Intra/Intermolecular forces Flashcards

(48 cards)

1
Q

What are the two kinds of forces that operate in a molecule?

A

Intramolecular and intermolecular forces

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2
Q

Define intramolecular forces

A

Forces that hold atoms together within a molecule

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3
Q

Define intermolecular forces

A

Forces that exist between molecules

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4
Q

What is an ionic bond?

A

A bond formed by the complete transfer of valence electron(s) between atoms, generating two oppositely charged ions

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5
Q

What happens to electrons in ionic bonds?

A

The metal loses electrons to become a positively charged cation, while the nonmetal accepts those electrons to become a negatively charged anion

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6
Q

Define electronegativity

A

The affinity or desire for electrons.
OR
capacity of receiving electrons

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7
Q

What is a covalent bond?

A

A bond formed between atoms that have similar electronegativities, sharing electrons to achieve octet configuration

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8
Q

What are the two types of covalent bonds?

A

Polar and nonpolar covalent bonds

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9
Q

Define nonpolar covalent bond

A

A bond formed between same atoms or atoms with very similar electronegativities, with a difference less than 0.5 (they “pull” each other the same)

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10
Q

Define polar covalent bond

A

A bond formed when atoms of slightly different electronegativities (slightly + or -) share electrons, with a difference between 0.5 and 1.9 (one “pulls” the other one more)

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11
Q

What is metallic bonding?

A

A type of covalent bonding occurring between atoms of metals, where valence electrons are free to move through the lattice

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12
Q

What is the ‘sea of electrons’ in metallic bonding?

A

Mobile electrons that move freely and cause the attraction to fixed positively charged metal ions

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13
Q

How do intermolecular forces affect physical properties?

A

They determine boiling point, melting point, density, and enthalpies of fusion and vaporization

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14
Q

What is the relationship between boiling point and intermolecular attractions?

A

Lower boiling point indicates weaker intermolecular attractions, while higher boiling point indicates stronger attractions

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15
Q

What are dipole-dipole interactions?

A

Forces of attraction enabling two polar molecules to attract one another (slightly + with slightly -)

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16
Q

What is hydrogen bonding?

A

A special type of intermolecular attraction between hydrogen in a polar bond and an unshared electron pair on a nearby small electronegative atom (H with F, O or N, and these last three can be with another atom in their partially negative end)
- tronger atraction and needs considerable energy to break it

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17
Q

Is hydrogen bonding a chemical bond?

A

No, it is a stronger form of dipole-dipole attraction

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18
Q

Define London dispersion forces (Van der Waal forces)

A

Attraction between two nonpolar molecules due to temporary dipoles, the weakest of intermolecular forces, existing between all types of molecules

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19
Q

What factors affect the strength of London dispersion forces?

A

The number of electrons in a molecule; more electrons result in stronger forces

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20
Q

What is the effect of molecular size on dispersion forces?

A

As molecular size and molar mass increase, dispersion forces become stronger

21
Q

Fill in the blank: The boiling and melting points of compounds depend on the type and strength of the _______.

A

intermolecular forces present

22
Q

What are the types of intramolecular forces?

A

ionic, covalent and metallic bonds

23
Q

what charge does a cation has?

A

positive, its a metal

24
Q

what charge does a anion has?

A

negative, its a non-metal

25
How to identify a ionic bond?
metal+non-metal, give electrons (this gives charge to the elements)
26
What is the last level of a element called?
valance electrons
27
elements in a table to identify elements:
name, Zymbol, z (atomic #), A (atomic mass), P (Protons), E (electrons) and N (neutrons)
28
what charge does a proton, electron and neutron has?
positive, negative, neutral
29
How to write the formula of a element?
fist metal then nonmetal
30
formula of atomic mass:
P+N
31
porcentages of the atomic mass in a atom:
99% in neucleous and 1% in E
32
How to identify a Covalent bond?
non metal + non metal, share electrons equally
33
steps on how to do a Louis dot driagram
1) sum of family of element x # of atoms of element, of each element (electrons present) 2) (8 x =/ atoms of H) + ( 2 x atoms of H) (electrons needed) 3) step 2 - step 1 (share electron) 4) step 3 divided by 2 (determine the # of bondings x---x) 5) step 3-1 (determine number of loose electrons)
34
What element if present is always at the center of the atom?
C - Carbon
35
whych type of covalent bond disolves? why?
polar covalent bond, because of its slight charge it pulls the slight or complete charge of other atoms e.g: water (polar because slightly + and -) disolves salt (full + and -) because the slightly positive (H) will "grab"/pull the negative of salt and the same with the slightly negative of water (O) will pull the positve of salt.
36
How to identify if its non polar, polar or ionic
non polar: - of elements will give <0.5 polar: - of elements will give 0.5-1.7 ionic: - of elements will give >1.7
37
what type of change does a metallic bond has?
Only physical change, because of this they keep their properties so they dont change names
38
what are alloys?
combination of 2 metals
39
list the intramolecular forces from strongest to weakest:
1) Metallic bonding 2) ionic bond 3)Polar Covalent Bond 4) Non Polar Covalent Bond
40
Intermolecular forces are important because:
 Intermolecular forces of attraction operate over short distances. If not for these forces, the condensed phases (liquids and solids) would not exist; gases would never change to liquids and solids  Properties of liquids, such as boiling point, vapor pressure, viscosity, and heat of vaporization, depend on the strengths of the intermolecular forces of attraction.  Properties of solids, such as melting point and heat of fusion depend on the strengths of the intermolecular forces of attraction
41
what happens if mass if greater when atoms are in proximity
the force between them will be greater
42
What is a dipole-ion bond?
the atraction between a full + or - atom with a slightly + or - atom Its the atraction between ionic molecule and a covalent polar molecule
43
why is dipole-ion stronger than dipole-dipole?
because it has a atom with hole charge
44
What intermolecular force has a induced dipole-dipole?
Londond Dispersion, because some times one atom pulls more than the other one.
45
How to know which force of a molecule has (steps):
1) if formula id given, draw lewis dot structure 2)if bonded directly with F, O or N its HYDROGEN BONG 3) if central atom doesnt have free electronsand the sorrounding elements are the same its non polar 4) if the molecule has just one element its non polar 5) If its non polar then its Van der Waals (London) 6) If non of the rules are aplied then its Dipole-Dipole
46
what means a atom is hydrophobic?
that it doesnt disolve in water (ion-ion and dipole-dipole)
47
what means a atom is hydrophilic?
that it disolves in water ( London)
48
List the intermolecular forces from stronger to weaker
1) ion-ion 2) ion-dipole (1 and 2 are solids normally) 3) Hydrogen bond 4) dipole-dipole (3 and 4 normally are liquid or gas) 5) London dispersion (gas)