IUPAC Nomenclature & Functional Groups Flashcards
Highest priority functional group is:
The most oxidized carbon functional group
Heteroatoms
Atoms besides carbon & hydorgen
What takes preference in labelling the carbon chain - double bond or triple bond:
Double bond
Ethyl alcohol/Ethanol
CH3CH2OH
Isopropyl alcohol/2-propanol
(CH3)(CH3)CHOH
Geminal diol
diol with hydroxyls on the same carbon
Vicinal diol
diol with hydroxyls on adjacent carbons
Aldehyde suffix
-al
Ketone suffix
-one
Prefix for aldehyde & ketone
oxo-
Naming system using greek letters next to carbonyl oxygen
alpha, beta, gamma, delta
Ester
-OR
Alkoxy group
-OR
Ester suffix
-yl and -oate/ -oic acid
Carboxylic acid suffix
-oic acid
Amide
Carbonyl group bound to N
Substituents on nitrogen in amide labelled with
N-
Amide suffix
-amide
Anhydride
formation from two carboxylic acid molecules
Acetyl group
CH3CO-
Acid Anhydride suffixes
-oyl and -oate
Acyl Chloride
-COCl
Acyl chloride suffix
-oyl chloride
When all substituents are same priority, how do you name the compound
By giving the lowest possible combination of numbers for substituents