifying the mould tool and reducing the pressure requirement; BETTER FOR a SINGLE, LARGE component.
57
Is fluid flow isothermal?
It is a non -isothermal flow in mould filling (temperature not the same throughout). There is a net heat flow away from the flowing melt (thermoplastics), as the cavity fills.  The opposite is true for rubbers / thermosets: heat flow to the flowing material). As Tmelt >> Tmould theres non-isothermal flow
58
What is the method of mould tool heating and cooling?
1. By circulation of a heat transfer medium through ‘cooling channels’ drilled into the mould plates. Water (chilled, or frozen from a mains supply) is used for sub-ambient temperatures and heated oil is usually used (from a separate, independently controlled mould heater) for temperatures higher than ambient. 2. Electrical resistance ‘cartridge’ heaters are used for heating specific areas of the mould, for example, in heated runner systems.
59
Why would heated mould be required for thermoplastics?
cooling the mould is typically essential when moulding thermoplastics, in order to stabilise the new shape that has been formed in an economically acceptable cooling time. 1. Moulding feasibility – effect on non-isothermal flow and pressure requirement (ΔP) for mould filling. 2. Structure development - mould temperature influences microstructural features such as orientation (flow-induced), residual cooling stress (thermally–induced), shrinkage and distortion, and strength of weld lines. 3. Promotion of crystallisation – thermoplastics crystallise at maximum rate around halfway between Tg and Tm. Elevated mould temperatures will enhance the rate of crystallinity development in specific engineering polymers (nylons, polyesters) for applications where rigidity / high modulus is required. 4. Product quality – other attributes of the product are dependent upon mould temperature, e.g. replication of the mould and surface quality.
60
What are main disadvantages of heated moulds for thermoplastics?
Increased cooling time, therefore: * Increased cycle time, in production
61
What are the 3 main things the mould temperature would affect within the material?
crystallinity, residual stress, microstructure
62
What are the 5 main shear flow assumptions?
1. Isothermal - actually are non-isothermal as Tc
63
What is the pressure profile of shear flow in mould filling a function of? and how is this determined?
The maximum pressure on the machined must be > that the sum of pressures from the sprue, runner, gate and cavity. These pressures are a function of melt temp, mould temperature, injection speed Q and therfore shear rate. ref eqs pg 112-115
64
What are the pressure gradients assumed to be for Newtonian and pseudoplastic fluids?
Newtonian - Linear Pseudoplastic fluids - non-linear
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For non-isothermal effects, what are the main assumptions of a 'frozen layer' approach?
1. The molten plastic is injected down to a relatively cold flow channel: heat transfer from the melt is extremely rapid at the mould wall, such that local temperature drops dramatically and the polymer solidifies; 2. As moving away from the mould surface, the colling rate diminishes, due to the thermal insulating character of the developing solid layer of polymer; 3. More shear heat is being generated as fresh melt flow through the channel, which itself decreases in thickness as the frozen layer grows; 4. Eventually, a pseudo thermal equilibrium is set up in the frozen layer, where the heat losses to the mould are counterbalanced by prolonged contact with the flowing melt; further growth of the frozen layer does not occur; 5. Since these events take place relatively quickly, the thickness of the frozen layer is assumed to be constant as a function of distance along the cavity (thickness H). ref eqs pg 117-124
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How can the cooling time be estimated?
 Of great significance to manufacturing feasibility is the cooling time for a moulded component.  An approach equivalent to frozen-layer development can also be used to estimate cooling time, if the correct demould (ejection) temperature (TEJ ) for the centre-plane of the thickest part-section, can be specified.  These represent the maximum temperatures at which mouldings can be ejected and remain form-stable.  Ejection temperatures are related to the thermal transition temperatures and can be summarised:  Amorphous Tg ± 20ºC  Semi-crystalline Tm – (20 to 40)ºC ref eq pg 126-127
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What are physical changes in process-property interactions?
Melt Transportation; breaking secondary bonds
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What are chemical changes in process-property interactions?
Reactions; breaking primary bonds. This can include degradation or cross linking of primary chains.
