Lecture 7-Ionic Bonding Flashcards

(57 cards)

1
Q

What is a chemical bond?

A

The attractive force that holds 2/+ atoms together in a molecule

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2
Q

Why do atoms combine?

A

To gain stability

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3
Q

How do e- in atoms distribute themselves?

A

In the most stable/lowest energy configuration

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4
Q

How can a combined molecule achieve lower energy?

A

By rearranging e- between atoms

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5
Q

All element except who show a strong tendency to join with other elements to form compounds/

A

Noble gases

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6
Q

What group of elements obey the 18 e- rule and not the octet rule?

A

Transition metals

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7
Q

The strength of an electrostatic interaction is what?

A
  • Proportional to the size of the charge

- Inversely proportional to distance^2

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8
Q

What operates between 2 atoms when they come close together?

A

Attractive + repulsive forces

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9
Q

When do like charges repel?

A

E-/E- + nucleus/nucleus

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10
Q

When do opposite charges attract?

A

E-/nucleus

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11
Q

What is electronegativity?

A

The ability of an atom to attract toward itself the e- in a chemical bond

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12
Q

What does electronegativity depend on?

A
  • N.O of protons
  • Distance from the nucleus
  • Amount of screening by inner e-
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13
Q

What is the most electronegative element and why?

A

Fluorine

  • Small
  • High nuclear charge
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14
Q

What does covalent bonding show?

A

Polarity of bonds

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15
Q

What does ionic bonding show?

A

Initial transfer of e- + direction

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16
Q

How are ionic bonds formed?

A

When 1/+ e- are FULLY transferred between atoms

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17
Q

Where does ionic bonding take place?

A

Between metals + non-metals

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18
Q

Metal atoms do what to attain noble gas structure?

A

Lose e- —–> cations (positive ions)

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19
Q

Non-metal atoms will do what to attain noble gas structure?

A

Gain e- —–> anions (negative ions)

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20
Q

What does the formation of an ionic bond involve?

A

A DECREASE in energy compared to 2 isolated atoms

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21
Q

The valency of an ion = what?

A

Its charge

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22
Q

Is an ionic bond non-directional?

A

YES

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23
Q

What does non-directionality mean?

A

The strength of the bond depends upon DISTANCE not directions

24
Q

What do ionic compounds dissolve + disassociate in?

A

Polar solvents

25
Are ionic compounds charged overall?
NO
26
When do ionic compounds conduct electricity?
When molten / in solution
27
What do ionic compounds form?
Regular crystalline solids with high melting temperatures
28
In an ionic lattice, what is every ion attracted to?
All other ions with the opposite charge
29
What is lattice energy?
The enthalpy of formation energy change forming 1 mole of ionic solid from its gaseous ions - measures bond strength
30
What factors favour an easy cation formation?
Low ionization energy of the METAL
31
What factors favour an easy anion formation?
- High e- affinity/electronegativity of the non-metal - Small size of NON-METAL - Low charge on ANION - Large electronegativity DIFFERENCE between combining atoms - High lattice energy of IONIC COMPOUND
32
What ions are smaller than parent ions?
Positive ions
33
What is polarisation?
Distortion of the e- cloud of an atom
34
How does a small ion have more polarizing power?
Higher charge density
35
How does a large ion have great polarizability?
Larger its N.O of e-
36
DO anions / cations have more polarising power and why?
CATIONS , because they are generally smaller
37
If a negative ion is distorted ,because of polarisation it has what?
COVALENT character
38
What is an ideal ionic compound composed of?
Completely separate spherical ions
39
When is an ionic compound likely to have covalent character?
The cation = small +/ high charge (highly polarising) | The anion = large +/ high charge (highly polarisable)
40
What are polyatomic ions?
Ions made up of more than 1 type of atom
41
What type of binding is present in polyatomic ions?
Covalent
42
Ammonium
NH4+
43
NITRATE
NO3-
44
CYANIDE
CN-
45
SULFATE
SO4 2-
46
HYDROXIDE
HO-
47
CARBONATE
C03 2-
48
PEROXIDE
02 2-
49
PHOSPHATE
P04 3-
50
ACETATE
CH3CO2-
51
PERMANGENATE
Mn04-
52
OXALATE
C2O4 2-
53
DICHROMATE
CrO7 2-
54
What is the first word of an ionic compound name?
The CATION (except ammonium)
55
What is the second word of an ionic compound name?
The ANION
56
If the second name of an ionic compound is polyatomic, what does it end in?
The name of the polyatomic ion
57
If the second name of an ionic compound is the element what does it end in?
-ide