Lecture 2 Flashcards

(42 cards)

1
Q

Why is carbon cycle important?

A

Sustaining biosphere.

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2
Q

Why is carbon important?

A

Fixing solar energy for entire ecosystem (photosynthesis)

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3
Q

How is carbon cycled and exchanged?

A

Photosynthesis, decomposition, respiration, and mineralisation.

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4
Q

What are heterotrophs?

A

Other feeders, cannot make their own food.
Oxidising organic molecules consumed from other organisms.

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5
Q

What are the heterotrophs processes?

A

Fermantation: anoxic environment, ferment carbohydrates to produce ethanol and other compounds.
Anaerobic respiration: some microorganisms use nitrate, sulphates and CO2 as electron acceptors in absence of oxygen.
Aerobic respiration: organic material completely oxidised to CO2+H2O

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5
Q

What are autotrophes?

A

Self feeders, use external source of energy, such as sunlight or chemically reduced matter

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6
Q

Where to autotrophic organisms derive carbon from?

A

Photosynthesis .
Oxygenic
CO2 + H2O -> (CH2O)n + O2
Anoxygenic
CO2 + H2S -> (CH2O)n + So

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7
Q

what are fast fluxes of carbon?

A

removal of CO2 from environment due to photosynthesis.

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7
Q

How is CO2 returned to environment?

A

Byproduct of respiration.

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8
Q

What is organic decomposition?

A

fungi and bacteria obtain organic material from dead sources.
produces CO2 and H2O, consumes O2.

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9
Q

What are primary factors determining terrestrial carbon?

A

Rain water and snow melt water.

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10
Q

What accounts for 90% of carbon flux between land and water?

A

Bicarbonate. (controls pH of natural waters)

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10
Q

Four forms of oceanic carbon.

A

DOC, DIC, POC, and marine biota itself.

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11
Q

Main mechanism of carbon removal in oceans?

A

Burial in sediments. Does not approach intake. 10000 year residence time.

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12
Q

Why does adding CO2 to atmosphere take hundreds of years to recalibrate?

A

Ability of carbon cycle to transport excess carbon away from atmosphere takes a long time.

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13
Q

What happens to CO2 from atmosphere?

A

Reduced by autotrophic organisms. Formula is: CO2 + H2O -> (CH2O)n + O2

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14
Q

What is gross primary production?

A

Total rate of photosynthesis consumed by respiration.

15
Q

What is primary net production?

A

Rate of storage of organic matter in excess of respiration.

16
Q

Largest reservoir of carbon.

A

Lithosphere. Very long turnover times.

17
Q

How is carbon released from lithosphere?

A

Erosion (resides in ocean for 10^5 years).
Resides in lithosphere for 10^8 years.

18
Q

Oxidation of reduced carbon?

A

C0(s) + O2 -> CO2

19
Q

Dissolution of carbonates?

A

CaCO3 (s) + CO2 (g) + H2O -. Ca2+ (aq) + 2HCO3-(aq)

20
Q

Impacts of human activity for carbon cycle.

A

Increased atmospheric CO2 by 50% since 1960 to today.
produce an excess 1000 metric tonnes of CO2 moved to atmosphere and hydrosphere.
Fossil fuels are carbon, and CO2 is released when burned. Removed from lithosphere moved to atmosphere. CO2 in atmosphere aborbs heat and re emits (greenhouse effect).
Deforestation and land-use changes also affect carbon cycle.
Increasing CO2 causes ocean acidification and temperature increases.
O2 is also consumed during combustion, concern for biodiversity.

21
Q

Why is Nitrogen important?

A

Essential element of protein (growth and energy)

22
Why does N2 need to be fixed?
N2 cannot be used by plants and animals.
23
What is N- fixation
Reduction of atmospheric N2 to NH3 or NH4+ or any organic N. N2+8H+ +8e- -> 2NH3 + H2
24
What is Nitrification
Oxidation of NH3 or NH4+ to NO2- then NO3- by microorganisms to produce energy.
25
Equation for AOB?
4NH4 + 6O2 -> 4NO2- + 4H20
25
How is ammonia oxidised?
Two groups of bacteria in sequence: AOB (ammonia oxidising bacteria) then NOB (Nitrite oxidising bacteria)
26
Equation for NOB
8NO2- + 4O2 -> 8NO3-
27
What is denitrificaton?
Reduction of NO3- to N2 or N2O. Performed by aerobes.
27
Equation for denitrification?
2NO3- + 12H+ -> N2 + 6H2O
28
DNRA
NO3- to Ammonium
28
Equation for DNRA?
NO3- + 8Fe2+ +21H2O -> NH4+ + 8Fe(OH)3 + 14H+
29
What is ammonification?
Breaking down of organic N to NH3 or NH4+.
30
What is Annamox?
Anaerobic ammonium oxidation.
30
Equation for ammonification?
(NH2)2CO -> CNO- + NH4+
31
Equation for Annamox
NH4+ + NO2- -> 2H2O + N2
32
Describe disruption of Nitrogen Cycle.
Humans have altered N cycle by intensive use of agriculture with an input of N as fertilisers. River runoff is main connection between terrestrial and ocean reservoirs. Fertilisers pollute ground water and bioaccumulate in food. NO3- is not considered toxic but leads to blue baby syndrome and linked with stomach cancer. Eutrophication when NO3- accumulates in water. Algal blooms in ponds in lake. Another way is NO production during combustion. High temperature combination of N2 and O2. Primary cause of smog. Irritates eyes, causes pulmonary disease, cardiovascular disease and asthma. Most NO is converted into HNO3 which contributes to acid rain, destroying aquatic systems and leach minerals and nutrients from soil. Changing agriculural practices increases biological N fixation by planting N fixing microorganisims such as legumes and cloves. Removes N from atmosphere and move to biosphere.
33
Why is phosphorous important?
Building block for DNA and essential for life, non-renewable, added to fertilisers
34
Describe the steps in phosphorous cycle.
1. Tectonic uplift, exposure to phosphorous-bearing rocks. 2. Physical erosion and chemical weathering provide dissolved and particulate phosphorous to rivers. 3. River transport takes to ocean. 4. Burial in sediments.
35
Phosphorous cycle disruption.
Mining phosphate rocks. 90% of countries do not have significant P reserves.