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What are the physical changes in the melting and shaping phase?
Melting- Polymer-additive interactions:  MIXING - dispersive - distributive  DEVOLATILISATION - loss of volatiles / gases - venting Shaping Phase (Flow & Cooling)-  MOLECULAR ORIENTATION - induced by stress (during flow) and rapid cooling  RESIDUAL STRESS: - induced by non-uniform cooling and thermal constraint  SHRINKAGE / DISTORTION: - anisotropic effects of orientation  MICROSTRUCTURALDIFFERENCES: - crystallinity - crystalline structure / texture - weld-lines - voids
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What are the chemical changes in the melting and shaping phase?
Melting- A) Decreases in molecular weight - mechanisms of degradation / decomposition:  Thermal  Oxidation (O2)  Hydrolysis (H2O) Accelerated by:  Mechanical stress  High residence time Shaping Phase (Flow and cooling)- B) Increases in molecular weight:  Crosslinking (either deliberate, or a by product of degradation)  Reactive processing(Note that thermosets and rubbers are deliberately crosslinked (‘cured’) in the final stages of processing)
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What is molecular orientation?
Preferred alignment of molecular chains in a fabricated product. It is similar to the concept of molecular relaxation so that in a random coil this is the lowest free energy state. When a HIGH stress is applied to this it can either slow cool(molecular relaxation) or fast cool(orientation).
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How can orientation be characterised?
Either through direction which is uniaxial or biaxial or through the magnitude of orientation - degree of alignment.
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What is the fountain flow model for orientation development in injection moulding?
In through thickness profiles of orientation in thermoplastics: 1. As molten polymer enters the mold, it flows faster in the center of the channel and slower near the cooler mold walls. There is highest shear stress at the walls and lowest at the center. At the flow front, polymer at the center moves outward and toward the mold walls, "fountaining" out, while previously arrived material near the walls gets pushed sideways and backward. Therefore chains in the center are less oriented due to lower shear rates but are highly stretched and oriented near the walls from the high shear. Final levels of orientation depend on cooling rate and shear stress, each altered by other variables.
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What is the effect of flow length on the development of orientation?
(1) Complex pattern close to the gate - due to effects of packing phase (2) Non-linear shear stress / pressure profile, due to: - pseudoplastic melt; - non-isothermal flow. Orientation increases at a smaller flow length. There is maximum shar stress and pressure at the gate but it is a minimum at the end of fill (furthest away). Ref eqs pg 141 for prediction.
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What are the effects of process variables(mould temp, melt temp, cavity thickness, hold on time, hold pressure) on degree of orientation?
Mould temp- increases then the degree of orientation decreases linearly - bc rapid cooling melt temp- increases then the degree of orientation decreases exponentially - bc high viscosity and shear stress Cavity thickness- increases then the degree of orientation decreases linearly - bc high shear stress and cooling rate Hold on time- increases then the degree of orientation increases exponentially - bc hold pressure - effect of packing Hold pressure-increases then the degree of orientation increases linearly
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What makes orientation increase?
If: mould temp is low , melt temp is low , cavity thickness is thin( high shear stress and cooling rate), hold on time is high, hold pressure is high (bc high shear stress)
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What causes double refraction?
the modulus and the refractive index of the material are a function of direction which leads to birefringence. To analyse light wave components must be vibrating in parallel or perpendicular to the orientation direction.
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What causes the development of residual stress?
A state of internal stress in fabricated products, as a result of inhomogeneous (nonuniform) cooling and constrained thermal contraction. AKA thermal, cooling or quenching stress. caused by NON UNIFORM COOLING not flow.
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What are the residual stress profiled as a result of cooling?
Typical residual stress profiles in injection moulded parts show tensile stress in the core of moulded parts, with compressive stress close to the surfaces. Theoretically (plate glass forming) the material cools from compression to being in tension back to compression (bell curve). Tensile stresses develop in the slower-cooling core. Compressive stresses form in the fast-cooling outer layers causing balanced residual stress profile (different in real life). This can cause non-uniform shrinkage as the outer layer solidify and shrink earlier than the inside and a temp gradient is created.