Lec4 Flashcards
(31 cards)
Thermodynamics science dealing with
_______,________,________.
heat, work and energy
Thermodynamics is an experimental science concerned with the study of everything related to______________ and_________________.
temperature
thermal energy
Thermodynamics is used in many branches of science such as…………
medicine, pharmacy, physics, chemistry and engineering applications
0th Law ⇒ Defines……
1 st Law ⇒ Defines……
2nd Law ⇒ Defines……
3rd Law ⇒ Gives Numerical Value to……
Temperature (T)
Energy (U or E)
Entropy (S)
Entropy
system………
is the specific part of the material to which the study is directed
Surrounding is …………
is the part that surrounds the system and exchanges energy or matter with it
The universe is…………
is both the system and the surrounding
A state function is……
is a property whose value does not depend on the path taken to reach that specific value
state functions include:
density, internal energy, enthalpy, entropy ,
path function is ……
Functions that depend on the path from two values are call path
functions.
Two important examples of a path function are:
heat and work
Process ………
is any change in a system that results in a change in pressure, temperature, or volume (thermodynamic coordinates).
Isothermal process is ………
it is the process in which the change is under a constant temperature
An isothermal process is one where the temperature………
does not change.
Adiabatic process :………
It is the process in which there is
no change in the amount of heat and takes place in an isolated system
An adiabatic process is one where there is no heat flow into or out of the system
T/F
T
Isobaric process : is……
: it is the process in which change is under constant pressure
reversible process is ……
A thermodynamic process (state i → state f ) is said to be reversible if the process can be turned back to such that both the system and the surroundings return to their original states, with no other change anywhere else in the universe. Changes are infinitesimally small in a reversible process.
Irreversible process
is one in which the system and its environment cannot return together to exactly the states that they were in. the thermodynamic coordinates are not homogeneous when the operation is performed
All Spontaneous processes are____________
irreversible
All Real processes are__________
irreversible
Thermal equilibrium is ……
: when the temperature is the same throughout the entire system.
Mechanical equilibrium: is……
when there is no change in pressure at any point of the system. However, the pressure may vary within the system due to gravitational effects.
Chemical equilibrium: ……
when the chemical composition of a system
does not change with time, i.e., no
chemical reactions occur.