IONIC EQUILIBRIA AND BUFFERED SOLUTIONS Flashcards

(51 cards)

1
Q

a substance that ionizes in water to produce hydrogen ions, H+

A

Arrhenius acid

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2
Q

a substance that dissociates in water to produce hydroxide ions, OH

A

Arrhenius base

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3
Q

acid is a proton (hydrogen ion) donor.

A

Brønsted-Lowry Acid

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4
Q

is a proton (hydrogen ion) acceptor.

A

Brønsted-Lowry base

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5
Q

Proton concept of Brønsted-Lowry

A

base + acid ↔ conjugate acid + conjugate base

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6
Q

The original BONDing Scientist

A

GILBERT N. LEWIS

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7
Q

electron-pair acceptor

A

Lewis Acid

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8
Q

electron-pair donor

A

Lewis base

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9
Q

Electron-pair concept

A

Lewis theory

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10
Q

Electron-pair concept

A

A substance that can act either as an acid or base

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11
Q
  • Numeric scale used to specify the acidity or alkalinity of an aqueous solution

The negative logarithm of H+ concentration

“power of hydrogen”

A

pH

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12
Q

Danish chemist in pH

A

Søren Peder Lauritz Sørensen in 1909

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13
Q

> pH 7
up to 14

A

Basic

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14
Q

=pH 7

A

Neutral

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15
Q

<pH7
down to o

A

Acidic

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16
Q

May be considered as weak acids or weak bases that exhibit color changes as their degree of dissociation varies with pH.

A

pH
indicators

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17
Q

Partially ionized in their solutions

A

Weak acids and bases

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18
Q

HCOOH

A

Formic

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19
Q

CH3COOH

A

Acetic

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20
Q

CC3COOH

A

Trichloroacetic

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21
Q

Hydrofluoric

22
Q

Hydrocyanic

23
Q

Hydrogen Sulfide

24
Q

NH3

25
N(CH3)3
Trimethyl Ammonia
26
C5H5N
Pyridine
27
NH4OH
Ammonium hydroxide
28
NH4
Ammonium
29
acid dissociation constant
Ka
30
negative logarithm of Ka
pKa
31
base dissociation constant
Kb
32
negative logarithm of Kb
pKb
33
pH = -log [H+]
Strong acids
34
pOH = -log [OH] pH = pKw - pOH
Strong bases
35
pH> pKa pH
High (Basic)
36
pH> pKa H+
Decreased
37
pH> pKa lonization
>50% IONIZED
38
pH
Low (Acidic)
39
pH
Increase
40
pH
>50% UN-IONIZED
41
pH = pKa pH
Neutral
42
pH = pKa H+
H+= OH-
43
pH = pKa lonization
50% IONIZED 50% UN- IONIZED
44
lonized Water Soluble
Water Soluble
45
lonized Lipid Membrane
DO NOT CROSS
46
Un-lonized Solubility
Water Insoluble
47
Un-lonized Lipid Membrane
CAN CROSS
48
A solution that resists major change in pH when small amounts of strong acid or strong base are added A typical huffer system contains a weak acid and its conjugate base
BUFFER SOLUTION
49
Common biochemical buffer systems are
H2CO3/HCO3 − H2PO4/HPO4 2+
50
The buffer component that reacts with added base Reaction converts it into its conjugate base
Weak Acid
51
The buffer component that reacts with added acid Reaction converts it into its conjugate acid
Conjugate Base of Weak Acid