Liquids and Solids Flashcards

(60 cards)

1
Q

Intermolecular Forces

A

Attractive or repulsive interactions between neighboring molecules

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2
Q

What can intermolecular forces determine?

A

Physical properties such as boiling point, melting point, solubility and density

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3
Q

Intramolecular forces

A

Interactions within a molecule that hold atoms together in a molecule

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4
Q

Types of intermolecular forces

A

London dispersion
Dipole- Dipole
Hydrogen Bonding

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5
Q

Intermolecular force type

London dispersion

A

Exist between all molecules
Weakest IMF
Temporary attractive force

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6
Q

Which intermolecular forces exist between all molecules?

A

London dispersion

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7
Q

Dipole- Dipole

A

Attractive forces between two polar molecules containing permanent dipoles

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8
Q

Permanent dipole

A

Molecules composed of atoms with different electronegativities

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9
Q

What determines the boiling point?

A

Strength of intermolecular force

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10
Q

Hydrogen bonds

A

Strong dipole- dipole interactions betweent a molecules containing a hydrogen atom bonded to N, O, or F

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11
Q

What is the rule for hydrogen bonding

A

Only a hydrogen bond if bonded to a Hydrogen, Oxygen, or Fluorine

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12
Q

Types of intramolecular forces

A

Polar covalent
nonpolar covalent
ionic
metallic bonds

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13
Q

Polar covalent

A

forms between two non metals of slightly different electronegativities

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14
Q

What type of intermolecular interactions are present in polar covalent compounds apart of?

A

dipole-dipole and london dispersion

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15
Q

Nonpolar covalent

A

Form between the same non metals or non metals with similiar electronegativities

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16
Q

What type of intermolecular interaction is present in nonpolar covalent bonds?

A

London dispersion

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17
Q

Ionic bonds

A

Formed between metal and non metal
Transfer of valence e’s from metal to non metal

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18
Q

Cation

A

Postively charged ion

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19
Q

Anion

A

Negativiely charged ion

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20
Q
A
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21
Q

Metallic bonds

A

Form between metal cations and the valence e’s moving freely through lattice

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22
Q

Which are weaker type of forces intermolecular or intramoelcular?

A

Intermolecular

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23
Q

Weakest to strongest intermolecular forces

A

London dispersion < dipole-dipole< H- bonding

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24
Q

Weakest to strongest intramolecular force

A

covalent< ionic < metallic (strongest)

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25
Endothermic
Heat required
26
Exothermic
Heat released
27
Draw the endothermic process of phase changes **(solid to gas)**
28
Draw the exothermic process for phase change **(gas to solid)**
29
What is the process called for a solid to a liquid?
Fusion
30
What is the process from liquid to gas?
Vaporization
31
What is the process from a solid to a gas?
Sublimation
32
Process from gas to liquid
Condensation
33
Process from a liquid to solid
Freezing
34
Process from gas to solid
Deposition
35
Entropy (S)
The disorder or randomness in a system
36
Positive ΔS
Increase in randomness
37
Negative ΔS
Decrease in randomness
38
Enthalpy (H)
Measures the heat in a system
39
What does ΔH represent
Amount of hear gained or lost b a system when a reaction is carried out at constant pressure
40
ΔH > 0 means what
Heat moves into the system so the reaction is **endothermic**
41
ΔH < 0 means what
Heat moves out of the system and the reaction is **exothermic**
42
Phase diagram
Draw out this diagram and label
43
Triple point
Point where all substances exists in the liquid, gas, and solid phase
44
Critical point
Point at which the liquid and gas phase become indistinguishbale
45
What is the point called passed the critical point?
Supercritical fluid
46
# Properties of liquids Miscibility
Degree to which a liquid mixes with another liquid
47
# Properties of liquids Viscosity
Measure of a fluid's resistance to flow
48
# Properties of liquids Surface tension
Ability of a liquid surface to resist external forces
49
# Properties of liquids Vapor Pressure
equilibrium pressure exerted by a vapor above its liquid
50
# Properties of liquids Which has a lower density liquids or solids
Liquids
51
# Properties of solids Ionic solids
Hard, non conductive, brittle and have a high melting point
52
Example of ionic solids
Table salt (NaCl)
53
Metallic solids
Malleable, ductile, conductive, high luster, variable melting pts and hardness
54
Covalent network solids
Hard, non coductive, high melting points
55
Example of covalent network solids
Diamonds
56
Molecular solids
Soft, non conductive, and low melting points
57
Types of unit cells
Simple cubic Body centered cubic Face centerd cubic
58
Simple cubic
1 atom per unit cell At every corner of the cube
59
Body centered cubic
2 atoms per unit cell with 1 atom in the center
60
Face centered cubic
4 atoms per unit cell