Lecture 1 : Intro Flashcards

1
Q

What are functional flavours? Give examples

.

A

Functional flavours are flavours that perform a specific function, such as flavour masking / enhancing / taste modifying ; or containing functional substances

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Functional substances examples
- artifical sweeteners for calorie reduction / sugar replacement
- metal chlorides (e.g. KCl) for salt reduction

Functional flavors are ingredients that enhance the taste of food and drinks while also providing health benefits.

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2
Q

What is the difference between off flavours and off taints?

A

Off-flavours are undesirable taste / smells arising from the detioriation of the food product, while flavour tants are undesirable taste / smells caused by contamination by an external environmental source.

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3
Q

What are the 2 values that describes the potency of flavour compounds (odourants, tastants) and what are their equations?

A
  1. Odour activity value = [odourant] / detection threshold (conc)
  2. Taste activity value = [tastant] / detection threshold (conc)

Both activity values are ratios

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4
Q

What are the 5 basic tastes?
And the 6th and 7th basic taste?

A
  • 5 basic taste : sweet, sour, salty, umami, bitter
  • 6th basic taste : kokumi
  • 7th basic taste : fat taste
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5
Q

Saltiness and sour taste is perceived through the activation of ____ on taste receptors.

A

Ion channels

sodium ions (Na+) entering the cell through channels primarily mediate salty taste, while hydrogen ions (H+) from acids entering through channels like ASICs (acid-sensing ion channels) trigger the perception of sourness

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6
Q

Sweetness and bitterness are perceived by ____ on taste receptors

A

Surface proteins

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7
Q

Kokumi is perceived by what receptors ?
What groups of compounds give rise to kokumi? [3]

A

G-protein coupled receptors;;

Compounds that give rise to kokumi : 1. Peptides & amino acids
2. Sulfur-containing compounds (in garlic, onion)
3. Lactones -> contribute to creaminess and mouthfeel (found in dairy / fatty foods)

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8
Q

Sweetness is most commonly associated with what group of compounds?

A

Simple sugars
- monosaccharides
- dissacharides

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9
Q

Other than simple sugars, what other classes of natural sweeteners are there? [3]

A
  1. Sugar alcohols (cooling sensation) - replace aldehyde grp of sugars with -OH
  2. Sweet proteins
  3. Glycosides -> sugar molecules that are bonded to other functional groups through glycosidic bonds
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10
Q

All sweet substances (steviol glycosides) produced from the stevia plant has the same sweetness and taste. True or False?

A

False. It depends on the number of glucose molecules present in the glycoside and location of glycosidic linkages, which can affect sweetness and bitter aftertaste.
- In general, more sugar units = sweeter and less bitter

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11
Q

Sugar alcohols have higher sweetness activity than sucrose (1.0). True or False?

A

False.

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12
Q

Which sugar alcohol has the sweetness closest to sucrose (1.0)?

A

Xylitol

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13
Q

All sweet proteins (100-3000) are inherently sweet. True or False?

A

False, sweet proteins such as Miraculin don’t have a sweet taste, but they conduct flavour modification by turning sourness into sweetness, thus increasing perception of sweetness

**Miraculin itself is not sweet. It binds to sweet taste receptors when acids are present.
This causes sour-tasting foods, like citrus, to be perceived as sweet. **

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14
Q

Artificial sweetners have ____ sweetness intensity than sucrose (1.0). state the values too.

A

Higher
- 200 - 20,000

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15
Q

What are some key differences between artificial sweeteners and natural sweetners, orther than sweetness activity? [4]

A

Artifical sweetners …
1. Lower in calories
2. Lower GI (as they are not digested)

3. Have a different mouthfeel
4. Have undesirable bitter aftertaste

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16
Q

List some examples of artifical sweetners. [6]

A

1.Cyclamate
2. Acesulfame potassium (Ace K)
3. Aspartame
4. Neotame
5. Saccharin
6. Sucralose

CAANSS

17
Q

Sour taste is usually associated with what class of compounds?

A

Organic aicds

18
Q

Which organic acid is the gold standard for sourness in the food industry?

A

Citric acid

19
Q

Phosphoric acid is used as an acidulant in what applications?

A

Beverages (soft drinks)

20
Q

Saltiness is usually associated with what compound?

A
  • Sodium (sodium chloride)
21
Q

What other substitutes can be used as salt (NaCl) replacers? [2,4]

A
  1. Metal chlorides (KCl, CaCl2)
  2. Metal sulfates (Na+, K+, Mg2+, Ca2+)
22
Q

What is the advantage and disadvantages of using KCl as a salt subsititue?

A

Advantage : reduce sodium intake, and increase potassium intake, in which many people are lacking. (reduced sodium also means reduced risk of hypertension)

Disadvantages :
1. lower saltiness (0.6)
2. bitter aftertaste

23
Q

Bitter substances are associated with what kind of compounds? [3]

A
  1. bitter AA / peptides (hydrophobic)
  2. Polyphenols (tannin)
  3. Alkaloid (caffeine)
23
Q

Umami / savoury substances are associated with what types of compounds? [3]. Give examples where applicable

A
  1. Peptides
  2. Amino acids (glutamate, MSG)
  3. Nucleotides : Guanosine monophosphate (GMP), inosine monophosphate (IMP)

Note : glutathione is a kokumi peptide, nit umami!

24
What is the definition of key odourants / character-impact aroma compounds?
A single / a group of aroma compounds that provide characteristic aroma of the food.
25
What are trigeminal sensations? Give the 3 most common trigenimal sensations.
Chemical sensations perceived by the trigeminal nerve.
Trigeminal sensations: 1. Astringency 2. Cooling sensation 3. Hot / pungent / spicy / tingling
26
What compounds is atringency associated with and how does astringency arise?
Astringency is associated with polyphenols, where they interact with salivary Proline-rich proteins and cause these proteins to precipitate, creating a dry, puckering sensation.
27
# **Chemethesis - trigeminal sensation** The cooling sensation is related to what group of compounds ? [1] Other than that group of compounds, what other 3 compounds can give rise to cooling sensation?
Sugar alcohols (aka polyols) (alcohols with more than 1 -OH group) **Examples** - Menthol : alcohol - Mentone : monoterpene alcohol - L-carvone : terpenoid
28
Hot / pungent / spicy / tingling is related to what compounds?
Capsaicin Capsaicinoids Piperine .....
29
# **Lab** What is the character impact compound for strawberry flavour?
Furaneol - Sweet, characteristic smell of strawberry / caramel
30
Benzaldehyde is the aroma character character-impact compound of a) apricot b) apple c) almond d) avocado e) asparagus.
c) almond
31
What is isomaltulose? Which enzyme is responsible for producing isomaltulose?
Isomaltulose (α-1,6 bond) is an isomer of sucrose (α-1,2 bond). - enzyme : isomerase