m21 | m22 | m23 | m24 Flashcards

1
Q

What are the three main types of hydrocarbons according to structure?

A
  • alkanes
  • alkenes
  • alkynes
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
2
Q

Why is it important for chemists to know what to call different molecules?

A

To ensure that everyone is kept on the same page, in terms of chemical nomeclature.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
3
Q

What does IUPAC mean?

A

International Union of Pure and Applied Chemistry

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
4
Q

The IUPAC formed such a committe to do exactly what?

A

To create a systematic set of rules for naming organic molecules, ensuring global uniformity

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
5
Q

Identify the item provided the description.

They only contain carbon-carbon or carbon-hydrogen single bonds.

A

alkanes

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
6
Q

True or false: Alkanes are the least saturated carbons due to their single bonds.

A

False

They are known to be the saturated hydrocarbons.

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
7
Q

Identify the item provided the description.

Alkanes are also known as the…

A

the bones of organic molecules

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
8
Q

There are two types of alkanes, what are these?

A
  • straight-chain alkanes
  • branched alkanes
How well did you know this?
1
Not at all
2
3
4
5
Perfectly
9
Q

What is the general formula for alkanes?

A

C(n)H(2n+2)

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
10
Q

These are compounds that have the same number and kinds of atoms but differ in structural arrangement.

A

Constitutional Isomers

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
11
Q

Identify the constitutional isomer.

  • chicken feet
  • equivalent to 2-methylpropane minus a single hydrogen group
A

tert-butyl

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
12
Q

Identify the constitutional isomer.

  • used when all carbons, except for one form a continuous chain
A

iso-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
13
Q

Identify the constitutional isomer.

  • used when the functional group is bonded to a secondary carbon
A

sec-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
14
Q

Identify the constitutional isomer.

  • all carbons form an continuous, unbranched linear chain
A

n-

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
15
Q
  • has an OH group bonded as one of its substituents
A

alcohol

How well did you know this?
1
Not at all
2
3
4
5
Perfectly
16
Q

Which prefixes can you ignore conforming to the standard alphabetization of nomenclature?

A

- tert & sec (go under b with butyl)
- number of identical substituents

17
Q

When given a cycloalkane along with an hydrocarbon chain, which should be the parent name?

A
  • the one with the longer continuous chain of carbons
18
Q

What functional group has this configuration: -OH?

A

alcohol

19
Q

Which specific type of alcohol is present in alcholic drinks such as beer and wine?

A

ethanol
(CH3CH3OH)

20
Q

Ethanol is also known as the byproduct of (?), or the breakdown of sugars into alcohols by yeast enzymes.

A

fermentation

21
Q

This alcohol is also known as wood alcohol.

A

methanol
(CH3OH)

22
Q

Which alcohol is known to be the component of rubbing alcohol?

A

isopropyl alcohol
(CH3)2CHOH

23
Q

What other importance does alcohol possess other than being useful in many drugs and organic materials?

A

They are useful intermmediates in synthesis beacuse they’re easily made and transformed into their functional groups.

24
Q

When naming alcohols, where should you start?

A

You start by identifying the longest chain with the -OH group in it and ensure that it has the least locant than other substituents.

25
Q

When naming alcohols, what do you do when a chiral center is shown?

A

Assign the stereochemistry of the chiral center and place this designation in front of the name. (R/S configuration)

R - clockwise : S - counterclockwise

26
Q

What is the general formula for alcohols?

A

CnH2n+1OH

27
Q
  • this is a stepwise process of how the starting material changes into the product
  • it shows which bonds are formed and broken and in what order
A

mechanism of a reaction

28
Q

What suffix is added to distinguish alkenes?

A

-ene

29
Q

When naming alkenes, how should you start off?

A

Find the longest chain that contains the double bond and number the parent chain from the side that reaches the double bond first.

30
Q

This type of sterochemistry has the identical substituents stick off the same side of the double bond.

A

cis stereochemistry

31
Q

This type of sterochemistry has the identical substituents stick off the opposite sides of the double bond.

A

trans stereochemistry

32
Q

This system involves the usage of priority lines for different substituents based on their atomic number.

A

E/Z system

33
Q

By which priority rules do the E/Z system abide by?

A

Cahn-Ingold-Prelog

34
Q

Which E/Z configuration is this?

The high-priority substituents are on the same side of the double bond.

A

Z - configuration
(Zusammen)

35
Q

Which E/Z configuration is this?

The high-priority substituents are on opposite sides of the double bond.

A

E - configuration
(Entgegen)

36
Q

These are molecules that contain triple carbon-carbon bonds.

A

alkynes

37
Q

This is a sequence of two or more individual reactions that converts a starting material into a desired product with a more complicated structure.

A

multistep synthesis

38
Q

If you have both an alkene and alkyne in the molecule….

A

Still, number the chain to give the alkyne the least possible number, then the alkene follows.