Lesson 11-15 Flashcards
(40 cards)
Electrolytic Cells
Reduction occurs at the cathode
Oxidation occurs at the anode
At the cathode, water is reduced to
The electrolysis of water produces hydrogen and oxygen gases
If the blood becomes acidic,
buffer solutions increase the pH value of blood
What effect will likely occur when a catalyst is added on a reaction
The system reaches equilibrium faster
Kc of H2 + I2 = 2Hl
2.0
Kc is 49 of H2 + I2 = 2HI
HI =
1.55
Cathode and Anode of
Ni(s) -> Ni2+(aq) + 2e-
Au3+(aq) + 3e- -> Au(s)
Au3+ , Ni
E = -0.257V
E = +1.498V
+1.755V
H of 2C(s diamond) -> 2C(s graphite)
H = -3.8 kJ
S of 2C(s diamond) -> 2C(s graphite)
S = + 6.72 J/mol
G of 2C(s diamond) -> 2C(s graphite)
G = -5.51 kJ
500°C N2(g) + 3H2(g) <-> 2NH3(g)
Shift to left
ion-product constant of water
Kw = [H3O+][OH-]
Kw value of water with oh 7.30
2512 x 10^-15
True or False
At point A on the tine axis, the concentration of all three gases is zero
False
The pOH of a solution of NaOH is 11.30. What is the [H+] for this solution?
2.0 x 10^-3
The value of Kw at 10° C is 2.95 x 10^-15
What is the [H3O+] at this temperature?
5.4 x 10^-8
The value of Kw at 10° C is 2.95 x 10^-15
pOH of water
7.3
pH = 4.87 ; Ka = 3.30 x 10^-5)
A/HA = ?
2.45
Which of the following chemical systems at equilibrium involves water acting a Bronsted-Lowry acid?
SO42- + H3O+ = HSO4- + H2O
The E° value of Ni2+/Ni is -0.25V and Ag+/Ag is +0.80V. If a cell is made by taking the two electrodes, what is the feasibility of the reaction?
Since E° value for the cell will be positive, redox reaction is feasible.
The concentration of H3O+ in a patient’s blood sample is 11.65 x 10-8 M. Is the blood acidic, basic, or neutral?
The solution is slightly acidic.
H3O+ 11.65 x 10 x 10^-8
OH-
8.51 x 10^-8
A few drops of concentrated sulphuric acid were added to a mixture of of methanol and 0.2 mol of ethanoic acid. Even after a considerable tir reaction mixture was found to contain some of each reactant. Which of following is the BEST explanation for the incomplete reaction?
An equilibrium mixture was formed.