INTRO TO POLYMER CHEM Flashcards

(37 cards)

1
Q

those that have side-[] chains that are
connected to the main chains.

A

branched

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2
Q

the R group are situated randomly at the alternate sides of the chain

A

Atactic configuration

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3
Q

CLASSIFICATIONS OF POLYMERS ACCORDING TO THERMAL RESPONSE

A

Thermoplastics (thermoplastic polymers)
Thermosets (thermosetting polymers)

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4
Q

modified natural polymers

A

semisynthetic

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5
Q

commercially sold water bottles, soft drink bottles, sport drink bottles, and condiment bottles

A

PET - polyethylene terephthalate

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6
Q

occurs in nature

A

natural

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7
Q

any plastic item not made from other 6 - cd’s, baby bottles, headlight lens

A

O - bisphenol A and others

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8
Q

when all the repeating units along a chain are different

A

Copolymer

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9
Q

those in which the repeat units are joined
together end to end in single chain

A

linear

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10
Q

add monomers to the growing chain.

A

propagation

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11
Q

CLASSIFICATIONS OF POLYMERS ACCORDING TO MOLECULAR STRUCTURE

A

linear
branched
cross-linked
network

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12
Q

Addition or Chain Polymerization Mechanism

A

Initiation
Propagation
termination

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13
Q

can be flexible or rigid is used for plumbing pipes, clear food packaging,

A

PVC - polyvinyl chloride

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14
Q

become permanently hard during formation and do not soften upon heating

A

Thermosets

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15
Q

TYPES OF GEOMETRIC ISOMERS

A

Cis- structure
Trans- structure

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16
Q

An R group is positioned on opposite sides of the double bond

A

Trans- structure

17
Q

are formed from simple addition of monomer molecules to each other in a quick succession by a chain mechanism without the liberation of small molecules.

A

addition polymer

18
Q

milk and juice bottles, detergent, shampoo, grocery bags, cereal box liners

A

PE-HD - polyethylene high density
HDPE

19
Q

yogurt containers, deli containers, furniture, luggage, winter clothing insulation

A

PP - polypropylene

20
Q

dry cleaning bags, bread bags, newspaper bags, paper milk cartons, produce bags, hot/cold beverage cups

A

LDPE - polyethylene low density

21
Q

the R group are situated at the alternate sides of the chain

A

Syndiotactic configuration

22
Q

soften when heated and harden when cooled processes that are totally reversible and may be repeated

A

Thermoplastics

23
Q

is a molecular compound distinguished by a high molar mass, ranging into thousands and millions of grams, and is constructed by the sequential stringing together of smaller molecules called monomers.

24
Q

An R group is positioned on same side of the double bond

A

Cis- structure

25
produces free radicals by breaking down a molecule
initiation
26
when two radicals encounter one another and combine. it eliminates both radicals and stop the growth of polymer chain
termination
27
adjacent linear chains are joined one to another at various positions by covalent bonds
cross-linked
28
when all the repeating units along a chain are of the same type
Homopolymer
29
occur between monomers containing polar groups which form polymer along with the elimination of small molecules
CONDENSATION POLYMERS
30
the R group are situated at the same side of the chain
Isotactic configuration
31
styrofoam - cups, plates, take-out containers
PS - polystyrene
32
a three-dimensional [] polymer that is formed from three or more active covalent bonds of multifunctional monomers
network
33
synthesized in the lab
synthetic
34
CLASSIFICATIONS OF POLYMERS ACCORDING TO ORIGIN:
natural, semisynthetic, synthetic
35
CLASSIFICATIONS OF POLYMERS ACCORDING TO MODE OF FORMATION:
addition polymers CONDENSATION POLYMERS Homopolymer Copolymer
36
CLASSIFICATIONS OF POLYMERS ACCORDING TO MOLECULAR CONFIGURATION:
TYPES OF POLYMERIC STEREOISOMERS TYPES OF GEOMETRIC ISOMERS
37
TYPES OF POLYMERIC STEREOISOMERS
Isotactic configuration Syndiotactic configuration Atactic configuration