Key Terms Flashcards

(49 cards)

1
Q

A chemical bond in which two atoms share one or more pairs of electrons.

A

Covalent Bond

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2
Q

Atoms of the same element having different numbers of neutrons in their nuclei.

A

Isotopes

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3
Q

A charged chemical species.

A

Ion

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4
Q

The most stable orbital arrangement of electrons in an atom or molecule.

A

Ground-state configuration

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5
Q

A chemical bond in which two atoms share one or more pairs of electrons.

A

Covalent Bond

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6
Q

The net electrical character arising from an asymmetric charge distribution.

A

Dipole moment

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7
Q

A compound formed between two elements with different electronegativities.

A

Ionic compound

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8
Q

A bond that possesses an asymmetric distribution of electrons.

A

A polar covalent bond

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9
Q

The molecular shape in which a central atom is bonded to four other atoms located at the corners of an imaginary tetrahedron.

A

Tetrahedral

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10
Q

The molecular shape in which a central atom is bonded to five other atoms located at the corners of a trigonal bipyramid.

A

Trigonal bipyramidal

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11
Q

The molecular shape in which a central atom is bonded to three other atoms lying in a plane at 120° angles to one another.

A

Trigonal planar

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12
Q

The principle of minimising electron–electron repulsion by placing electron pairs as far apart as possible.

A

Valence-shell-electron-pair repulsion (VSEPR)

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13
Q

The temperature and pressure above which the distinction between the liquid and vapour phases disappears.

A

Critical point

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14
Q

The attractive force between polar molecules that results from the negative end of one molecule aligning with the positive end of its neighbour.

A

Dipole–dipole forces

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15
Q

The force resulting from the induction of a dipole in a molecule by a neighbouring molecule having a permanent dipole.

A

Dipole-induced dipole forces

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16
Q

The attraction between the negatively charged electron cloud of one molecule and the positively charged nuclei of neighbouring molecules.

A

Dispersion forces

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17
Q

A moderately strong intermolecular attraction caused by the partial sharing of electrons between a highly electronegative atom of F, O or N and the polar hydrogen atom in a F─H, O─H or N─H bond.

A

Hydrogen bond

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18
Q

The ease with which the electron density about an atom or molecule can be distorted.

A

Polarisability

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19
Q

A molecule composed only of carbon and hydrogen atoms in which all carbon–carbon bonds are single.

A

Alkane

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20
Q

An unsaturated hydrocarbon with a carbon–carbon double bond.

21
Q

An unsaturated hydrocarbon with a carbon–carbon triple bond.

22
Q

The bonds connecting axial groups. For organic conformers, the axial bonds are those that are oriented perpendicular to the plane of the chair, boat or envelope.

23
Q

A stereoisomer that differs in the positioning of two groups with respect to a reference plane.

A

cis–trans isomer

24
Q

An isomer that cannot be interconverted by rotation around a single bond.

A

Configurational isomer

25
Isomers with different sequences of atom connectivity.
Constitutional isomers
26
Bonds oriented in a chair conformation of a cyclic structure in the general plane of the seat of the chair.
Equatorial bonds
27
A group of atoms within an organic molecule that determines the molecule’s chemical reactivity.
Functional group
28
A molecule composed only of carbon and hydrogen atoms.
Hydrocarbon
29
A hydrocarbon in which at least one carbon atom does not have the maximum possible number of atoms bonded to it.
Unsaturated hydrocarbon
30
A compound in which the carbon atom of the C═O group is bonded to two hydrocarbon groups.
Ketone
31
Isomers with the same molecular formula and the same connectivity but different orientations of their atoms in space.
Stereoisomers
32
A molecule that contains a separation of electric charge.
Polar molecule
33
Molecules with the same molecular formula but different structures.
Isomers
34
An ─OH group.
Hydroxyl Group
35
A functional group generated by combining a carboxylic acid and an alcohol with the elimination of water to give a carbonyl carbon atom that is also further bound to a different saturated carbon atom via an oxygen atom linkage.
Ester
36
A pair of stereoisomers that are nonsuperimposable mirror images of each other.
Enantiomers
37
A compound with two alcohol groups.
Diol
38
A pair of stereoisomers that are not mirror images of each other.
Diastereomers
39
Isomers with different sequences of atom connectivity.
Constitutional isomers
40
Describes an object that is not superimposable on its mirror image.
Chiral
41
A ─COOH group.
Carboxyl group
42
Molecules containing the C═O (carbonyl) group.
Carbonyl compounds
43
An acyl group bonded to a trivalent nitrogen atom.
Amide
44
An amine in which the nitrogen atom is bonded only to alkyl groups.
aliphatic amine
45
A compound containing an ─OH (hydroxyl) group bonded to an sp3 hybridised carbon atom.
Alcohol
46
A carbonyl group bonded to an alkyl or aryl group
Acyl group
47
Describes an object that lacks chirality; that is, it is superimposable on its mirror image.
Achiral
48
Derivatives of ammonia in which one or more hydrogen atoms are replaced by alkyl or aryl groups.
Amines
49
The ease with which the electron density about an atom or molecule can be distorted
Polarisability