Introductiom to organic Chemistry Flashcards
(28 cards)
General formula for alkanes
C2H2n +2
Generał formula for alkenes
C2H2n
General formula for cycloalkanes
C2H2n
State 2 features of a homologous series
-same functional group
-very similar chemical properties
Empirical formula
Simplest whole number ratio of the numbers of atoms of each element in a compound
Displaced formula
Shows every atom and bond within a compound
Skeletal formula
Only shows the carbon chain of on organic compound.No need to show hydrogen atoms but must show any other atoms attached to the carbon chain such as cl,br,o,oh
Structural isomerism
When molecules have the same molecular formula but different structural formula
Chain isomerism
when the longest chain is changed in a molecule
Positional isomerism
When the position of the functional group is changed
Functional group isomerism
when the functional group is changed so that 2 molecules have different functional groups but the same molecular formula
Stereo isomerism
Molecules have the same structure formula, but different arrangement of atoms in space
E/z isomerism
Do you have e/z molecules must have
-A double bond which restricts rotation
-Each carbon in the double bond must have two different groups bonded
Hydrocarbon
Compounds containing carbon and hydrogen only
Saturated hydrocarbon
Contains single bonds only
Alkanes
Saturated hydrocarbon that contains only C-C and C-H single bonds
Physical properties of alkanes
-Boiling point increases with increasing carbon chain length as there’s more electrons and stronger VanderWaal forces between molecules
-When branching and increases but the number of electrons remains the same boiling point decreases due to the weaker, VanderWaal forces and less surface contact
Name, a process of separating an alkane from a mixture of compounds
Fractional distillation
Outline essential features of fractional distillation
-different hydrocarbons have different boiling points
-Larger hydrocarbons have higher boiling points
-very hot temperatures at the bottom
-Larger hydrocarbons condense first and are collected at the bottom
Explain oil companies need to crack heavy fractions
Higher demand for small, alkanes and alkanes
What does thermal cracking produce?
Two alkanes one alkane
Conditions for thermal cracking
-high temperature=700-1200k
-high pressure=7000kpa
What does catalytic cracking
Cycloalkanes
Branched alkanes
Conditions for catalytic cracking
-high temperature =700k
-mild pressure=100kpa
-catalyst =zeolite