Measuring pH Flashcards

(35 cards)

1
Q

[x] means

A

the concentration of x

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2
Q

what is the equation to show when water molecules undergo self ionisation

A

H2O(l) + H2O(l) ⇌ H3O+(aq) + OH−(aq)

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3
Q

how does water behave when reacting with itself

A

as both a very weak base and very weak acid

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4
Q

Kw

A

ionic product of water

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5
Q

formula to calculate Kw

A

[H3O+][OH-]=1x10^-14 at 25°C

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6
Q

how is the Kw formula justified

A

all aqeuous solutions conatin H3O+ ions and OH- ions and the product of their molar concentrations is always 1x10^-14 at 25°C and therfore if either [H3O+][OH-]increases than the concentration of the other must decrease proportionatley

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7
Q

formula to calculate concentration of H3O+ from known concentration of OH-

A

[H3O+] = 1x10^-14/[OH-]

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8
Q

formula to calculate concentration of OH- from known concentration of H3O+

A

[OH-} = 1x10^-14/[H3O+]

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9
Q

[H3O+][OH-] is known as

A

the ionic product of water

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10
Q

in pure water and neutral solutions [H3O+]

A

10^-7

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11
Q

in pure water and neutral solutions [OH-]

A

10^-7

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12
Q

in acidic solutions [H3O+]

A

[H3O+]>10^-7

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13
Q

in acidic solutions [OH-]

A

[OH-}<10^-7

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14
Q

in basic solutions [H3O+]

A

[H3O+]<10^-7

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15
Q

in basic solutions [OH-]

A

[OH-}>10^-7

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16
Q

how to calculate [H3O+] from known acid concentration

A

if the acid contains 1 hydrogen atom, its [H3O+] is equal to its concentration,if the acid contains 2 hydrogen atoms its [H3O+] is double its concentration

17
Q

how to calculate [OH-] from base

A

if the base contains 1 hydrogen atom, its [OH-] is equal to its concentration,if the base contains 2 hydrogen atoms its [OH-] is double its concentration

18
Q

formula to calculate pH

A

pH=-log10[H3O+]

19
Q

at 25°C, neutral solutions have a pH of

20
Q

at 25°C, acidic solutions have a pH of

21
Q

at 25°C, basic solutions have a pH of

22
Q

a solution of pH 2 has how many more H3O+ ions than a pH of 3

A

ten times the concentration of the H3O+

23
Q

how to calculate the [H3O+] from known pH

A

[H3O+] = 10^-pH

24
Q

pH metres do what

A

provide a specific quantitative measurement of pH

25
how do pH metres work
by measuring the difference in electrical potential between two probes due to the concentration of charged particles or ions in the solution
26
what are indicators
substances that change colour when they are added to an acidic or basic solution
27
what is universal indicator
a mixture of a variety of other indicators that can be used to measure the approximate pH of a solution
28
litmus paperr
one of tthe simplest and most common indicatorrs which uses a dye derived from lichens
29
litmus paper in acidic solutions
blue litmus paper will turn red
30
littmus paper in basic solutions
red litmus paper will turn blue
31
why as indicators less accurate then pH metres
indicators only provide a pH range for a given solution
32
accuracy of pH metres
highly accurate, usually correct to +-0.01 pH uints and is built into the calibration of the metre
33
why are pH metres more precise
because there is no change to the calibration of the instrument between measurements
34
why are indicators less precise
the estimated pH of a given solution may differ greatly between multiple trials
35
end point
the point at which the indicator changes colour