mechanisms Flashcards

(12 cards)

1
Q

for nucleophilic substituition w ammonia what r the conditions

A
  • dissolved in ethanolic solvent
    XS
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2
Q

for nucleophilic substituition w OH- what r the conditions

A

aqueous
room temp

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3
Q

for nucleophilic substituition w CN what r the conditions

A

WARM
dissolved in ethanolic solvent

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4
Q

conditions for elimination of halogenoalkanes

A
  • oh- ethanolic
  • heat
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5
Q

what does oh- act as in elimination of halogenoalkane

A

base

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6
Q

EA of alkenes w sufuric acid

A

delta pos on H + delta neg on O in h2so4 - oh bond breaks towards delta neg h2so4

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7
Q

cond for acid catalysed elim mechanism (alc to alkene)

A

warm, under reflux
w conc h2so4/h3po4

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8
Q

cond for acid catalysed addition mechanism (alkene to alc)

A

req high T +P
H+ from H3PO4

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9
Q

what is nucleophilic addition for

A
  1. reduction of aldehydes and ketons into 1’/2’ alc
  2. carbonyl compounds w KCN + dilute acid -> hydroxynitriles

ALD + KET -> ALC/HYDROXYNITRILES

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10
Q

NA of aldehyde -> alc where does the H+ come from

A

from water/WA or NaBH4

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11
Q

N AE is for what

A

acyl chlorides!!!!

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12
Q
A
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