mechanisms Flashcards
(12 cards)
for nucleophilic substituition w ammonia what r the conditions
- dissolved in ethanolic solvent
XS
for nucleophilic substituition w OH- what r the conditions
aqueous
room temp
for nucleophilic substituition w CN what r the conditions
WARM
dissolved in ethanolic solvent
conditions for elimination of halogenoalkanes
- oh- ethanolic
- heat
what does oh- act as in elimination of halogenoalkane
base
EA of alkenes w sufuric acid
delta pos on H + delta neg on O in h2so4 - oh bond breaks towards delta neg h2so4
cond for acid catalysed elim mechanism (alc to alkene)
warm, under reflux
w conc h2so4/h3po4
cond for acid catalysed addition mechanism (alkene to alc)
req high T +P
H+ from H3PO4
what is nucleophilic addition for
- reduction of aldehydes and ketons into 1’/2’ alc
- carbonyl compounds w KCN + dilute acid -> hydroxynitriles
ALD + KET -> ALC/HYDROXYNITRILES
NA of aldehyde -> alc where does the H+ come from
from water/WA or NaBH4
N AE is for what
acyl chlorides!!!!