Lec4 Flashcards

(31 cards)

1
Q

Thermodynamics science dealing with
_______,________,________.

A

heat, work and energy

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2
Q

Thermodynamics is an experimental science concerned with the study of everything related to______________ and_________________.

A

temperature

thermal energy

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3
Q

Thermodynamics is used in many branches of science such as…………

A

medicine, pharmacy, physics, chemistry and engineering applications

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4
Q

0th Law ⇒ Defines……
1 st Law ⇒ Defines……
2nd Law ⇒ Defines……
3rd Law ⇒ Gives Numerical Value to……

A

Temperature (T)

Energy (U or E)

Entropy (S)

Entropy

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5
Q

system………

A

is the specific part of the material to which the study is directed

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6
Q

Surrounding is …………

A

is the part that surrounds the system and exchanges energy or matter with it

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7
Q

The universe is…………

A

is both the system and the surrounding

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8
Q

A state function is……

A

is a property whose value does not depend on the path taken to reach that specific value

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9
Q

state functions include:

A

density, internal energy, enthalpy, entropy ,

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10
Q

path function is ……

A

Functions that depend on the path from two values are call path
functions.

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11
Q

Two important examples of a path function are:

A

heat and work

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12
Q

Process ………

A

is any change in a system that results in a change in pressure, temperature, or volume (thermodynamic coordinates).

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13
Q

Isothermal process is ………

A

it is the process in which the change is under a constant temperature

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14
Q

An isothermal process is one where the temperature………

A

does not change.

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15
Q

Adiabatic process :………

A

It is the process in which there is
no change in the amount of heat and takes place in an isolated system

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16
Q

An adiabatic process is one where there is no heat flow into or out of the system
T/F

17
Q

Isobaric process : is……

A

: it is the process in which change is under constant pressure

18
Q

reversible process is ……

A

A thermodynamic process (state i → state f ) is said to be reversible if the process can be turned back to such that both the system and the surroundings return to their original states, with no other change anywhere else in the universe. Changes are infinitesimally small in a reversible process.

19
Q

Irreversible process

A

is one in which the system and its environment cannot return together to exactly the states that they were in. the thermodynamic coordinates are not homogeneous when the operation is performed

20
Q

All Spontaneous processes are____________

21
Q

All Real processes are__________

22
Q

Thermal equilibrium is ……

A

: when the temperature is the same throughout the entire system.

23
Q

Mechanical equilibrium: is……

A

when there is no change in pressure at any point of the system. However, the pressure may vary within the system due to gravitational effects.

24
Q

Chemical equilibrium: ……

A

when the chemical composition of a system
does not change with time, i.e., no
chemical reactions occur.

25
Energy States : 3
1️⃣-Unstable: falling or rolling 2️⃣-Stable: at rest in lowest energy state 3️⃣-Metastable: generally has a shorter lifetime than the lowest
26
**Open** System is …….
which is the system that allows the exchange of matter and energy between the system and the surrounding medium.
27
**Closed ** system is…….
which allows the exchange of energy only between the system and the surrounding medium in the form of heat or work.
28
**Isolated ** system is …….
does not allow the transfer of any of the energy and matter between the system and the surrounding medium.
29
**First law of thermodynamics** states that :
energy is Conserved; can neither be created nor destroyed, only altered in form
30
The 1st Law of Thermodynamics is a statement of____________
conservation of energy
31
The internal energy of a system can changes in two general ways As heat or as work T/F
T