Lectures 4-7 Flashcards

1
Q

Internal Energy is…

A

Sum of all of the microscopic forms of energy

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2
Q

Boundary work is…

A

Work associated with the system boundary changing shape

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3
Q

Equation for boundary work

A

W b = P * change in V

Boundary W = pressure * change in volume

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4
Q

The general equation for boundary work

A

W b = integral ( P dV )

Boundary W = integral (pressure * change in volume)

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5
Q

Enthalpy combines…

Denoted by letter…

A

Internal energy and Boundary work

H

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6
Q

Enthalpy should be used for systems with a …

A

CHANGING volume

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7
Q

On the other hand, internal energy should be used for systems with a…

A

FIXED volume

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8
Q

Base equation of enthalpy

A

H = U + W b

Enthalpy = internal energy + Boundary work

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9
Q

Equation for enthalpy subbing in for the Boundary work equation

A

H = U + PV

Enthalpy = Internal energy + (pressure * volume)

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10
Q

First Law of Thermodynamics

A

Energy can neither be created or destroyed; it can only change forms

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11
Q

An energy balance is when you …

A

find the difference in the sums of all the energy going into the system as well as those leaving the system.

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12
Q

When carrying out an energy balance equation, we must remember to account for the energy associated with

A

mass

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13
Q

When considering a stationary system energy balance equation, what can we assume as 0… This leaves only —, — and — to consider.

A

Kinetic and all potential energies

Mass, work and heat

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14
Q

What interactions affect the energy content of a control volume/system?

A

As well as mass flow, heat and work

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15
Q

When analysing a closed system what term can we remove from the energy balance equation

A

mass term as it is a closed system where no mass crosses the system boundary

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16
Q

Closed system energy balance equation is

A

E system = Q net + W net

E system = change in U (change in internal energy)

as change in U = Q net + W net (net thermal energy and net work done)

17
Q

When a system runs in a cycle, what must return to its original state

A

The working fluid

18
Q

Efficiency in terms of a system measures what

A

how well an energy transfer or conversion has been carried out

19
Q

Specific heat capacity is defined as

A

the amount of energy required to raise the temperature of a unit mass of substance by one degree

20
Q

In thermo module, the two types of specific heat are

A

c v (constant volume) and c p (constant pressure)

21
Q

For solids and vapours are there two different values for specific heat?

A

No

22
Q

State specific heat capacity at constant volume

A

The amount of energy required to raise the temperature of a unit mass by 1K (or 1 degree C) with the volume being held constant.

23
Q

Equation for specific heat capacity at constant volume, to derivation of final equation using the 1st Law of Thermodynamics

A
  1. c v = ( change in q / change in T ) v
  2. 1st law of thermo Q 1-2 = U2 - U1 + W 1-2
  3. Work term would be zero as the volume stays constant with NO boundary work so Q 1-2 = U2 - U1 (+ 0)
  4. So change in q = change in u (q is thermal energy and u is internal energy)
  5. c v = ( change in u / change in T ) v
24
Q

What are the units for specific heat cap at constant vol

A

kJ/kg・K