LM19-20 Flashcards

(44 cards)

1
Q

Polar definition

A

Electrons are shared unequally and favor one side over the other

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2
Q

Nonpolar

A

Electrons are shared equally, are placed equidistant from each point

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3
Q

H2O is polar due to _____

A

Lone electron pairs on the central atom that cause it to have a non-linear arrangement

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4
Q

Bond length of H2 molecule

A

74 picometers

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5
Q

Octet rule

A

atoms want a filled outer shell (s2, s2p6)

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6
Q

∆EN, what does it show

A

difference in electronegativities, tells polarity and type of bond

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7
Q

Polarity

A

Separation of electrical charge in a bond/molecule

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8
Q

Covalent bonds’ ∆EN value

A

∆EN < 1.5 (approximate)

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9
Q

Ionic bonds’ ∆EN value

A

∆EN > 1.5 (approximate)

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10
Q

As ∆EN gets higher, ionic character (tendency to transfer electrons) ____

A

increases

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11
Q

Non-polar bonds’ ∆EN values

A

∆EN = 0 (approximate value, can reach up to ∆EN = 0.4)

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12
Q

Polar bonds’ ∆EN values

A

∆EN ≠ 0

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13
Q

EN possible values

A

0-4

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14
Q

Hydrogen EN value

A

2.1

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15
Q

Second row EN values

A

1.0-4.0, increasing by 0.5

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16
Q

Dipole Moment

A

Vectors that have magnitude and direction that show the difference in EN values between two atoms

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17
Q

A dipole moment points to the atom with _______

A

greater EN value

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18
Q

Dipole moment 𝛿+

A

Less electronegative atom

19
Q

Dipole moment 𝛿-

A

More electronegative atom

20
Q

A symmetrical molecule is _______

21
Q

An asymmetrical molecule is _______

22
Q

For a molecule to be non-polar, dipole vectors should ________

23
Q

Coulombic attraction

A

Attraction between oppositely charged particles

24
Q

What potential energy does a hydrogen bond have?

A

-7 x 10^-19 J

25
As bond distance gets shorter, potential energy ______
decreases
26
Why does potential energy increase when atoms get extremely close?
The positive charges of the nuclei begin to repel each other
27
What is the bond length of atoms in relation to potential energy?
The internuclear distance at which potential energy is the lowest is the bond length
28
Endothermic process
The breaking of a bond through adding energy
29
Exothermic process
The forming of a bond through releasing energy
30
Lewis-Dot for Ionic Bonds: the anion will...
Be placed within brackets with a full shell
31
Lewis-Dot for Ionic Bonds: the cation will...
Be placed outside of the brackets
32
Lattice energy
energy required to break the bond in an ionic compound (how strongly bound it is)
33
Charge density
The quantity of charge in a certain volume
34
Characteristics that increase charge density
Decreased size, increased magnitude of charges (doubly-charged, etc)
35
Charge density's relationship with lattice energy is
directly proportional
36
Charge density increases attraction because of
the increased magnitude of charges more strongly drawing opposite charges
37
Ranking charge density prioritizes ___
magnitude of charge
38
As attraction increases, bond length
decreases
39
As attraction increases, bond energy
increases
40
Polarization Power
ability of cation to distort anion electron cloud
41
Polarization power increases if a cation has _____
more charge density
42
Polarizability
tendency of anion to be polarized
43
Polarizability increases if an anion's size _____
increases; so electron cloud is more distorted
44