Lecture 1- Bonds Flashcards
(33 cards)
What is the bonding process?
electrons bond to nucleus to form an atom, atom bond together to form a molecule, molecules bond together to form a solid.
Orbital are known as
electron shells, they have fixed energy levels
Bond energy is also known as
bonding energy or ionization potential
What causes strong bonds
more negative energy and therefore more stability
What does an incomplete orbital imply
more possible bonds given by the electronegativity values
What is electronegativity
is the power of an atom in a molecule that will hold or attract electrons to itself
Tendency of electronegativity
decreases as it goes down the periodic table and increases as it goes to the right
Factors of Bonding
seek for octet completion and occurs due to electrostatic attraction (positive and negative)
Types of Bonding
ionic, metallic, covalent
Ionic bonding tendency
electrons will transfer from the almost empty valence bond to the almost full valence band/ minimizes potential energy
Covalent bonding tendency
electrons are shared in a common valence shell, potential energy is minimized, visualized as electrostatic potential surface
Metallic bonding tendency
electrons are shared in a delocalized manner, for good conductors of electricity , good ductility, properties can be tailored to application
Weakest type of bond and why
metallic because of possible chemical reactions like corrosion
What is ductility
ability to be stretched or bent without breaking
What is delocalized manner
can move through solids and away from original atom
How is the bond type triangle set up
it is between two different binary compounds. x values: compares electronegativity of compounds & y values: difference in electronegativity
What does the bond type triangle do
separates compounds into MIC regions (METALLIC, IONIC AND COVALENT) & if they are metals and covalent (METALLOIDS)
Nonbonding interactions
electrons are not shared and are usually polar molecules (permanent dipole) or induced dipoles (temporary dipoles)
How do you calculate dipole moments
mu= charge * distance
Hydrogen bonding is also called
H-bond or hydrogen bridge
How does the hydrogen bond occur
hydrogen bonds to 2 elements through electrostatic attraction
Between which elements does hydrogen bonding occur
oxygen, nitrogen and fluorine
Permanent dipoles are also called
dipole-dipole interaction
Permanent dipole tendency
molecules line up, weaker than hydrogen bonding