MARY - Topic 5 Flashcards

1
Q

What does a boundary surface represent?

A

A 95% probability of where electron density is located for a given orbital.

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2
Q

Why doesn’t it give a 100% probability?

A
1 = R(r) never touches the r axis
2 = so R(r0 only reaches '0' at infinity
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3
Q

What is an angular node?

A

When angular wavefunction = 0, they are either planes or cones and don’t depend on r.

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4
Q

What happens with other one electron systems?

A

When you increase the number of protons in the nucleus, the most likely distance from the nucleus of finding the e- is less, so rdf max is less.

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