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A LEVEL CHEMISTRY PAPER 1 > Inorganic > Flashcards

Flashcards in Inorganic Deck (39):
1

State how the element sulfur deviates from the general trend in first ionisation energies across Period 3. Explain your answer (3 marks)

-Lower
-Two of the electrons in 3p orbital
-Undergo electron pair repulsion

2

Strongest type of intermolecular force in Hydrogen Sulfide (H2S):

-Dipole-Dipole OR VDW

3

When H+ ions react with H20 molecules, H30+ ions are formed.
Name the type of bond formed and explain how this type of bond is formed (2 marks)

-Dative covalent bonding
-O donates a lone pair of electrons to the H+ ion

4

Give the name of a SOLID pollutant which may form when pentane burns incompletely in air ( 1 mark)

Carbon

5

Suggest a type of compound that can be manufactured from the alkene in this cracking reaction (1 mark)

-Plastics,polymers

6

Explain briefly how the relative abundance of an ion is measured in a mass spectrometer (2 marks)

-Ion hits detector and forms current
-Bigger current = bigger abundance

7

What is the bent bond angle?

104.5

8

This sodium halide is a white solid that reacts with concentrated sulfuric acid to give a brown gas

NaBr

9

When a solution of this sodium halide is mixed with silver nitrate solution no precipitate is formed.

NaF

10

When this solid sodium halide reacts with conc sulfuric acid, the reaction mixture remains white and steamy fumes are given off

NaCl

11

A colourless aqueous solution of this sodium halide reacts with orange bromine water to give a dark brown solution

NaI

12

State a use of magnesium hydroxide in medicine

Antacid

13

Explain why strontium has a higher melting point than barium (2 marks)
(Look at periodic table, anomaly question as strontium is higher up/smaller than barium)

-Valence electrons closer to nucleus in Sr
-Which results in a stronger attraction between the nucleus and outer electrons therefore more energy required to overcome

14

Calcium carbonate is an insoluble solid that can be used in a reaction to lower the acidity of water in a lake.

Explain why the rate of this reaction decreases when the temp of water in the lake FALLS. (3 marks)

-When temperature decreases the energy of the particles (H+) decrease
-Therefore less particles with greater than or equal to the activation energy
-Therefore less successful collisions

15

Hydrogen is used in the chemical industry.
Tungsten is extracted by passing hydrogen over heated tungsten oxide (WO3)
State the role of hydrogen in this reaction (1 mark)

Reducing agent

16

State a risk of using hydrogen gas in metal extractions

-Flammable/explosive

17

Write an equation for the reaction of magnesium with titanium(IV) chloride:

2Mg+TiCl4---->2MgCl2 + Ti

18

Suggest a reason why the catalyst may be hot (1 mark)

-To overcome activation energy

19

Suggest a reason why the catalyst remains hot during the reaction ( 1 mark).

-The reaction is exothermic (releases heat energy)

20

State the characteristic property of transition metals that enables them to act as
catalysts in redox reactions. (1 mark)

Variable oxidation state

21

Contact process:

SO2 + V2O5 → SO3 + V2O4

2V2O4 + O2 ---> 2V205

22

Suggest one reason why poisoning reduces the effectiveness of a heterogeneous
catalyst. (1 mark)

Poison attaches to surface

23

Suggest how poisoning of a catalyst, used in an industrial process, can be
minimised. ( 1 mark)

Purify reactants

24

State a medical use of barium sulfate and state why it is safe. (2 marks)

-Used in a barium meal
-It is insoluble

25

Magnesium burns with a bright white light and is used in flares and fireworks.

Use your knowledge of the reactions of Group 2 metals with water to explain why
water should not be used to put out a fire in which magnesium metal is burning. (2 marks)

-Hydrogen / H2 produced
-Risk of explosion

26

Explain why toxicity of chlorine doesn't stop it being used in water

Used in small amounts / Dilute(Low) concentrations

27

Reaction of chlorine with cold water:

Cl2 + H2O ----> HCl + HClO

28

Sodium bromide reacts with concentrated sulfuric acid in a different way from
sodium chloride.
Write an equation for this reaction of sodium bromide and explain why bromide ions
react differently from chloride ions. (3 marks)

2NaBr + 2H2SO4 -----> Na2SO4 + Br2 + SO2 + 2H2O
Br- ions are bigger than Cl- ions
Therefore Br– ions more easily oxidised (lose an electron more easily)

(NaBr also has the reaction of
NaBr + H2SO4 --> NaHSO4 + HBr) - HBr can go on to react to make reaction above (not including na2so4)

29

K2Cr2O7 reaction with iron half equations:

Fe2+ goes to Fe3+
Chromium in Cr2O72- ----> Cr3+
Cr2O72- +14H+ +6e- ----------> 2Cr3+ +7H2O
6Fe2+ -----> 6Fe3+ +6e-
(1:6 ratio)

30

KMnO4 Reaction half equation:

Manganate goes to Mn2+ in MnO4-
MnO4- +8H+ +5e- ------> Mn2+ +4H2O

31

In a titration question, you are asked to work out the mass of FeSO4.7H2O. When calculating Mr, do you count 7(H2O) (7x18) when calculating overall Mr?

Yes count moles of water so FeSO4.7H2O
55.8+32,1+64+7x(18) = 277.9

32

How many sig figs should you give a calculated titration mass to?

3 sig figs

33

Explain why sodium oxide forms an alkaline solution when it reacts with water.
[2 marks]

-Sodium oxide contains O2- ions
-Which react with water to form OH- ions, making alkaline

34

pH of Ca(OH)2 solution:

14

35

State a reagent used to test for presence of sulfafe ions:
And think of the equation AND ioni c equation:

Barium Chloride

BaCl2 (aq)+ SO42- ——-> BaSO4 (s)+ 2Cl-

IONIC
Ba2+ + SO42- —-> BaSO4

36

Displacement reaction of Cl2 reacting with NaBr

Cl2 + 2NaBr ---> Br2 + 2NaCl

37

Reaction of sodium chloride with concentrated sulfuric acid:

NaCl(s) + H2SO4(l) ---> NaHSO4(s) + HCl(g)
This reaction can be used to prepare hydrogen chloride gas

38

Reaction of sodium fluoride with conc sulfuric acid:

NaF(s) + H2SO4(l) ---> NaHSO4(s) +HF(g)

39

Reaction(s) of sodium iodide with concentrated sulfuric acid:

Hydrogen Iodide
Black Solid- Iodine
H2S- Bad egg smell
Sulfur- yellow solid
SO2- Colourless
NaI + H2SO4 ---> NaHSO4 + HI
REACTION GOES ON TO:
8H+ +8I- + H2SO4(l) ---> H2S(g) + 4H2O(l) + 4I2 (s)