Le Chatelier's Principle Flashcards

(35 cards)

1
Q

What is Le Chatelier’s principle?

A

Le Chatelier’s principle states that if a dynamic equilibrium is disturbed by changing the conditions, the position of equilibrium shifts to counteract the change.

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2
Q

True or False: Increasing the concentration of a reactant shifts the equilibrium to the right.

A

True

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3
Q

What effect does decreasing the volume of a gas mixture have on equilibrium?

A

Decreasing the volume shifts the equilibrium towards the side with fewer moles of gas.

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4
Q

Fill in the blank: According to Le Chatelier’s principle, if the temperature of an exothermic reaction is increased, the equilibrium will shift to the __________.

A

left

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5
Q

How does increasing the concentration of products affect the equilibrium position?

A

It shifts the equilibrium to the left, favoring the formation of reactants.

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6
Q

What happens to equilibrium when a catalyst is added?

A

A catalyst does not affect the position of equilibrium; it only speeds up the rate at which equilibrium is reached.

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7
Q

True or False: Decreasing the temperature of an endothermic reaction shifts the equilibrium to the right.

A

False

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8
Q

In a reaction with equal moles of gas on both sides, what is the effect of changing the volume?

A

There is no effect on the position of equilibrium.

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9
Q

What is the effect of increasing temperature on an endothermic reaction?

A

It shifts the equilibrium to the right, favoring product formation.

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10
Q

Multiple Choice: What happens when the concentration of a reactant is decreased?

A

A) The equilibrium shifts to the right B) The equilibrium shifts to the left C) No change D) The reaction stops

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11
Q

What is a dynamic equilibrium?

A

A dynamic equilibrium is a state in which the rates of the forward and reverse reactions are equal, resulting in constant concentrations of reactants and products.

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12
Q

Fill in the blank: An increase in pressure will shift the equilibrium towards the side with __________ moles of gas.

A

fewer

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13
Q

True or False: Adding an inert gas to a reaction at constant volume affects the equilibrium position.

A

False

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14
Q

What happens to the equilibrium position if both reactants and products are increased equally?

A

There is no change in the position of equilibrium.

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15
Q

What type of reaction is favored by decreasing temperature?

A

Exothermic reactions are favored by decreasing temperature.

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16
Q

Multiple Choice: Which of the following will NOT change the position of equilibrium?

A

A) Change in concentration B) Change in temperature C) Addition of a catalyst D) Change in pressure

17
Q

How does a shift to the right affect the concentrations of reactants and products?

A

It increases the concentration of products and decreases the concentration of reactants.

18
Q

Define ‘shift to the left’ in terms of equilibrium.

A

A shift to the left means that the reaction favors the formation of reactants over products.

19
Q

True or False: The position of equilibrium can be affected by changes in temperature, pressure, and concentration.

20
Q

What is the effect of increasing pressure on a reaction with more moles of gas on the reactants side?

A

It shifts the equilibrium to the left.

21
Q

Fill in the blank: A __________ reaction absorbs heat from the surroundings.

22
Q

What is the relationship between the direction of the shift and the nature of the reaction (endothermic/exothermic)?

A

For endothermic reactions, increasing temperature shifts right; for exothermic reactions, it shifts left.

23
Q

Multiple Choice: What effect does a decrease in temperature have on an exothermic reaction?

A

A) Shifts right B) Shifts left C) No effect D) Reaction stops

24
Q

What is the impact of dilution on the equilibrium of a reaction involving aqueous solutions?

A

Dilution decreases the concentration of all species, potentially shifting equilibrium depending on the relative changes.

25
True or False: Changing the concentration of a solid or liquid in a reaction at equilibrium changes the position of equilibrium.
False
26
What is the effect of adding more solvent to a reaction at equilibrium?
It can shift the equilibrium towards the side with more solute particles.
27
Fill in the blank: The equilibrium constant (K) is only affected by changes in __________.
temperature
28
What is meant by 'equilibrium constant'?
The equilibrium constant (K) is a numerical value that expresses the ratio of the concentrations of products to reactants at equilibrium.
29
True or False: The equilibrium position can be predicted based on the coefficients in the balanced equation.
True
30
What role does temperature play in Le Chatelier's principle?
Temperature changes can favor either the forward or reverse reaction, depending on whether the reaction is endothermic or exothermic.
31
Multiple Choice: Which factor does NOT affect the equilibrium position?
A) Concentration B) Temperature C) Catalyst D) Pressure
32
What does a shift in equilibrium indicate about the reaction?
It indicates that the reaction is responding to changes in concentration, pressure, or temperature to restore balance.
33
Fill in the blank: When the concentration of products decreases, the equilibrium shifts to the __________.
right
34
What is the principle behind Le Chatelier's principle?
The principle is based on the system's tendency to counteract changes to re-establish equilibrium.
35
what are some examples of stressors in chemical rxns?
changes in temp, conc, vol, and pressure