Isomers Flashcards
(9 cards)
Structural isomers
same molecular formula but different structural formula (connected in different ways).
3 types of structural isomers – chain, position and functional group.
Chain isomers
same functional groups but different arrangements of the carbon skeleton. Some are straight chained while others are branched in different ways.
Position Isomers
same skeleton and same atoms or groups of atoms attached. Only difference is that the atoms or groups are attached to different carbon atoms.
Functional group isomers
same atoms arranged into different functional groups.
Stereoisomers
isomers that differ in spatial arrangement of atoms, rather than order of atomic connectivity
Chiral molecules
contain at least one carbon atom with four nonidentical substituents. Such a carbon atom is called a chiral center
Enantiomers
chiral molecules that are mirror images of one another
molecules are non-superimposable on one another
molecules cannot be placed on top of one another and give the same molecule
racemic mixture
consists of chiral molecules, but it has no net optical activity
process by which a racemic mixture is formed
racemization
One way to do this is to mix equal amounts of enantiomeric substances