Measuring pH Flashcards
(35 cards)
[x] means
the concentration of x
what is the equation to show when water molecules undergo self ionisation
H2O(l) + H2O(l) ⇌ H3O+(aq) + OH−(aq)
how does water behave when reacting with itself
as both a very weak base and very weak acid
Kw
ionic product of water
formula to calculate Kw
[H3O+][OH-]=1x10^-14 at 25°C
how is the Kw formula justified
all aqeuous solutions conatin H3O+ ions and OH- ions and the product of their molar concentrations is always 1x10^-14 at 25°C and therfore if either [H3O+][OH-]increases than the concentration of the other must decrease proportionatley
formula to calculate concentration of H3O+ from known concentration of OH-
[H3O+] = 1x10^-14/[OH-]
formula to calculate concentration of OH- from known concentration of H3O+
[OH-} = 1x10^-14/[H3O+]
[H3O+][OH-] is known as
the ionic product of water
in pure water and neutral solutions [H3O+]
10^-7
in pure water and neutral solutions [OH-]
10^-7
in acidic solutions [H3O+]
[H3O+]>10^-7
in acidic solutions [OH-]
[OH-}<10^-7
in basic solutions [H3O+]
[H3O+]<10^-7
in basic solutions [OH-]
[OH-}>10^-7
how to calculate [H3O+] from known acid concentration
if the acid contains 1 hydrogen atom, its [H3O+] is equal to its concentration,if the acid contains 2 hydrogen atoms its [H3O+] is double its concentration
how to calculate [OH-] from base
if the base contains 1 hydrogen atom, its [OH-] is equal to its concentration,if the base contains 2 hydrogen atoms its [OH-] is double its concentration
formula to calculate pH
pH=-log10[H3O+]
at 25°C, neutral solutions have a pH of
7
at 25°C, acidic solutions have a pH of
less than 7
at 25°C, basic solutions have a pH of
more than 7
a solution of pH 2 has how many more H3O+ ions than a pH of 3
ten times the concentration of the H3O+
how to calculate the [H3O+] from known pH
[H3O+] = 10^-pH
pH metres do what
provide a specific quantitative measurement of pH