Key Flashcards

1
Q

Ester —> 1° alcohol

A

+ excess LiALH4

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2
Q

Aldehyde —> 1° alcohol

A

+ NaBH4

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3
Q

Ketone —> 2° alcohol

A

+ NaBH4

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4
Q

Acyl chloride —> amide

A

2 equiv. R2NH

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5
Q

Aldehyde —> 2° alcohol

A

RMgX

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6
Q

Ester —> 3° alcohol

A

RMgX

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7
Q

Ketone —> 3° alcohol

A

RMgX

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8
Q

Methanal CH2O —> 1° alcohol

A

RMgX

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9
Q

Ester —> ester

A

NaOR, HOR

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10
Q

Alcohol —> alkyl bromide

A

PBr3
Inversion

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11
Q

Alcohol —> alkyl tosylate

A

TsCl
Retention

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12
Q

Alcohol —> alkyl chloride

A

SOCl2
Inversion

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13
Q

1° alcohol —> aldehyde

A

DMSO

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14
Q

2° alcohol —> ketone

A

DMSO

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15
Q

Alcohol —> alkene

A

POCl3

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16
Q

Ester —> carboxylic acid

A

NaOH, H2O

17
Q

Acetic anhydride —> ester

A

ROH or AROH

18
Q

Acetic anhydride —> amide

A

NH3, RNH2, or R2NH

19
Q

1,2 diols —> aldehyde or ketone

A

Concentrated H2SO4, △