MEGR 1100 Flashcards

(59 cards)

1
Q

The electron of a hydrogen atom revolves around the nucleus in subtle circle orbits

A

Postulates

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2
Q

What are the 3 Quantum Conditions

A

Size, shape, and orientation

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3
Q

n=

A

The principle quantum number determines the energy of the orbital

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4
Q

l=

A

The angular momentum determines the shape of the orbital

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5
Q

m sub l

A

The magnetic quantum number determines the orientation of the orbital

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6
Q

m sub s

A

The electron spin quantum number is characterized by the magnetic movement

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7
Q

Can be positive or negative

A

n

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8
Q

Describes the shape 0- (n-1)

A

l

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9
Q

l=0

A

S orbital

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10
Q

l=1

A

P orbital

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11
Q

l=2

A

D orbital

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12
Q

l= 3

A

F orbital

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13
Q

Determines the orientation

A

m sub l

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14
Q

m sub l =

A

negative l to positive l

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15
Q

2 spin magnitudes of negative 1/2 to positive 1/2

A

m sub s

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16
Q

No two electrons can have the same 4 quantum numbers

A

Pauli Exclusion Principle

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17
Q

The minimum amount of energy required to remove the most loosely bound electron of an isolated neutral atom molecule

A

Ionization Energies

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18
Q

The amount of energy released when an electron is attached to a neutral atom or molecule in the gaseous state to form a negative ion

A

Electron Affinity

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19
Q

unpaired electrons attracted by a magnetic field

A

Paramagnetic

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20
Q

fully paired electrons are not attracted by a magnetic field

A

Diamagnetic

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21
Q

stable atom posses eight valence electrons

A

Octet Rule

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22
Q

Metal and non-metal (electrostatic)

A

Ionic bonding

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23
Q

Non-metals

A

Covalent bonding

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24
Q

Delocalized, metals, electrically conductive (molecular)

A

Metallic Bonding

25
Shared pair of electrons comes from one atom
Coordinate Bonding
26
electrons going to be shared
Covalent Bonds
27
Formal Charge =
Valence electrons- Non-Bounded electrons- bounded electrons that
28
sharing or taking electrons to be isoelectronic with noble gas (full octet)
Bonding
29
Trades electrons; metals and non-metals
Ionic Bonds
30
Shares electrons; non-metals
Covalent Bonds
31
Delocalized electrons; metals and conductive
Metallic
32
All chemical Processes consume (endothermic) or release (exothermic) energy
Energy of Ionic Bond Formation
33
Valence shell electron pair repulsion
Vesper Theory
34
2 things around a central atom
linear molecule
35
108 degrees
linear molecule angle
36
3 things surrounded by a central atom
Trigonal Plane
37
120 degrees
Trigonal Plane angle
38
Three things around a central atom with non bounded electrons
Bent molecule
39
less than 120 degrees and around 116 degrees
Bent molecule angle
40
4 things surrounded by a central atom
Tetrahedral
41
109.5 degrees
Tetrahedral angle
42
3 atoms are surrounded by a central atom but with non bounded electrons
Trigonal pyramidal
43
Less than 109.5 degrees around 107 degrees
Trigonal Pyramidal angle
44
Translational, Rotational, and Vibrational
Degrees of Freedom
45
Moves in the x, y, and z direction
Translational
46
Rotates around an axis going through the center of the molecule (through the bond line) involving momentum
Rotational
47
Only applicable at higher temperatures. Linear molecules: 3N-5, Non-Linear molecule: 3N-6 for an N-atom molecule
Vibrational
48
Mostly electrostatic attraction between oppositely charged particles
Ionic Crystals
49
loses and electron
smaller radii
50
Gains an electron
larger radii
51
substances that tend to have a define shape
Solids
52
Same forces as solid bonding these atoms, but the strength of the forces is not sufficient
Liquid
53
Repeating/periodic array and bounded o their nearest atom
Crystalline solid
54
Lacks a systematic and regular arrangement of. resembles a liquid
Non-Crystalline Solid
55
-A crystalline solid for which the periodic and repeated atomic pattern extends through the entire crystal. -Non grain boundaries. -exists in nature but can be produced artificially -quartz, salt, diamond, and topaz
Single crystal
56
-Composed of more than crystal or grain -grain boundaries -different atomic orientations
Polycrystal
57
Atomic hard-sphere model and reduced sphere model
Crystal structure
58
3D array of points coinciding with atom positions
Lattice
59
Basic structure unit of crystal structure that represents the symmetry of a crystal structure
Unit Cell