Intra/Intermolecular forces Flashcards
(48 cards)
What are the two kinds of forces that operate in a molecule?
Intramolecular and intermolecular forces
Define intramolecular forces
Forces that hold atoms together within a molecule
Define intermolecular forces
Forces that exist between molecules
What is an ionic bond?
A bond formed by the complete transfer of valence electron(s) between atoms, generating two oppositely charged ions
What happens to electrons in ionic bonds?
The metal loses electrons to become a positively charged cation, while the nonmetal accepts those electrons to become a negatively charged anion
Define electronegativity
The affinity or desire for electrons.
OR
capacity of receiving electrons
What is a covalent bond?
A bond formed between atoms that have similar electronegativities, sharing electrons to achieve octet configuration
What are the two types of covalent bonds?
Polar and nonpolar covalent bonds
Define nonpolar covalent bond
A bond formed between same atoms or atoms with very similar electronegativities, with a difference less than 0.5 (they “pull” each other the same)
Define polar covalent bond
A bond formed when atoms of slightly different electronegativities (slightly + or -) share electrons, with a difference between 0.5 and 1.9 (one “pulls” the other one more)
What is metallic bonding?
A type of covalent bonding occurring between atoms of metals, where valence electrons are free to move through the lattice
What is the ‘sea of electrons’ in metallic bonding?
Mobile electrons that move freely and cause the attraction to fixed positively charged metal ions
How do intermolecular forces affect physical properties?
They determine boiling point, melting point, density, and enthalpies of fusion and vaporization
What is the relationship between boiling point and intermolecular attractions?
Lower boiling point indicates weaker intermolecular attractions, while higher boiling point indicates stronger attractions
What are dipole-dipole interactions?
Forces of attraction enabling two polar molecules to attract one another (slightly + with slightly -)
What is hydrogen bonding?
A special type of intermolecular attraction between hydrogen in a polar bond and an unshared electron pair on a nearby small electronegative atom (H with F, O or N, and these last three can be with another atom in their partially negative end)
- tronger atraction and needs considerable energy to break it
Is hydrogen bonding a chemical bond?
No, it is a stronger form of dipole-dipole attraction
Define London dispersion forces (Van der Waal forces)
Attraction between two nonpolar molecules due to temporary dipoles, the weakest of intermolecular forces, existing between all types of molecules
What factors affect the strength of London dispersion forces?
The number of electrons in a molecule; more electrons result in stronger forces
What is the effect of molecular size on dispersion forces?
As molecular size and molar mass increase, dispersion forces become stronger
Fill in the blank: The boiling and melting points of compounds depend on the type and strength of the _______.
intermolecular forces present
What are the types of intramolecular forces?
ionic, covalent and metallic bonds
what charge does a cation has?
positive, its a metal
what charge does a anion has?
negative, its a non-metal