Mass Spectrometer Flashcards
(13 cards)
What happens to the ions when they hit the detector?
Loose their charge and are removed through a vacuum
how are the ions accelerated?
Using negatively charged plates
what is the process after ionisation?
Acceleration
what does the electromagnet do?
Makes a magnetic field to direct the ions travel, the strength is increased slowly so that each particle deflects in turn. Heavier ions are deflected less and 2+ ions are deflected twice as much.
why does the sample have to be vaporised?
So it can move around freely
How are the atoms ionised?
High energy electrons fired from electron gun which knock off an electron from the atom
What deflects moving ions round a curved path?
Electromagnetic field
What accelerated the ions before they’re deflected?
A series of charged plates?
why so the ions separate into various paths?
Isotopes are present
Give two reasons why the sample must be ionised?
- To accelerate the ions
2. To be detected
explain briefly how the relative abundance of an ion is measured in a mass spec
- ions hit detector and cause a current
* bigger the current the more of that isotope
why do isotopes have the same chemical properties?
because they have the same number of electrons in their outer shell
explain why the ionisation energy of every element is endothermic
energy needed to overcome attraction between positive nucleus and negative electron