Introduction to Organic Chemistry: Isomerism - E/Z Isomers Flashcards Preview

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Flashcards in Introduction to Organic Chemistry: Isomerism - E/Z Isomers Deck (7)
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1
Q

What is stereoisomerism?

A
  • Stereoisomers have the same structural formula, but their atoms are arranged differently in place
2
Q

What is E/Z isomerism?

A
  • E–Z isomerism is a form of stereoisomerism and occurs as a result of restricted rotation about the planar carbon– carbon double bond
3
Q

Explain why molecules with a C=C double bond are planar and have restricted rotation

A
  • Carbon atoms in a C=C double bond and the atoms bonding to these carbons all lie in the same plane
  • Described to be trigonal planar
  • Atoms around C=C double bonds cannot rotate like they can around single bonds
4
Q

When do E/Z isomers occur in alkenes?

A
  • E/Z stereoisomers are caused by the restricted rotation about a C=C double bond
  • If both double-bond carbons have two different groups or atoms attached to them, you get E and Z isomers
5
Q

What are E isomers?

A
  • E (entgegen) means opposite
  • If the two substituents with the highest molecular mass are on different sides of the double bond (top/bottom), it is the E isomer
6
Q

What are Z isomers?

A
  • Z (zusammen) means together
  • If the two substituents with the highest molecular mass are on the same side of the double bond (top/bottom), it is the Z isomer
7
Q

What are the Cahn-Ingold-Prelog priority rules?

A

• Assign a priority to the two atoms attached to each side of the double bond (left/right)

  • Look at atoms directly bonded to each of the C=C carbon atoms
  • Atom with higher atomic number is given higher priority
  • If the same, look at next atom in groups

• Work out if they are E or Z

  • Look at how two highest priority groups are arranged
  • If they’re both on same side of C=C bond (top/bottom), it is Z
  • If they’re on different sides, it is E

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