Inorganic tests Flashcards
(17 cards)
Solid halide + concentrated sulfuric acid precautions
- must be carried out on a small scale
- carried out in fume cupboard
solid chloride + conc sulphuric acid
- steamy fumes (white fume)
HCl
solid bromide + conc sulphuric acid
- steamy fumes, brown vapour
HBr, Br2, SO2(colourless)
solid iodide + conc sulphuric acid
- steamy fumes
- purple vapour
- black solid
- yellow solid
HI, I2, S, H2S(colourless)
precautions of silver nitrate test
- anions such as carbonates that would form ppt with silver nitrates are removed by dding dilute nitric acid before silver nitrate
chloride + silver nitrate
white ppt (AgCl)
chloride + silver nitrate + dil ammonia
soluble
bromide + silver nitrate
cream ppt (AgBr)
bromide + silver nitrate + dilute ammonia
insoluble
bromide + silver nitrate + conc ammonia
soluble
iodide + silver nitrate
pale yellow ppt (AgI)
iodide + silver nitrate + dil ammonia
insoluble
iodide + silver nitrate + conc ammonia
insoluble
sulphate (VI) SO42- + barium chloride
white ppt BaSO4
sulphate (IV) SO32- + barium chloride
white ppt BaSO3
carbonate + barium chloride
white ppt (BaCO3)
when dil HCl added to the anion solution before the addition of aq barium chloride
only sulphate (VI) anion will form precipitate
other anions will dissolve